Laser Direct Write Synthesis of Lead Halide Perovskites

Chou, Stanley S.; Swartzentruber, Brian S.; Janish, Matthew T.; Meyer, Kristin C.; Biedermann, Laura B.; Okur, Serdal; Burckel, D. Bruce; Carter, C. Barry; Kaehr, Bryan

doi:10.1021/acs.jpclett.6b01557

Laser Direct Write Synthesis of Lead Halide Perovskites

Journal Article · Mon Sep 05 00:00:00 EDT 2016 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.6b01557· OSTI ID:1332912

Chou, Stanley S. ^[1]; Swartzentruber, Brian S. ^[2]; Janish, Matthew T. ^[3]; Meyer, Kristin C. ^[4]; Biedermann, Laura B. ^[1]; Okur, Serdal ^[5]; Burckel, D. Bruce ^[1]; Carter, C. Barry ^[6]; Kaehr, Bryan ^[7]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Center for Integrated Nanotechnologies
Univ. of Connecticut, Storrs, CT (United States). Dept. of Materials Science and Engineering
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Advanced Materials Lab.
Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Electrical and Computer Engineering
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Center for Integrated Nanotechnologies; Univ. of Connecticut, Storrs, CT (United States). Dept. of Materials Science and Engineering
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Advanced Materials Lab.; Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemical and Biological Engineering

Lead halide perovskites are increasingly considered for applications beyond photovoltaics, for example, light emission and detection, where an ability to pattern and prototype microscale geometries can facilitate the incorporation of this class of materials into devices. In this study, we demonstrate laser direct write of lead halide perovskites, a remarkably simple procedure that takes advantage of the inverse dependence between perovskite solubility and temperature by using a laser to induce localized heating of an absorbing substrate. We also demonstrate arbitrary pattern formation of crystalline CH₃NH₃PbBr₃ on a range of substrates and fabricate and characterize a microscale photodetector using this approach. This direct write methodology provides a path forward for the prototyping and production of perovskite-based devices.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1332912

Report Number(s):: SAND2016--10725J; 648559

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 19 Vol. 7; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (28)

