Formation of a Fluorous/Organic Biphasic Supramolecular Octopus Assembly for Enhanced Porphyrin Phosphorescence in Air

Yang, Chi; Arvapally, Ravi K.; Tekarli, Sammer M.; Salazar, Gustavo A.; Elbjeirami, Oussama; Wang, Xiaoping; Omary, Mohammad A.

doi:10.1002/anie.201411462

Formation of a Fluorous/Organic Biphasic Supramolecular Octopus Assembly for Enhanced Porphyrin Phosphorescence in Air

Journal Article · Tue Mar 03 00:00:00 EST 2015 · Angewandte Chemie International Edition (Online)

DOI:https://doi.org/10.1002/anie.201411462· OSTI ID:1335317

Yang, Chi ^[1]; Arvapally, Ravi K. ^[1]; Tekarli, Sammer M. ^[1]; Salazar, Gustavo A. ^[1]; Elbjeirami, Oussama ^[1]; Wang, Xiaoping ^[2]; Omary, Mohammad A. ^[1]

Univ. of North Texas, Denton, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The trinuclear triangle-shaped system [tris{3,5-bis(heptafluoropropyl)-1,2,4-triazolatosilver(I)}] (1) and the multi-armed square-shaped metalloporphyrin PtOEP or the free porphyrin base H2OEP serve as excellent octopus hosts (OEP=2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine). Coupling of the fluorous/organic molecular octopi 1 and H2OEP or PtOEP by strong quadrupole-quadrupole and metal- interactions affords the supramolecular assemblies [1PtOEP] or [1H(2)OEP] (2a), which feature nanoscopic cavities surrounding the upper triangular and lower square cores. The fluorous/organic biphasic configuration of [1PtOEP] leads to an increase in the phosphorescence of PtOEP under ambient conditions. Guest molecules can be included in the biphasic double-octopus assembly in three different site-selective modes.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1335317

Journal Information:: Angewandte Chemie International Edition (Online), Journal Name: Angewandte Chemie International Edition (Online) Journal Issue: 16 Vol. 54; ISSN 1521-3773

Publisher:: Gesselschaft Deutscher ChemikerCopyright Statement

Country of Publication:: United States

Language:: English

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CCDC 1036094: Experimental Crystal Structure Determination: GUJQIN : (2,3,7,8,12,13,17,18-Octaethylporphyrinato)-platinum tris(μ2-3,5-bis(perfluoro-n-propyl)-1,2,4-triazolato)-tri-silver benzene solvate Yang, Chi; Arvapally, Ravi K.; Tekarli, Sammer https://doi.org/10.5517/cc13s4df The current record is supplemented by this dataset	dataset	November 2014
CCDC 1036095: Experimental Crystal Structure Determination: GUJQOT : 2,3,7,8,12,13,17,18-Octaethylporphyrin tris(μ2-3,5-bis(perfluoro-n-propyl)-1,2,4-triazolato)-tri-silver benzene solvate Yang, Chi; Arvapally, Ravi K.; Tekarli, Sammer https://doi.org/10.5517/cc13s4fg The current record is supplemented by this dataset	dataset	November 2014
CCDC 1036096: Experimental Crystal Structure Determination: GUJQUZ : (2,3,7,8,12,13,17,18-Octaethylporphyrinato)-platinum tris(μ2-3,5-bis(perfluoro-n-propyl)-1,2,4-triazolato)-tri-silver acetone solvate Yang, Chi; Arvapally, Ravi; Tekarli, Sammer https://doi.org/10.5517/cc13s4gh The current record is supplemented by this dataset	dataset	November 2014
CCDC 1036097: Experimental Crystal Structure Determination: GUJRAG : (2,3,7,8,12,13,17,18-Octaethylporphyrinato)-platinum tris(μ2-3,5-bis(perfluoro-n-propyl)-1,2,4-triazolato)-tri-silver acetonitrile solvate Yang, Chi; Arvapally, Ravi; Tekarli, Sammer https://doi.org/10.5517/cc13s4hj The current record is supplemented by this dataset	dataset	January 2015

Formation of a Fluorous/Organic Biphasic Supramolecular Octopus Assembly for Enhanced Porphyrin Phosphorescence in Air

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