Turning the halide switch in the synthesis of Au–Pd alloy and core–shell nanoicosahedra with terraced shells: Performance in electrochemical and plasmon-enhanced catalysis

Hsu, Shih -Cheng; Chuang, Yu -Chun; Sneed, Brian T.; Cullen, David A.; Chiu, Te -Wei; Kuo, Chun -Hong

doi:10.1021/acs.nanolett.6b02005

Turning the halide switch in the synthesis of Au–Pd alloy and core–shell nanoicosahedra with terraced shells: Performance in electrochemical and plasmon-enhanced catalysis

Journal Article · Fri Jan 01 00:00:00 EST 2016 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.6b02005· OSTI ID:1330559

Hsu, Shih -Cheng ^[1]; Chuang, Yu -Chun ^[2]; Sneed, Brian T. ^[3]; Cullen, David A. ^[3]; Chiu, Te -Wei ^[4]; Kuo, Chun -Hong ^[5]

Academia Sinica, Taipei (Taiwan); National Taipei Univ. of Technology, Taipei (Taiwan)
National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Taipei Univ. of Technology, Taipei (Taiwan)
Academia Sinica, Taipei (Taiwan)

Au Pd nanocrystals are an intriguing system to study the integrated functions of localized surface plasmon resonance (LSPR) and heterogeneous catalysis. Gold is both durable and can harness incident light energy to enhance the catalytic activity of another metal, such as Pd, via the SPR effect in bimetallic nanocrystals. Despite the superior catalytic performance of icosahedral (IH) nanocrystals compared to alternate morphologies, the controlled synthesis of alloy and core shell IH is still greatly challenged by the disparate reduction rates of metal precursors and lack of continuous epigrowth on multiply twinned boundaries of such surfaces. Herein, we demonstrate a one-step strategy for the controlled growth of monodisperse Au Pd alloy and core shell IH with terraced shells by turning an ionic switch between [Br ]/[Cl^–] in the coreduction process. The core shell IH nanocrystals contain AuPd alloy cores and ultrathin Pd shells (<2 nm). They not only display more than double the activity of the commercial Pd catalysts in ethanol electrooxidation attributed to monatomic step terraces but also show SPR-enhanced conversion of 4-nitrophenol. Furthermore, this strategy holds promise toward the development of alternate bimetallic IH nanocrystals for electrochemical and plasmon-enhanced catalysis.

View Accepted Manuscript (DOE)

Research Organization:: Nuclear Science User Facility (NSUF); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1330559

Journal Information:: Nano Letters, Journal Name: Nano Letters Journal Issue: 9 Vol. 16; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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