Controlled Synthesis of Organic/Inorganic van der Waals Solid for Tunable Light-Matter Interactions Niu, Lin; Liu, Xinfeng; Cong, Chunxiao Advanced Materials, Vol. 27, Issue 47 https://doi.org/10.1002/adma.201503367	journal	October 2015
“Liquid Knife” to Fabricate Patterning Single-Crystalline Perovskite Microplates toward High-Performance Laser Arrays Feng, Jiangang; Yan, Xiaoxu; Zhang, Yifan Advanced Materials, Vol. 28, Issue 19 https://doi.org/10.1002/adma.201505952	journal	March 2016
Chemically Exfoliated MoS ₂ as Near-Infrared Photothermal Agents Chou, Stanley S.; Kaehr, Bryan; Kim, Jaemyung Angewandte Chemie, Vol. 125, Issue 15 https://doi.org/10.1002/ange.201209229	journal	March 2013
I-V hysteresis of methylammonium lead halide perovskite films on microstructured electrode arrays: Dependence on preparation route and voltage scale: I - V hysteresis of perovskite films on microstructured electrode arrays Stumpp, Martina; Ruess, Raffael; Horn, Jonas physica status solidi (a), Vol. 213, Issue 1 https://doi.org/10.1002/pssa.201532527	journal	October 2015
Patterning and photoluminescent properties of perovskite-type organic/inorganic hybrid luminescent films by soft lithography Cheng, Z. Y.; Wang, Z.; Xing, R. B. Chemical Physics Letters, Vol. 376, Issue 3-4 https://doi.org/10.1016/S0009-2614(03)01017-0	journal	July 2003
Comparative study on the excitons in lead-halide-based perovskite-type crystals CH₃NH₃PbBr₃ CH₃NH₃PbI₃ Tanaka, Kenichiro; Takahashi, Takayuki; Ban, Takuma Solid State Communications, Vol. 127, Issue 9-10, p. 619-623 https://doi.org/10.1016/S0038-1098(03)00566-0	journal	September 2003
Scintillation properties of (C6H13NH3)2PbI4: Exciton luminescence of an organic/inorganic multiple quantum well structure compound induced by 2.0 MeV protons Shibuya, K.; Koshimizu, M.; Takeoka, Y. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 194, Issue 2 https://doi.org/10.1016/S0168-583X(02)00671-7	journal	August 2002
Origin of J – V Hysteresis in Perovskite Solar Cells Chen, Bo; Yang, Mengjin; Priya, Shashank The Journal of Physical Chemistry Letters, Vol. 7, Issue 5 https://doi.org/10.1021/acs.jpclett.6b00215	journal	February 2016
High-Density and Uniform Lead Halide Perovskite Nanolaser Array on Silicon Wang, Kaiyang; Gu, Zhiyuan; Liu, Shuai The Journal of Physical Chemistry Letters, Vol. 7, Issue 13 https://doi.org/10.1021/acs.jpclett.6b01072	journal	June 2016
Using Laser-Induced Thermal Voxels to Pattern Diverse Materials at the Solid–Liquid Interface Zarzar, Lauren D.; Swartzentruber, B. S.; Donovan, Brian F. ACS Applied Materials & Interfaces, Vol. 8, Issue 33 https://doi.org/10.1021/acsami.6b06625	journal	August 2016
Laser-Induced Hydrothermal Growth of Heterogeneous Metal-Oxide Nanowire on Flexible Substrate by Laser Absorption Layer Design Yeo, Junyeob; Hong, Sukjoon; Kim, Gunho ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b01125	journal	May 2015
Fully Printed Halide Perovskite Light-Emitting Diodes with Silver Nanowire Electrodes Bade, Sri Ganesh R.; Li, Junqiang; Shan, Xin ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b07506	journal	December 2015
Flexible Hybrid Organic–Inorganic Perovskite Memory Gu, Chungwan; Lee, Jang-Sik ACS Nano, Vol. 10, Issue 5 https://doi.org/10.1021/acsnano.6b01643	journal	April 2016
Multiphoton Lithography of Nanocrystalline Platinum and Palladium for Site-Specific Catalysis in 3D Microenvironments Zarzar, Lauren D.; Swartzentruber, B. S.; Harper, Jason C. Journal of the American Chemical Society, Vol. 134, Issue 9 https://doi.org/10.1021/ja211602t	journal	February 2012
Nanoscale Graphene Oxide (nGO) as Artificial Receptors: Implications for Biomolecular Interactions and Sensing Chou, Stanley S.; De, Mrinmoy; Luo, Jiayan Journal of the American Chemical Society, Vol. 134, Issue 40 https://doi.org/10.1021/ja306767y	journal	September 2012
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Solution Growth of Single Crystal Methylammonium Lead Halide Perovskite Nanostructures for Optoelectronic and Photovoltaic Applications Fu, Yongping; Meng, Fei; Rowley, Matthew B. Journal of the American Chemical Society, Vol. 137, Issue 17 https://doi.org/10.1021/jacs.5b02651	journal	April 2015
Extremely Slow Photoconductivity Response of CH ₃ NH ₃ PbI ₃ Perovskites Suggesting Structural Changes under Working Conditions Gottesman, Ronen; Haltzi, Eynav; Gouda, Laxman The Journal of Physical Chemistry Letters, Vol. 5, Issue 15 https://doi.org/10.1021/jz501373f	journal	July 2014
Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates Docampo, Pablo; Ball, James M.; Darwich, Mariam Nature Communications, Vol. 4, Article No. 2761 https://doi.org/10.1038/ncomms3761	journal	November 2013
High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization Saidaminov, Makhsud I.; Abdelhady, Ahmed L.; Murali, Banavoth Nature Communications, Vol. 6, Article No. 7586 https://doi.org/10.1038/ncomms8586	journal	July 2015
Understanding catalysis in a multiphasic two-dimensional transition metal dichalcogenide Chou, Stanley S.; Sai, Na; Lu, Ping Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9311	journal	October 2015
Planar-integrated single-crystalline perovskite photodetectors Saidaminov, Makhsud I.; Adinolfi, Valerio; Comin, Riccardo Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9724	journal	November 2015
Giant switchable photovoltaic effect in organometal trihalide perovskite devices Xiao, Zhengguo; Yuan, Yongbo; Shao, Yuchuan Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4150	journal	December 2014
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors Zhu, Haiming; Fu, Yongping; Meng, Fei Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4271	journal	April 2015
Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter‐wave spectroscopy Poglitsch, A.; Weber, D. The Journal of Chemical Physics, Vol. 87, Issue 11, p. 6373-6378 https://doi.org/10.1063/1.453467	journal	December 1987
Non-ferroelectric nature of the conductance hysteresis in CH ₃ NH ₃ PbI ₃ perovskite-based photovoltaic devices Beilsten-Edmands, J.; Eperon, G. E.; Johnson, R. D. Applied Physics Letters, Vol. 106, Issue 17 https://doi.org/10.1063/1.4919109	journal	April 2015
Wafer-scale growth of large arrays of perovskite microplate crystals for functional electronics and optoelectronics Wang, Gongming; Li, Dehui; Cheng, Hung-Chieh Science Advances, Vol. 1, Issue 9 https://doi.org/10.1126/sciadv.1500613	journal	October 2015
CH3NH3PbX3, ein Pb(II)-System mit kubischer Perowskitstruktur / CH3NH3PbX3, a Pb(II)-System with Cubic Perovskite Structure Weber, Dieter Zeitschrift für Naturforschung B, Vol. 33, Issue 12 https://doi.org/10.1515/znb-1978-1214	journal	December 1978

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Recent Advances in Perovskite Micro- and Nanolasers Wang, Kaiyang; Wang, Shuai; Xiao, Shumin Advanced Optical Materials, Vol. 6, Issue 18 https://doi.org/10.1002/adom.201800278	journal	June 2018
Nonvolatile Rewritable Photomemory Arrays Based on Reversible Phase‐Change Perovskite for Optical Information Storage Zou, Chen; Zheng, Jiajiu; Chang, Cheng Advanced Optical Materials, Vol. 7, Issue 18 https://doi.org/10.1002/adom.201900558	journal	May 2019
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Towards the scale-up of the formation of nanoparticles on α-Ag2WO4 with bactericidal properties by femtosecond laser irradiation Assis, Marcelo; Cordoncillo, Eloisa; Torres-Mendieta, Rafael Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-19270-9	journal	January 2018
Perovskite-based photodetectors: materials and devices Wang, Huan; Kim, Dong Ha Chemical Society Reviews, Vol. 46, Issue 17 https://doi.org/10.1039/c6cs00896h	journal	January 2017
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