Using laser-induced thermal voxels to pattern diverse materials at the solid–liquid interface

Zarzar, Lauren D.; Swartzentruber, B. S.; Donovan, Brian F.; Hopkins, Patrick E.; Kaehr, Bryan

doi:10.1021/acsami.6b06625

Using laser-induced thermal voxels to pattern diverse materials at the solid–liquid interface

Journal Article · Fri Aug 05 00:00:00 EDT 2016 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.6b06625· OSTI ID:1330208

Zarzar, Lauren D. ^[1]; Swartzentruber, B. S. ^[2]; Donovan, Brian F. ^[3]; Hopkins, Patrick E. ^[3]; Kaehr, Bryan ^[4]

The Pennsylvania State Univ., University Park, PA (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Univ. of Virginia, Charlottesville, VA (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); The Univ. of New Mexico, Albuquerque, NM (United States)

We describe a high-resolution patterning approach that combines the spatial control inherent to laser direct writing with the versatility of benchtop chemical synthesis. By taking advantage of the steep thermal gradient that occurs while laser heating a metal edge in contact with solution, diverse materials comprising transition metals are patterned with feature size resolution nearing 1 μm. We demonstrate fabrication of reduced metallic nickel in one step and examine electrical properties and air stability through direct-write integration onto a device platform. In conclusion, this strategy expands the chemistries and materials that can be used in combination with laser direct writing.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1330208

Report Number(s):: SAND--2016-10660J; 648515

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 33 Vol. 8; ISSN 1944-8244

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Nanostructure and Mechanism of Metal Deposition by a Laser‐Induced Photothermal Reaction Greenberg, Ehud; Armon, Nina; Kapon, Omree Advanced Materials Interfaces, Vol. 6, Issue 14 https://doi.org/10.1002/admi.201900541	journal	May 2019
Simultaneous laser-induced synthesis and micro-patterning of a metal organic framework Armon, Nina; Greenberg, Ehud; Edri, Eitan Chemical Communications, Vol. 55, Issue 85 https://doi.org/10.1039/c9cc05990c	journal	January 2019
The laser writing of highly conductive and anti-oxidative copper structures in liquid Zhou, Xingwen; Guo, Wei; Zhu, Ying Nanoscale, Vol. 12, Issue 2 https://doi.org/10.1039/c9nr07248a	journal	January 2020
Substrate thermal conductivity controls the ability to manufacture microstructures via laser-induced direct write Tomko, John A.; Olson, David H.; Braun, Jeffrey L. Applied Physics Letters, Vol. 112, Issue 5 https://doi.org/10.1063/1.5016073	journal	January 2018
Flexible and rapid fabrication of silver microheaters with spatial-modulated multifoci by femtosecond laser multiphoton reduction Qian, Dongdong; Yang, Liang; Zhang, Yacao Optics Letters, Vol. 43, Issue 21 https://doi.org/10.1364/ol.43.005335	journal	January 2018

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Ni electrode
laser direct write
laser-induced heating
metals
microstructures
solvothermal synthesis

Using laser-induced thermal voxels to pattern diverse materials at the solid–liquid interface

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References (29)

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