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Title: Methods for polymer synthesis

Patent ·
OSTI ID:1334668

The present invention provides methods for reducing induction periods in epoxide-CO.sub.2 copolymerizations. In certain embodiments, the methods include the step of contacting an epoxide with CO.sub.2 in the presence of two catalysts: an epoxide hydrolysis catalyst and an epoxide CO.sub.2 copolymerization catalyst. In another aspect, the invention provides catalyst compositions comprising a mixture of an epoxide hydrolysis catalyst and an epoxide CO.sub.2 copolymerization catalyst.

Research Organization:
Novomer, Inc. Ithaca, NY (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FE0002474
Assignee:
Novomer, Inc. (Ithaca, NY)
Patent Number(s):
9,512,269
Application Number:
14/367,333
OSTI ID:
1334668
Resource Relation:
Patent File Date: 2012 Dec 20
Country of Publication:
United States
Language:
English

References (2)

Polycarbonate Polyol Compositions and Methods patent-application September 2011
Cobalt Catalysts for the Alternating Copolymerization of Propylene Oxide and Carbon Dioxide:  Combining High Activity and Selectivity journal August 2005

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