Discovery of Fe–Ce Oxide/BiVO4 Photoanodes through Combinatorial Exploration of Ni–Fe–Co–Ce Oxide Coatings

Shinde, Aniketa; Guevarra, Dan; Liu, Guiji; Sharp, Ian D.; Toma, Francesca M.; Gregoire, John M.; Haber, Joel A.

doi:10.1021/acsami.6b06714

Title: Discovery of Fe–Ce Oxide/BiVO₄ Photoanodes through Combinatorial Exploration of Ni–Fe–Co–Ce Oxide Coatings

Journal Article · Tue Aug 23 00:00:00 EDT 2016 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.6b06714· OSTI ID:1333887

Shinde, Aniketa ^[1]; Guevarra, Dan ^[1]; Liu, Guiji ^[2]; Sharp, Ian D. ^[2]; Toma, Francesca M. ^[2]; Gregoire, John M. ^[1]; Haber, Joel A. ^[1]

California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Joint Center for Artificial Photosynthesis (JCAP) and Chemical Sciences Division

An efficient photoanode is a prerequisite for a viable solar fuels technology. The challenges to realizing an efficient photoanode include the integration of a semiconductor light absorber and a metal oxide electrocatalyst to optimize corrosion protection, light trapping, hole transport, and photocarrier recombination sites. To efficiently explore metal oxide coatings, we employ a high-throughput methodology wherein a uniform BiVO 4 film is coated with 858 unique metal oxide coatings covering a range of metal oxide loadings and the full (Ni-Fe-Co-Ce)O x pseudoquaternary composition space. Photoelectrochemical characterization of the photoanodes reveals that specific combinations of metal oxide composition and loading provide up to a 13-fold increase in the maximum photoelectrochemical power generation for oxygen evolution in pH 13 electrolyte. Through mining of the high-throughput data we identify composition regions that form improved interfaces with BiVO 4 . Of particular note, integrated photoanodes with catalyst compositions in the range Fe (0.4-0.6) Ce (0.6-0.4) O x exhibit high interface quality and excellent photoelectrochemical power conversion. Scaled-up inkjet-printed electrodes and photoanodic electrodeposition of this composition on BiVO 4 confirms the discovery and the synthesis-independent interface improvement of (Fe-Ce)O x coatings on BiVO 4.

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Research Organization:: California Institute of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0004993; AC02-05CH11231

OSTI ID:: 1333887

Alternate ID(s):: OSTI ID: 1454487

Journal Information:: ACS Applied Materials and Interfaces, Vol. 8, Issue 36; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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Title: Discovery of Fe–Ce Oxide/BiVO4 Photoanodes through Combinatorial Exploration of Ni–Fe–Co–Ce Oxide Coatings

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Title: Discovery of Fe–Ce Oxide/BiVO₄ Photoanodes through Combinatorial Exploration of Ni–Fe–Co–Ce Oxide Coatings