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Title: SHINE and Mini-SHINE Column Designs for Recovery of Mo from 140 g-U/L Uranyl Sulfate

Abstract

Argonne is assisting SHINE Medical Technologies (SHINE) in their efforts to develop an accelerator-driven process that utilizes a uranyl-sulfate solution for the production of fission Mo-99. In an effort to design a Mo-recovery system for the SHINE project using low-enriched uranium (LEU), we conducted batch, breakthrough, and pulse tests to determine the Mo isotherm, mass-transfer zone (MTZ), and system parameters for a 130 g-U/L uranyl sulfate solution at pH 1 and 80°C, as described previously. The VERSE program was utilized to calculate the MTZ under various loading times and velocities. The results were then used to design Mo separation and recovery columns employing a pure titania sorbent (110-μm particles, S110, and 60 Å pore size). The plant-scale column designs assume Mo will be separated from 271 L of a 141 g-U/L uranyl sulfate solution, pH 1, containing 0.0023 mM Mo. The VERSE-designed recovery systems have been tested and verified in laboratory-scale experiments, and this approach was found to be very successful.

Authors:
 [1];  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation (NA-20)
OSTI Identifier:
1330563
Report Number(s):
ANL/NE-16/11
129607; TRN: US1700448
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 43 PARTICLE ACCELERATORS; MATERIALS RECOVERY; URANYL SULFATES; SLIGHTLY ENRICHED URANIUM; MOLYBDENUM 99; DESIGN; MASS TRANSFER; TITANIUM OXIDES; ISOTHERMS; TEMPERATURE RANGE 0273-0400 K; FISSION; LOADING; BENCH-SCALE EXPERIMENTS; ACCELERATORS; PULSES; VELOCITY; ZONES; EXTRACTION COLUMNS; Mo-99; SHINE

Citation Formats

Stepinski, Dominique C., and Vandegrift, George F. SHINE and Mini-SHINE Column Designs for Recovery of Mo from 140 g-U/L Uranyl Sulfate. United States: N. p., 2016. Web. doi:10.2172/1330563.
Stepinski, Dominique C., & Vandegrift, George F. SHINE and Mini-SHINE Column Designs for Recovery of Mo from 140 g-U/L Uranyl Sulfate. United States. doi:10.2172/1330563.
Stepinski, Dominique C., and Vandegrift, George F. Thu . "SHINE and Mini-SHINE Column Designs for Recovery of Mo from 140 g-U/L Uranyl Sulfate". United States. doi:10.2172/1330563. https://www.osti.gov/servlets/purl/1330563.
@article{osti_1330563,
title = {SHINE and Mini-SHINE Column Designs for Recovery of Mo from 140 g-U/L Uranyl Sulfate},
author = {Stepinski, Dominique C. and Vandegrift, George F.},
abstractNote = {Argonne is assisting SHINE Medical Technologies (SHINE) in their efforts to develop an accelerator-driven process that utilizes a uranyl-sulfate solution for the production of fission Mo-99. In an effort to design a Mo-recovery system for the SHINE project using low-enriched uranium (LEU), we conducted batch, breakthrough, and pulse tests to determine the Mo isotherm, mass-transfer zone (MTZ), and system parameters for a 130 g-U/L uranyl sulfate solution at pH 1 and 80°C, as described previously. The VERSE program was utilized to calculate the MTZ under various loading times and velocities. The results were then used to design Mo separation and recovery columns employing a pure titania sorbent (110-μm particles, S110, and 60 Å pore size). The plant-scale column designs assume Mo will be separated from 271 L of a 141 g-U/L uranyl sulfate solution, pH 1, containing 0.0023 mM Mo. The VERSE-designed recovery systems have been tested and verified in laboratory-scale experiments, and this approach was found to be very successful.},
doi = {10.2172/1330563},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {9}
}

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