Beyond Yolk–Shell Nanoparticles: Fe 3 O 4 @Fe 3 C Core@Shell Nanoparticles as Yolks and Carbon Nanospindles as Shells for Efficient Lithium Ion Storage

Zhang, Jianan; Wang, Kaixi; Xu, Qun; Zhou, Yunchun; Cheng, Fangyi; Guo, Shaojun

doi:10.1021/acsnano.5b00760

Title: Beyond Yolk–Shell Nanoparticles: Fe ₃ O ₄ @Fe ₃ C Core@Shell Nanoparticles as Yolks and Carbon Nanospindles as Shells for Efficient Lithium Ion Storage

Journal Article · Wed Feb 25 00:00:00 EST 2015 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.5b00760· OSTI ID:1329578

Zhang, Jianan ^[1]; Wang, Kaixi ^[1]; Xu, Qun ^[1]; Zhou, Yunchun ^[2]; Cheng, Fangyi ^[3]; Guo, Shaojun ^[4]

Zhengzhou Univ. (People Republic of China). College of Materials Science and Engineering
Chinese Academy of Sciences (CAS), Changchun (China). National Analytical Research Center of Electrochemistry and Spectroscopy
Nankai niv., Tianjin (People's Republic of China). Key Lab. of Advanced Energy Materials Chemistry
Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Physical Chemistry and Applied Spectroscopy

In order to well address the problems of large volume change and dissolution of Fe₃O₄ nanomaterials during Li⁺ intercalation/extraction, herein we demonstrate a one-step in situ nanospace-confined pyrolysis strategy for robust yolk–shell nanospindles with very sufficient internal void space (VSIVS) for high-rate and long-term lithium ion batteries (LIBs), in which an Fe₃O₄@Fe₃C core@shell nanoparticle is well confined in the compartment of a hollow carbon nanospindle. This structure can not only introduce VSIVS to accommodate volume change of Fe₃O₄ but also afford a dual shell of Fe₃C and carbon to restrict Fe₃O₄ dissolution, thus providing dual roles for greatly improving the capacity retention. Consequently, Fe₃O₄@Fe₃C–C yolk–shell nanospindles deliver a high reversible capacity of 1128.3 mAh g^–1 at even 500 mA g^–1, excellent high rate capacity (604.8 mAh g^–1 at 2000 mA g^–1), and prolonged cycling life (maintaining 1120.2 mAh g^–1 at 500 mA g^–1 for 100 cycles) for LIBs, which are much better than those of Fe₃O₄@C core@shell nanospindles and Fe₃O₄ nanoparticles. The present Fe₃O₄@Fe₃C–C yolk–shell nanospindles are the most efficient Fe₃O₄-based anode materials ever reported for LIBs.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1329578

Report Number(s):: LA-UR-15-21479

Journal Information:: ACS Nano, Vol. 9, Issue 3; ISSN 1936-0851

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 190 works

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Title: Beyond Yolk–Shell Nanoparticles: Fe 3 O 4 @Fe 3 C Core@Shell Nanoparticles as Yolks and Carbon Nanospindles as Shells for Efficient Lithium Ion Storage

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Title: Beyond Yolk–Shell Nanoparticles: Fe ₃ O ₄ @Fe ₃ C Core@Shell Nanoparticles as Yolks and Carbon Nanospindles as Shells for Efficient Lithium Ion Storage