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Influence of phase connectivity on the relationship among capillary pressure, fluid saturation, and interfacial area in two-fluid-phase porous medium systems

Journal Article · · Physical Review E
 [1];  [2];  [3];  [3]
  1. Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Univ. of North Carolina, Chapel Hill, NC (United States)

Here, multiphase flow in porous medium systems is typically modeled using continuum mechanical representations at the macroscale in terms of averaged quantities. These models require closure relations to produce solvable forms. One of these required closure relations is an expression relating fluid pressures, fluid saturations, and, in some cases, the interfacial area between the fluid phases, and the Euler characteristic. An unresolved question is whether the inclusion of these additional morphological and topological measures can lead to a non-hysteretic closure relation compared to the hysteretic forms that are used in traditional models, which typically do not include interfacial areas, or the Euler characteristic. We develop a lattice-Boltzmann (LB) simulation approach to investigate the equilibrium states of a two-fluid-phase porous medium system, which include disconnected now- wetting phase features. The proposed approach is applied to a synthetic medium consisting of 1,964 spheres arranged in a random, non-overlapping, close-packed manner, yielding a total of 42,908 different equilibrium points. This information is evaluated using a generalized additive modeling approach to determine if a unique function from this family exists, which can explain the data. The variance of various model estimates is computed, and we conclude that, except for the limiting behavior close to a single fluid regime, capillary pressure can be expressed as a deterministic and non-hysteretic function of fluid saturation, interfacial area between the fluid phases, and the Euler characteristic. This work is unique in the methods employed, the size of the data set, the resolution in space and time, the true equilibrium nature of the data, the parameterizations investigated, and the broad set of functions examined. The conclusion of essentially non-hysteretic behavior provides support for an evolving class of two-fluid-phase flow in porous medium systems models.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1330524
Alternate ID(s):
OSTI ID: 1315862
Journal Information:
Physical Review E, Journal Name: Physical Review E Journal Issue: 3 Vol. 94; ISSN PLEEE8; ISSN 2470-0045
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English

References (96)

