Two-stage spin transition of iron in FeAl-bearing phase D at lower mantle

Wu, Xiang; Wu, Ye; Lin, Jung-Fu; Liu, Jin; Mao, Zhu; Guo, Xinzhuan; Yoshino, Takashi; McCammon, Catherine; Prakapenka, Vitali B.; Xiao, Yuming

doi:10.1002/2016JB013209

Title: Two-stage spin transition of iron in FeAl-bearing phase D at lower mantle

Journal Article · Sat Sep 17 00:00:00 EDT 2016 · Journal of Geophysical Research. Solid Earth

DOI:https://doi.org/10.1002/2016JB013209· OSTI ID:1331674

Wu, Xiang ^[1]; Wu, Ye ^[2]; Lin, Jung-Fu ^[3]; Liu, Jin ^[4]; Mao, Zhu ^[5]; Guo, Xinzhuan ^[6]; Yoshino, Takashi ^[7]; McCammon, Catherine ^[8]; Prakapenka, Vitali B. ^[9]; Xiao, Yuming ^[10]

China Univ. of Geosciences, Wuhan (China); Peking Univ. (China)
Peking Univ. (China)
Univ. of Texas, Austin, TX (United States); Center for High Pressure Science and Technology Advanced Research, Shanghai (China)
Univ. of Texas, Austin, TX (United States)
Univ. of Science and Technology of China, Hefei (China)
China Univ. of Geosciences, Wuhan (China); Okayama Univ., Tottori (Japan)
Okayama Univ., Tottori (Japan)
Univ. Bayreuth (Germany)
Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources (CARS)
Carnegie Inst. of Science, Washington, DC (United States). Geophysical Lab., HPCAT

Hydrous magnesium silicate phase D plays a key role in the transport of water from the upper to the lower mantle via subducted slabs. Here we report pressure dependence hyperfine and lattice parameters of FeAl-bearing phase D up to megabar pressures using synchrotron nuclear forward scattering and X-ray diffraction in a diamond anvil cell at room temperature. We report FeAl-bearing phase D undergoes a two-stage high-spin to low-spin transition of iron for Fe²⁺ at 37–41 GPa and for Fe³⁺ at 64–68 GPa. These transitions are accompanied by an increase in density and a significant softening in the bulk modulus and bulk velocity at their respective pressure range. The occurrence of the dense low-spin FeAl-bearing phase D with relatively high velocity anisotropies in deep-subducted slabs can potentially contribute to small-scale seismic heterogeneities in the middle-lower mantle beneath the circum-Pacific area.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); National Science Foundation of China (NSFC); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; NA0001974; FG02-99ER45775; U1232204; 41473056

OSTI ID:: 1331674

Journal Information:: Journal of Geophysical Research. Solid Earth, Vol. 121, Issue 9; ISSN 2169-9313

Publisher:: American Geophysical UnionCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 12 works

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