Evaluation of Fuel-Borne Sodium Effects on a DOC-DPF-SCR Heavy-Duty Engine Emission Control System: Simulation of Full-Useful Life

Journal Article · Tue Apr 05 04:00:00 EDT 2016 · SAE International Journal of Fuels and Lubricants (Online)

DOI:https://doi.org/10.4271/2016-01-2322· OSTI ID:1333492

Lance, Michael; Wereszczak, Andrew; Toops, Todd J.; Ancimer, Richard; An, Hongmei; Li, Junhui; Rogoski, Leigh; Sindler, Petr; Williams, Aaron; Ragatz, Adam; McCormick, Robert L.

For renewable fuels to displace petroleum, they must be compatible with emissions control devices. Pure biodiesel contains up to 5 ppm Na + K and 5 ppm Ca + Mg metals, which have the potential to degrade diesel emissions control systems. This study aims to address these concerns, identify deactivation mechanisms, and determine if a lower limit is needed. Accelerated aging of a production exhaust system was conducted on an engine test stand over 1,001 hr using B20 doped with 14 ppm Na. During the study, oxides of nitrogen (NOx) emissions exceeded the engine certification limit of 0.33 g/bhp-hr before the 435,000-mile requirement. Replacing aged diesel oxidation catalyst (DOC), diesel particulate filter (DPF), and selective catalytic reduction (SCR) devices with new degreened parts showed that each device contributed equally to the NOx increase. Following this systems-based evaluation, a detailed investigation of the individual components was completed. Na was determined to have minimal impact on DOC activity. For this system, it is estimated that B20-Na resulted in 50% more ash into the DPF. However, the Na did not diffuse into the cordierite DPF nor degrade its mechanical properties. The SCR degradation was found to be caused by a small amount of precious group metals contamination that increased ammonia oxidation, and lowered NOx reduction. Therefore, it was determined that the primary effect of Na in this study is through increased ash in the DPF rather than deactivation of the catalytic activity.

• Research Organization: NREL (National Renewable Energy Laboratory (NREL), Golden, CO (United States))
• Sponsoring Organization: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Biodiesel Board
• DOE Contract Number: AC36-08GO28308
• OSTI ID: 1333492
• Report Number(s): NREL/JA-5400-66463
• Journal Information: SAE International Journal of Fuels and Lubricants (Online), Journal Name: SAE International Journal of Fuels and Lubricants (Online) Journal Issue: 3 Vol. 9; ISSN 1946-3960
• Publisher: SAE International
• Country of Publication: United States
• Language: English

Related Subjects

33 ADVANCED PROPULSION SYSTEMS
biodiesel
diesel emissions
diesel oxidation catalyst
diesel particle filter
sodium
urea selective catalytic reduction