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Energetics and Solvation Effects at the Photoanode/Catalyst Interface: Ohmic Contact versus Schottky Barrier

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.5b00798· OSTI ID:1328817
 [1];  [2];  [3]
  1. Joint Center for Artificial Photosynthesis, California Institute of Technology and Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
  2. Joint Center for Artificial Photosynthesis, California Institute of Technology and Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States, Materials and Process Simulation Center, California Institute of Technology, Pasadena, California 91125, United States
  3. Institute for Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States, Argonne National Laboratory, Lemont, Illinois 60439, United States
Not Available
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States); California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
Grant/Contract Number:
AC02-06CH11357; SC0004993
OSTI ID:
1328817
Alternate ID(s):
OSTI ID: 1391705
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 16 Vol. 137; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

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Water Oxidation at Hematite Photoelectrodes with an Iridium-Based Catalyst journal February 2013
Optimizing the Band Edges of Tungsten Trioxide for Water Oxidation: A First-Principles Study journal March 2014
Photoelectrochemical cells journal November 2001
Electrochemical deposition and photoelectrochemistry of CuWO4, a promising photoanode for water oxidation journal January 2011
Improving O2 production of WO3 photoanodes with IrO2 in acidic aqueous electrolyte journal January 2014
Effect of growth conditions on surface morphology and photoelectric work function characteristics of iridium oxide thin films journal March 1999
Role of the deep-lying electronic states of MoO3 in the enhancement of hole-injection in organic thin films journal September 2009
Charge generation layers comprising transition metal-oxide/organic interfaces: Electronic structure and charge generation mechanism journal May 2010
The charge-asymmetric nonlocally determined local-electric (CANDLE) solvation model journal February 2015
Two-photon photoemission spectroscopy of Ti O 2 ( 110 ) surfaces modified by defects and O 2 or H 2 O adsorbates journal July 2004
Atomic and electronic structures of nano- and amorphous CdS/Pt interfaces journal December 2010
Optical properties of tungsten trioxide from first-principles calculations journal April 2013
Schottky Barrier Heights and the Continuum of Gap States journal February 1984
Role of virtual gap states and defects in metal-semiconductor contacts journal March 1987
Photochemical and Photoelectrochemical Reduction of CO 2 journal May 2012

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