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Title: High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes

Journal Article · · Advanced Energy Materials (Online)

High energy and cost-effective lithium sulfur (Li-S) battery technology has been vigorously revisited in recent years due to the urgent need of advanced energy storage technologies for transportation and large-scale energy storage applications. However, the market penetration of Li-S batteries has been plagued due to the gap in scientific knowledge between the fundamental research and the real application need. Herein, we focus on the cathode part of the Li-S system and discuss 1) the progress and issues of literature-reported sulfur cathode; 2) how to employ materials chemistry/science to address the challenges to thicken sulfur cathode; 3) the factors that affect the electrochemical performances of Li-S cells constructed at a relevant scale. This progress report attempts to tie the fundamental understanding closely to the practical application of Li-S batteries so that it may provide new insights for the research efforts of Li-S battery technology.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1333457
Report Number(s):
PNNL-SA-107462; 48379; VT1201000
Journal Information:
Advanced Energy Materials (Online), Vol. 5, Issue 16; ISSN 1614-6840
Publisher:
Wiley
Country of Publication:
United States
Language:
English