Synthesis of a ferrolite: A zeolitic all-iron framework

Latshaw, Allison M.; Chance, W. Michael; Morrison, Gregory; zur Loye, Karl D.; Wilkins, Branford O.; Smith, Mark D.; Whitfield, Pamela S.; Kirkham, Melanie J.; Stoian, Sebastian A.; zur Loye, Hans -Conrad

doi:10.1002/anie.201607800

Title: Synthesis of a ferrolite: A zeolitic all-iron framework

Journal Article · Wed Sep 21 00:00:00 EDT 2016 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201607800· OSTI ID:1329145

Latshaw, Allison M. ^[1]; Chance, W. Michael ^[1]; Morrison, Gregory ^[1]; zur Loye, Karl D. ^[1]; Wilkins, Branford O. ^[1]; Smith, Mark D. ^[1]; Whitfield, Pamela S. ^[2]; Kirkham, Melanie J. ^[2]; Stoian, Sebastian A. ^[3];

^[1]

Univ. of South Carolina, Columbia, SC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Florida State Univ., Tallahassee, FL (United States)

Here, crystals of the first sodalite-type zeolite containing an all-iron framework, a ferrolite, Ba₈(Fe₁₂O₂₄)Na_y(OH)6 • xH₂O, were synthesized using the hydroflux method in nearly quantitative yield. Ba₈(Fe₁₂O₂₄)Na_y(OH)₆ • xH₂O crystallizes in the cubic space group _Pm3¯m with α = 10.0476(1) Å. Slightly distorted FeO₄ tetrahedra are linked to form Fe₄O₄ and Fe₆O₆ rings, which in turn yield channels and internal cavities that are characteristic of the sodalite structure. Barium, sodium, and hydroxide ions and water molecules are found in the channels and provide charge balance. Magnetic measurements indicate that the ferrolite exhibits magnetic order up to at least 700 K, with the field-cooled and zero-field-cooled curves diverging. Analysis of the ⁵⁷Fe Mossbauer spectra revealed two spectral components that have equal spectral areas, indicating the presence of two subsets of iron centers in the structure. Dehydrated versions of the ferrolite were also prepared by heating the sample.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1329145

Journal Information:: Angewandte Chemie (International Edition), Vol. 55, Issue 42; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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