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Title: Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries

Abstract

Here, we evaluate the utilities of fluorescence-yield (FY) modes in soft X-ray absorption spectroscopy (XAS) of several cathodematerials for Li-ion batteries. In the case of total-FY (TFY) XAS for LiNi 0.5Mn 1.5O 4, the line shape of the Mn L 3-edge XAS was largely distorted by the self-absorption and saturation effects, while the distortions were less pronounced at the Ni L 3 edge. The distortions were suppressed for the inverse-partial-FY (IPFY) spectra. We found that, in the cathodematerials, the IPFY XAS is highly effective for the Cr, Mn, and Fe L edges and the TFY and PFY modes are useful enough for the Ni L edge which is far from the O K edge.

Authors:
 [1];  [1];  [2];  [1];  [3];  [4];  [5];  [6];  [7];  [8];  [9]; ORCiD logo [9];  [10];  [11]
  1. National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan)
  2. National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan); Kyushu Univ., Fukuoka (Japan)
  3. The Univ. of Tokyo, Tokyo (Japan)
  4. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  5. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  6. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Santa Cruz, CA (United States)
  7. The Univ. of Tokyo, Chiba (Japan); Waseda Univ., Tokyo (Japan)
  8. Jilin Univ., Changchun (People's Republic of China)
  9. Univ. of Waterloo, Waterloo, ON (Canada)
  10. Univ. of Saskatchewan, Saskatoon, SK (Canada)
  11. The Univ. of Tokyo, Chiba (Japan)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
NREL Laboratory Directed Research and Development (LDRD); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1329991
Alternate Identifier(s):
OSTI ID: 1378978
Report Number(s):
NREL/JA-5900-67327
Journal ID: ISSN 2158-3226; AAIDBI
Grant/Contract Number:  
AC36-08GO28308; AC02-05CH11231
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 6; Journal Issue: 3; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; x-ray absorption spectroscopy; nickel; cathodes; emission spectra; electronic structure

Citation Formats

Asakura, Daisuke, Hosono, Eiji, Nanba, Yusuke, Zhou, Haoshen, Okabayashi, Jun, Ban, Chunmei, Glans, Per -Anders, Guo, Jinghua, Mizokawa, Takashi, Chen, Gang, Achkar, Andrew J., Hawthron, David G., Regier, Thomas Z., and Wadati, Hiroki. Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries. United States: N. p., 2016. Web. doi:10.1063/1.4943673.
Asakura, Daisuke, Hosono, Eiji, Nanba, Yusuke, Zhou, Haoshen, Okabayashi, Jun, Ban, Chunmei, Glans, Per -Anders, Guo, Jinghua, Mizokawa, Takashi, Chen, Gang, Achkar, Andrew J., Hawthron, David G., Regier, Thomas Z., & Wadati, Hiroki. Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries. United States. doi:10.1063/1.4943673.
Asakura, Daisuke, Hosono, Eiji, Nanba, Yusuke, Zhou, Haoshen, Okabayashi, Jun, Ban, Chunmei, Glans, Per -Anders, Guo, Jinghua, Mizokawa, Takashi, Chen, Gang, Achkar, Andrew J., Hawthron, David G., Regier, Thomas Z., and Wadati, Hiroki. Mon . "Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries". United States. doi:10.1063/1.4943673. https://www.osti.gov/servlets/purl/1329991.
@article{osti_1329991,
title = {Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries},
author = {Asakura, Daisuke and Hosono, Eiji and Nanba, Yusuke and Zhou, Haoshen and Okabayashi, Jun and Ban, Chunmei and Glans, Per -Anders and Guo, Jinghua and Mizokawa, Takashi and Chen, Gang and Achkar, Andrew J. and Hawthron, David G. and Regier, Thomas Z. and Wadati, Hiroki},
abstractNote = {Here, we evaluate the utilities of fluorescence-yield (FY) modes in soft X-ray absorption spectroscopy (XAS) of several cathodematerials for Li-ion batteries. In the case of total-FY (TFY) XAS for LiNi0.5Mn1.5O4, the line shape of the Mn L3-edge XAS was largely distorted by the self-absorption and saturation effects, while the distortions were less pronounced at the NiL3 edge. The distortions were suppressed for the inverse-partial-FY (IPFY) spectra. We found that, in the cathodematerials, the IPFY XAS is highly effective for the Cr, Mn, and Fe L edges and the TFY and PFY modes are useful enough for the NiL edge which is far from the O K edge.},
doi = {10.1063/1.4943673},
journal = {AIP Advances},
number = 3,
volume = 6,
place = {United States},
year = {Mon Mar 07 00:00:00 EST 2016},
month = {Mon Mar 07 00:00:00 EST 2016}
}

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Works referenced in this record:

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997

  • Padhi, A. K.
  • Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
  • DOI: 10.1149/1.1837571