On the dynamics and kinematics of two‐fluid‐phase flow in porous media journal July 2015
Pore-scale displacement mechanisms as a source of hysteresis for two-phase flow in porous media: FLUID TOPOLOGY journal March 2016
Trapping and hysteresis in two-phase flow in porous media: A pore-network study: Trapping and Hysteresis in Two-Phase Flow journal July 2013
A level set method for simulating capillary-controlled displacements at the pore scale with nonzero contact angles: Level Set Simulation of Capillary Displacement journal August 2013
Modeling Groundwater Flow and Contaminant Transport book January 2010
Introduction to the Thermodynamically Constrained Averaging Theory for Porous Medium Systems book January 2014
Lattice Boltzmann method for microfluidics: models and applications journal April 2010
Image analysis algorithms for estimating porous media multiphase flow variables from computed microtomography data: a validation study journal February 2009
Straightforward intermediate rank tensor product smoothing in mixed models journal February 2012
Insights into the Relationships Among Capillary Pressure, Saturation, Interfacial Area and Relative Permeability Using Pore-Network Modeling journal December 2007
New Trapping Mechanism in Carbon Sequestration journal August 2009
Capillary Pressure Curve for Liquid Menisci in a Cubic Assembly of Spherical Particles Below Irreducible Saturation journal March 2011
Uniqueness of Specific Interfacial Area–Capillary Pressure–Saturation Relationship Under Non-Equilibrium Conditions in Two-Phase Porous Media Flow journal February 2012
The influence of porous medium characteristics and measurement scale on pore-scale distributions of residual nonaqueous-phase liquids journal November 1992
Toward an improved description of the physics of two-phase flow journal January 1993
Investigation of the residual–funicular nonwetting-phase-saturation relation journal November 2000
Modeling support of functional relationships between capillary pressure, saturation, interfacial area and common lines journal February 2001
Wettability alteration in carbonates journal April 2003
Pore-scale characteristics of multiphase flow in porous media: A comparison of air–water and oil–water experiments journal February 2006
Approximation of interfacial properties in multiphase porous medium systems journal March 2007
Impact of geometrical properties on permeability and fluid phase distribution in porous media journal September 2008
Lattice-Boltzmann simulations of the capillary pressure–saturation–interfacial area relationship for porous media journal November 2009
On the reconstruction of structural and functional properties in random heterogeneous media journal February 2011
Pore-scale imaging and modelling journal January 2013
X-ray imaging and analysis techniques for quantifying pore-scale structure and processes in subsurface porous medium systems journal January 2013
Effect of fluid topology on residual nonwetting phase trapping: Implications for geologic CO2 sequestration journal December 2013
Quantification of soil structure based on Minkowski functions journal October 2010
Recent developments on carbon capture and storage: An overview journal September 2011
Characterisation of irregular spatial structures by parallel sets and integral geometric measures journal July 2004
A novel heterogeneous algorithm to simulate multiphase flow in porous media on multicore CPU–GPU systems journal July 2014
Computational modelling of polymer electrolyte membrane (PEM) fuel cells: Challenges and opportunities journal April 2007
Extraction of physically realistic pore network properties from three-dimensional synchrotron X-ray microtomography images of unconsolidated porous media systems journal January 2005
A critical review of two-phase flow in gas flow channels of proton exchange membrane fuel cells journal August 2010
Tracking interface and common curve dynamics for two-fluid flow in porous media journal April 2016
Wettability Changes in Trichloroethylene-Contaminated Sandstone journal April 2001
Measuring Air−Water Interfacial Areas with X-ray Microtomography and Interfacial Partitioning Tracer Tests journal March 2007
Review on Scale Dependent Characterization of the Microstructure of Porous Media journal January 2002
Pore-scale modeling extension of constitutive relationships in the range of residual saturations journal January 2001
Linking pressure and saturation through interfacial areas in porous media journal January 2004
A comparison of geographical information systems-based algorithms for computing the TOPMODEL topographic index: A COMPARISON OF TOPOGRAPHIC INDEX ALGORITHMS journal June 2004
Interfacial area measurements for unsaturated flow through a porous medium: INTERFACIAL AREA MEASUREMENTS journal December 2004
Biodegradation during contaminant transport in porous media: 8. The influence of microbial system variability on transport behavior and parameter determination: INFLUENCE OF MICROBIAL VARIABILITY ON CO journal April 2006
Comparison of pressure-saturation characteristics derived from computed tomography and lattice Boltzmann simulations: TOMOGRAPHY AND LB PRESSURE-SATURATION journal December 2007
Measurement and prediction of the relationship between capillary pressure, saturation, and interfacial area in a NAPL-water-glass bead system: CAPILLARY PRESSURE, SATURATION, AND IFA journal August 2010
Network model investigation of interfacial area, capillary pressure and saturation relationships in granular porous media: NEW NETWORK MODEL FOR CAPILLARY FLOW journal June 2010
Specific interfacial area: The missing state variable in two-phase flow equations?: INVESTIGATION OF EXTENDED DARCY'S LAW journal May 2011
Visualization of residual organic liquid trapped in aquifers journal February 1992
Pore-Scale Modeling of Nonwetting-Phase Residual in Porous Media journal March 1995
A Functional Relationship Between Capillary Pressure, Saturation, and Interfacial Area as Revealed by a Pore-Scale Network Model journal August 1996
Air-Water Interfacial Area and Capillary Pressure: Porous-Medium Texture Effects and an Empirical Function journal July 2012
