Fabrication of efficient low-bandgap perovskite solar cells by combining formamidinium tin iodide with methylammonium lead iodide

Liao, Weiqiang; Zhao, Dewei; Yu, Yue; Shrestha, Niraj; Ghimire, Kiran; Grice, Corey R.; Wang, Changlei; Xiao, Yuqing; Cimaroli, Alexander J.; Ellingson, Randy J.; Podraza, Nikolas J.; Zhu, Kai; Xiong, Ren -Gen; Yan, Yanfa

doi:10.1021/jacs.6b08337

Fabrication of efficient low-bandgap perovskite solar cells by combining formamidinium tin iodide with methylammonium lead iodide

Journal Article · Tue Sep 13 00:00:00 EDT 2016 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.6b08337· OSTI ID:1328732

Liao, Weiqiang ^[1]; Zhao, Dewei ^[2]; Yu, Yue ^[2]; Shrestha, Niraj ^[2]; Ghimire, Kiran ^[2]; Grice, Corey R. ^[2]; Wang, Changlei ^[3]; Xiao, Yuqing ^[4]; Cimaroli, Alexander J. ^[2]; Ellingson, Randy J. ^[2]; Podraza, Nikolas J. ^[2]; Zhu, Kai ^[5]; Xiong, Ren -Gen ^[6]; Yan, Yanfa ^[2]

The Univ. of Toledo, Toledo, OH (United States); Southeast Univ., Nanjing (China)
The Univ. of Toledo, Toledo, OH (United States)
The Univ. of Toledo, Toledo, OH (United States); Wuhan Univ., Wuhan (China)
Wuhan Univ., Wuhan (China)
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Southeast Univ., Nanjing (China)

Mixed tin (Sn)-lead (Pb) perovskites with high Sn content exhibit low bandgaps suitable for fabricating the bottom cell of perovskite-based tandem solar cells. In this work, we report on the fabrication of efficient mixed Sn-Pb perovskite solar cells using precursors combining formamidinium tin iodide (FASnI₃) and methylammonium lead iodide (MAPbI₃). The best-performing cell fabricated using a (FASnI₃)_0.6(MAPbI₃)_0.4 absorber with an absorption edge of ~1.2 eV achieved a power conversion efficiency (PCE) of 15.08 (15.00)% with an open-circuit voltage of 0.795 (0.799) V, a short-circuit current density of 26.86(26.82) mA/cm², and a fill factor of 70.6(70.0)% when measured under forward (reverse) voltage scan. In conclusion, the average PCE of 50 cells we have fabricated is 14.39 ± 0.33%, indicating good reproducibility.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1328732

