In situ solid-state electrochemistry of mass-selected ions at well-defined electrode–electrolyte interfaces

Prabhakaran, Venkateshkumar; Johnson, Grant E.; Wang, Bingbing; Laskin, Julia

doi:10.1073/pnas.1608730113

In situ solid-state electrochemistry of mass-selected ions at well-defined electrode–electrolyte interfaces

Journal Article · Mon Nov 07 00:00:00 EST 2016 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1608730113· OSTI ID:1331219

^[1]; Johnson, Grant E. ^[1]; Wang, Bingbing ^[2]; Laskin, Julia ^[1]

Physical Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352,
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352

Significance

In situ characterization of kinetics at electrode–electrolyte interfaces (EEIs) is crucial to the rational design of efficient and sustainable solid-state electrochemical technologies. A significant advancement has been made to rationally understand processes at EEIs using solid-state in situ thin-film electrochemical cells fabricated using specially designed ionic liquid membranes with excellent mass-transfer properties. The in situ cells are used to characterize well-defined EEIs generated using ion soft-landing (SL) in controlled environments, both in vacuum and in the presence of reactant gases. Populating EEIs with precisely defined electroactive species using SL facilitates molecular-level understanding of electron transfer processes within deposited species and between species and electrodes, thus providing a powerful methodology to characterize technologically relevant EEIs during operation.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1331219

Alternate ID(s):: OSTI ID: 1339859

Report Number(s):: PNNL-SA--118405

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 47 Vol. 113; ISSN 0027-8424

Publisher:: Proceedings of the National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

References (40)