Earthquake triggering and large-scale geologic storage of carbon dioxide journal June 2012
Real-time 3D imaging of Haines jumps in porous media flow journal February 2013
Dynamic network modeling of two-phase drainage in porous media journal January 2005
Three-dimensional mixed-wet random pore-scale network modeling of two- and three-phase flow in porous media. I. Model description journal February 2005
Two-phase flow in porous media: Crossover from capillary fingering to compact invasion for drainage journal February 2005
Macroscopic capillarity and hysteresis for flow in porous media journal January 2006
Cluster evolution in steady-state two-phase flow in porous media journal February 2006
Prediction of fluid occupancy in fractures using network modeling and x-ray microtomography. I: Data conditioning and model description journal July 2007
Prediction of fluid occupancy in fractures using network modeling and x-ray microtomography. II: Results journal July 2007
Distribution of multiphase fluids in porous media: Comparison between lattice Boltzmann modeling and micro-x-ray tomography journal February 2008
Characteristic lengths affecting evaporative drying of porous media journal May 2008
Pore-scale studies of spontaneous imbibition into oil-saturated porous media journal June 2008
Effect of pore structure on capillary condensation in a porous medium journal February 2009
Steady-state, simultaneous two-phase flow in porous media: An experimental study journal September 2009
Influence of wetting conditions on drainage in porous media: A microfluidic study journal August 2011
Generalized nonequilibrium capillary relations for two-phase flow through heterogeneous media journal January 2012
Pore-scale evaporation-condensation dynamics resolved by synchrotron x-ray tomography journal January 2012
Impact of structured heterogeneities on reactive two-phase porous flow journal September 2012
Microfluidics of imbibition in random porous media journal February 2013
Pore-scale modeling of multiphase reactive transport with phase transitions and dissolution-precipitation processes in closed systems journal April 2013
Pore-scale micro-computed-tomography imaging: Nonwetting-phase cluster-size distribution during drainage and imbibition journal September 2013
Interfacial velocities and capillary pressure gradients during Haines jumps journal October 2013
Interfacial dynamics of two immiscible fluids in spatially periodic porous media: The role of substrate wettability journal July 2014
History effects on nonwetting fluid residuals during desaturation flow through disordered porous media journal April 2015
Capillary saturation and desaturation journal December 2015
Finite-volume method with lattice Boltzmann flux scheme for incompressible porous media flow at the representative-elementary-volume scale journal February 2016
Lattice Boltzmann simulation of the gas-solid adsorption process in reconstructed random porous media journal April 2016
Dynamics of Drying in 3D Porous Media journal August 2008
Nonlocal Interface Dynamics and Pattern Formation in Gravity-Driven Unsaturated Flow through Porous Media journal December 2008
Steady-State Two-Phase Flow in Porous Media: Statistics and Transport Properties journal February 2009
Wettability Stabilizes Fluid Invasion into Porous Media via Nonlocal, Cooperative Pore Filling journal October 2015
Uniqueness of Reconstruction of Multiphase Morphologies from Two-Point Correlation Functions journal September 2002
On Concise 3-D Simple Point Characterizations: A Marching Cubes Paradigm journal January 2009
3D structural analysis: sensitivity of Minkowski functionals: 3D STRUCTURAL ANALYSIS: SENSITIVITY OF MINKOWSKI FUNCTIONALS journal November 2010
Fast stable direct fitting and smoothness selection for generalized additive models journal July 2008
Pore-scale analysis of trapped immiscible fluid structures and fluid interfacial areas in oil-wet and water-wet bead packs: Pore-scale analysis of trapped immiscible fluid structures journal April 2011
Generalized additive models for large data sets journal May 2014
A Critical Overview of Computational Fluid Dynamics Multiphase Models for Proton Exchange Membrane Fuel Cells journal January 2009
Integral Geometry in Statistical Physics journal April 1998
Modeling Fluid flow in oil Reservoirs journal January 2005
Magnitude and Detailed Structure of Residual Oil Saturation journal April 1983
Effect of Capillary Number on the Microstructure of Residual Oil in Strongly Water-Wet Sandstones journal August 1988
Entrapment and Mobilization of Residual Oil in Bead Packs journal August 1988
Capillary Behavior in Porous Solids journal December 1941
A Closed-form Equation for Predicting the Hydraulic Conductivity of Unsaturated Soils1 journal January 1980
Tomographical Imaging and Mathematical Description of Porous Media Used for the Prediction of Fluid Distribution journal January 2006

Cited By (11)

A linear constitutive model for unsaturated poroelasticity by micromechanical analysis journal December 2019
Porous Media Characterization Using Minkowski Functionals: Theories, Applications and Future Directions journal November 2018
Topological Persistence for Relating Microstructure and Capillary Fluid Trapping in Sandstones journal January 2019
The Impact of Pore-Scale Flow Regimes on Upscaling of Immiscible Two-Phase Flow in Porous Media journal September 2018
Relative Permeability Scaling From Pore‐Scale Flow Regimes journal April 2019
Pore‐Scale Modeling of Fluid‐Fluid Interfacial Area in Variably Saturated Porous Media Containing Microscale Surface Roughness journal January 2020
Geometric state function for two-fluid flow in porous media journal August 2018
On the consistency of scale among experiments, theory, and simulation text January 2017
Toward a New Generation of Two-Fluid Flow Models Based on the Thermodynamically-Constrained Averaging Theory journal October 2019
On the Consistency of Scale Among Experiments, Theory, and Simulation journal September 2016
On the consistency of scale among experiments, theory, and simulation journal January 2017

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