Probing Operating Electrochemical Interfaces by Photons and Neutrons Itkis, Daniil M.; Velasco-Velez, Juan Jesus; Knop-Gericke, Axel ChemElectroChem, Vol. 2, Issue 10 https://doi.org/10.1002/celc.201500155	journal	September 2015
Preparation of Surface Organometallic Catalysts by Gas-Phase Ligand Stripping and Reactive Landing of Mass-Selected Ions Johnson, Grant E.; Laskin, Julia Chemistry - A European Journal, Vol. 16, Issue 48 https://doi.org/10.1002/chem.201002292	journal	November 2010
Soft- and reactive landing of ions onto surfaces: Concepts and applications: CONCEPTS AND APPLICATIONS Johnson, Grant E.; Gunaratne, Don; Laskin, Julia Mass Spectrometry Reviews, Vol. 35, Issue 3 https://doi.org/10.1002/mas.21451	journal	April 2015
Electrospray Ion Beam Deposition of Clusters and Biomolecules Rauschenbach, Stephan; Stadler, Frank L.; Lunedei, Eugenio Small, Vol. 2, Issue 4, p. 540-547 https://doi.org/10.1002/smll.200500479	journal	April 2006
Characterization of the Ion Beam Focusing in a Mass Spectrometer Using an IonCCD™ Detector Johnson, Grant E.; Hadjar, Omar; Laskin, Julia Journal of The American Society for Mass Spectrometry, Vol. 22, Issue 8 https://doi.org/10.1007/s13361-011-0154-4	journal	May 2011
Gas-Phase Fragmentation Pathways of Mixed Addenda Keggin Anions: PMo12-nWnO40 3– (n = 0–12) Gunaratne, K. Don D.; Prabhakaran, Venkateshkumar; Johnson, Grant E. Journal of The American Society for Mass Spectrometry, Vol. 26, Issue 6 https://doi.org/10.1007/s13361-015-1090-5	journal	April 2015
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35 https://doi.org/10.1016/j.apcatb.2004.06.021	journal	March 2005
Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy Wibowo, Rahmat; Aldous, Leigh; Jacobs, Robert M. J. Chemical Physics Letters, Vol. 509, Issue 1-3 https://doi.org/10.1016/j.cplett.2011.04.071	journal	June 2011
Soft landing of mass-selected gold clusters: Influence of ion and ligand on charge retention and reactivity Johnson, Grant E.; Laskin, Julia International Journal of Mass Spectrometry, Vol. 377 https://doi.org/10.1016/j.ijms.2014.05.013	journal	February 2015
Nanostructured Electrolytes for Stable Lithium Electrodeposition in Secondary Batteries Tu, Zhengyuan; Nath, Pooja; Lu, Yingying Accounts of Chemical Research, Vol. 48, Issue 11 https://doi.org/10.1021/acs.accounts.5b00427	journal	October 2015
Soft Landing of Complex Ions for Studies in Catalysis and Energy Storage Laskin, Julia; Johnson, Grant E.; Prabhakaran, Venkateshkumar The Journal of Physical Chemistry C, Vol. 120, Issue 41 https://doi.org/10.1021/acs.jpcc.6b06497	journal	September 2016
Low-Energy Ionic Collisions at Molecular Solids Cyriac, Jobin; Pradeep, T.; Kang, H. Chemical Reviews, Vol. 112, Issue 10, p. 5356-5411 https://doi.org/10.1021/cr200384k	journal	June 2012
Electrochemical Properties of Polyoxometalates as Electrocatalysts Sadakane, Masahiro; Steckhan, Eberhard Chemical Reviews, Vol. 98, Issue 1 https://doi.org/10.1021/cr960403a	journal	February 1998
Oxygen Reduction on Platinum Low-Index Single-Crystal Surfaces in Sulfuric Acid Solution: Rotating Ring-Pt(hkl) Disk Studies Markovic, Nenad M.; Gasteiger, Hubert A.; Ross, Philip N. The Journal of Physical Chemistry, Vol. 99, Issue 11, p. 3411-3415 https://doi.org/10.1021/j100011a001	journal	March 1995
The electrode/electrolyte interface - a status report Bard, Allen J.; Abruna, Hector D.; Chidsey, Chris E. The Journal of Physical Chemistry, Vol. 97, Issue 28 https://doi.org/10.1021/j100130a007	journal	July 1993
Electronic structure and redox mechanism of dodecamolybdophosphate Taketa, Hiroshi; Katsuki, Sinichi; Eguchi, Koichi The Journal of Physical Chemistry, Vol. 90, Issue 13 https://doi.org/10.1021/j100404a034	journal	June 1986
In Operando X-ray Absorption Fine Structure Studies of Polyoxometalate Molecular Cluster Batteries: Polyoxometalates as Electron Sponges Wang, Heng; Hamanaka, Shun; Nishimoto, Yoshio Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja2117206	journal	March 2012
Strong Effects of Cluster Size and Air Exposure on Oxygen Reduction and Carbon Oxidation Electrocatalysis by Size-Selected Pt _n ( n ≤ 11) on Glassy Carbon Electrodes Proch, Sebastian; Wirth, Mark; White, Henry S. Journal of the American Chemical Society, Vol. 135, Issue 8 https://doi.org/10.1021/ja309868z	journal	February 2013
New Perspectives on the Charging Mechanisms of Supercapacitors Forse, Alexander C.; Merlet, Céline; Griffin, John M. Journal of the American Chemical Society, Vol. 138, Issue 18 https://doi.org/10.1021/jacs.6b02115	journal	April 2016
Molecular and Electronic Structures, Brönsted Basicities, and Lewis Acidities of Group VIB Transition Metal Oxide Clusters Li, Shenggang; Dixon, David A. The Journal of Physical Chemistry A, Vol. 110, Issue 19 https://doi.org/10.1021/jp060735b	journal	May 2006
Oxygen Reduction Reaction in Ionic Liquids: The Addition of Protic Species Switzer, Elise E.; Zeller, Robert; Chen, Qing The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp400845u	journal	April 2013
Oxygen Reduction Reaction in Room Temperature Protic Ionic Liquids Khan, Asim; Lu, Xunyu; Aldous, Leigh The Journal of Physical Chemistry C, Vol. 117, Issue 36 https://doi.org/10.1021/jp405759j	journal	August 2013
Controlling the Charge State and Redox Properties of Supported Polyoxometalates via Soft Landing of Mass-Selected Ions Gunaratne, K. Don D.; Johnson, Grant E.; Andersen, Amity The Journal of Physical Chemistry C, Vol. 118, Issue 48 https://doi.org/10.1021/jp505050m	journal	October 2014
Cluster Size Controls Branching between Water and Hydrogen Peroxide Production in Electrochemical Oxygen Reduction at Pt _n /ITO von Weber, Alexander; Baxter, Eric T.; White, Henry S. The Journal of Physical Chemistry C, Vol. 119, Issue 20 https://doi.org/10.1021/jp5119234	journal	January 2015
Voltammetric Characterization of the Ferrocene\|Ferrocenium and Cobaltocenium\|Cobaltocene Redox Couples in RTILs Rogers, Emma I.; Silvester, Debbie S.; Poole, Darren L. The Journal of Physical Chemistry C, Vol. 112, Issue 7 https://doi.org/10.1021/jp710134e	journal	February 2008
Determination of the Diffusion Coefficient of Protons in Nafion Thin Films by ac -Electrogravimetry Sel, Ozlem; To Thi Kim, L.; Debiemme-Chouvy, Catherine Langmuir, Vol. 29, Issue 45 https://doi.org/10.1021/la401453e	journal	October 2013
Ionic liquids and their solid-state analogues as materials for energy generation and storage MacFarlane, Douglas R.; Forsyth, Maria; Howlett, Patrick C. Nature Reviews Materials, Vol. 1, Issue 2 https://doi.org/10.1038/natrevmats.2015.5	journal	January 2016
Decoupling hydrogen and oxygen evolution during electrolytic water splitting using an electron-coupled-proton buffer Symes, Mark D.; Cronin, Leroy Nature Chemistry, Vol. 5, Issue 5 https://doi.org/10.1038/nchem.1621	journal	April 2013
Rational design of efficient electrode–electrolyte interfaces for solid-state energy storage using ion soft landing Prabhakaran, Venkateshkumar; Mehdi, B. Layla; Ditto, Jeffrey J. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11399	journal	April 2016
Soft landing of bare nanoparticles with controlled size, composition, and morphology Johnson, Grant E.; Colby, Robert; Laskin, Julia Nanoscale, Vol. 7, Issue 8 https://doi.org/10.1039/C4NR06758D	journal	January 2015
Design and performance of a high-flux electrospray ionization source for ion soft landing Gunaratne, K. Don D.; Prabhakaran, Venkateshkumar; Ibrahim, Yehia M. The Analyst, Vol. 140, Issue 9 https://doi.org/10.1039/C5AN00220F	journal	January 2015
Soft landing of bare PtRu nanoparticles for electrochemical reduction of oxygen Johnson, Grant E.; Colby, Robert; Engelhard, Mark Nanoscale, Vol. 7, Issue 29 https://doi.org/10.1039/C5NR03154K	journal	January 2015
Differential capacitance of the double layer at the electrode/ionic liquids interface Lockett, Vera; Horne, Mike; Sedev, Rossen Physical Chemistry Chemical Physics, Vol. 12, Issue 39 https://doi.org/10.1039/c0cp00170h	journal	January 2010
Soft-landing preparative mass spectrometry Verbeck, Guido; Hoffmann, William; Walton, Barbara The Analyst, Vol. 137, Issue 19 https://doi.org/10.1039/c2an35550g	journal	January 2012
Structure, properties and reactivity of polyoxometalates: a theoretical perspective López, Xavier; Carbó, Jorge J.; Bo, Carles Chemical Society Reviews, Vol. 41, Issue 22 https://doi.org/10.1039/c2cs35168d	journal	January 2012
Collisions of ions with surfaces at chemically relevant energies: Instrumentation and phenomena Grill, Verena; Shen, Jianwei; Evans, Chris Review of Scientific Instruments, Vol. 72, Issue 8 https://doi.org/10.1063/1.1382641	journal	August 2001
Carbon-based electrocatalysts for advanced energy conversion and storage Zhang, Jintao; Xia, Zhenhai; Dai, Liming Science Advances, Vol. 1, Issue 7 https://doi.org/10.1126/sciadv.1500564	journal	August 2015
In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode Huang, J. Y.; Zhong, L.; Wang, C. M. Science, Vol. 330, Issue 6010, p. 1515-1520 https://doi.org/10.1126/science.1195628	journal	December 2010
Soft Landing of Complex Molecules on Surfaces Johnson, Grant E.; Hu, Qichi; Laskin, Julia Annual Review of Analytical Chemistry, Vol. 4, Issue 1, p. 83-104 https://doi.org/10.1146/annurev-anchem-061010-114028	journal	July 2011
Overview of Electrochemical Energy Storage and Conversion Shen, Pei Kang; Wang, Chao-Yang; Ping, San Electrochemical Energy https://doi.org/10.1201/b19061-2	book	December 2015

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In situ solid-state electrochemistry of mass-selected ions at well-defined electrode–electrolyte interfaces

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