Report Number(s):: NREL/JA--5900-67260

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 38 Vol. 138; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Opportunities and challenges for tandem solar cells using metal halide perovskite semiconductors Leijtens, Tomas; Bush, Kevin A.; Prasanna, Rohit Nature Energy, Vol. 3, Issue 10 https://doi.org/10.1038/s41560-018-0190-4	journal	July 2018
Efficient two-terminal all-perovskite tandem solar cells enabled by high-quality low-bandgap absorber layers Zhao, Dewei; Chen, Cong; Wang, Changlei Nature Energy, Vol. 3, Issue 12 https://doi.org/10.1038/s41560-018-0278-x	journal	November 2018
Monolithic all-perovskite tandem solar cells with 24.8% efficiency exploiting comproportionation to suppress Sn(ii) oxidation in precursor ink Lin, Renxing; Xiao, Ke; Qin, Zhengyuan Nature Energy, Vol. 4, Issue 10 https://doi.org/10.1038/s41560-019-0466-3	journal	September 2019
Metal halide perovskite tandem and multiple-junction photovoltaics Eperon, Giles E.; Hörantner, Maximilian T.; Snaith, Henry J. Nature Reviews Chemistry, Vol. 1, Issue 12 https://doi.org/10.1038/s41570-017-0095	journal	November 2017
Tailoring metal halide perovskites through metal substitution: influence on photovoltaic and material properties Klug, Matthew T.; Osherov, Anna; Haghighirad, Amir A. Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/c6ee03201j	journal	January 2017
The rapid evolution of highly efficient perovskite solar cells Correa-Baena, Juan-Pablo; Abate, Antonio; Saliba, Michael Energy & Environmental Science, Vol. 10, Issue 3 https://doi.org/10.1039/c6ee03397k	journal	January 2017
High efficiency planar Sn–Pb binary perovskite solar cells: controlled growth of large grains via a one-step solution fabrication process Li, Lingang; Zhang, Fan; Hao, Yuying Journal of Materials Chemistry C, Vol. 5, Issue 9 https://doi.org/10.1039/c6tc05325d	journal	January 2017
A technoeconomic analysis of perovskite solar module manufacturing with low-cost materials and techniques Song, Zhaoning; McElvany, Chad L.; Phillips, Adam B. Energy & Environmental Science, Vol. 10, Issue 6 https://doi.org/10.1039/c7ee00757d	journal	January 2017
Predicting and optimising the energy yield of perovskite-on-silicon tandem solar cells under real world conditions Hörantner, Maximilian T.; Snaith, Henry J. Energy & Environmental Science, Vol. 10, Issue 9 https://doi.org/10.1039/c7ee01232b	journal	January 2017
New-generation integrated devices based on dye-sensitized and perovskite solar cells Yun, Sining; Qin, Yong; Uhl, Alexander R. Energy & Environmental Science, Vol. 11, Issue 3 https://doi.org/10.1039/c7ee03165c	journal	January 2018
C ₆₀ additive-assisted crystallization in CH ₃ NH ₃ Pb _0.75 Sn _0.25 I ₃ perovskite solar cells with high stability and efficiency Liu, Chong; Li, Wenzhe; Li, Hongliang Nanoscale, Vol. 9, Issue 37 https://doi.org/10.1039/c7nr03507a	journal	January 2017
Highly (100)-oriented CH ₃ NH ₃ PbI ₃ (Cl) perovskite solar cells prepared with NH ₄ Cl using an air blow method Oku, Takeo; Ohishi, Yuya; Ueoka, Naoki RSC Advances, Vol. 8, Issue 19 https://doi.org/10.1039/c7ra13582c	journal	January 2018
Mixed cation hybrid lead halide perovskites with enhanced performance and stability Xu, Feng; Zhang, Taiyang; Li, Ge Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/c7ta00042a	journal	January 2017
Roadmap and roadblocks for the band gap tunability of metal halide perovskites Unger, E. L.; Kegelmann, L.; Suchan, K. Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/c7ta00404d	journal	January 2017
Effects of organic cations on the defect physics of tin halide perovskites Shi, Tingting; Zhang, Hai-Shan; Meng, Weiwei Journal of Materials Chemistry A, Vol. 5, Issue 29 https://doi.org/10.1039/c7ta02662e	journal	January 2017
Influence of metal substitution on hybrid halide perovskites: towards lead-free perovskite solar cells Chatterjee, Soumyo; Pal, Amlan J. Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/c7ta09943f	journal	January 2018
Unusual two-step sequential reversible phase transitions with coexisting switchable nonlinear optical and dielectric behaviors in [(CH ₃ ) ₃ NCH ₂ Cl] ₂ [ZnCl ₄ ] Liao, Wei-Qiang; Gao, Ji-Xing; Hua, Xiu-Ni Journal of Materials Chemistry C, Vol. 5, Issue 45 https://doi.org/10.1039/c7tc04095d	journal	January 2017
Rational chemical doping of metal halide perovskites Zhang, Xinyuan; Li, Lina; Sun, Zhihua Chemical Society Reviews, Vol. 48, Issue 2 https://doi.org/10.1039/c8cs00563j	journal	January 2019
A cascade-type electron extraction design for efficient low-bandgap perovskite solar cells based on a conventional structure with suppressed open-circuit voltage loss Liu, Meiyue; Chen, Ziming; Chen, Zhen Materials Chemistry Frontiers, Vol. 3, Issue 3 https://doi.org/10.1039/c8qm00620b	journal	January 2019
Enhanced performance of tin halide perovskite solar cell by addition of lead thiocyanate Gao, Fengqiang; Li, Chunhai; Qin, Liang RSC Advances, Vol. 8, Issue 25 https://doi.org/10.1039/c8ra00809d	journal	January 2018
Synergistic effects of thiocyanate additive and cesium cations on improving the performance and initial illumination stability of efficient perovskite solar cells Wang, Changlei; Song, Zhaoning; Yu, Yue Sustainable Energy & Fuels, Vol. 2, Issue 11 https://doi.org/10.1039/c8se00200b	journal	January 2018
Metallic tin substitution of organic lead perovskite films for efficient solar cells Zhao, Jinjin; Wei, Liyu; Jia, Chunmei Journal of Materials Chemistry A, Vol. 6, Issue 41 https://doi.org/10.1039/c8ta05282d	journal	January 2018
High performance low-bandgap perovskite solar cells based on a high-quality mixed Sn–Pb perovskite film prepared by vacuum-assisted thermal annealing Liu, Meiyue; Chen, Ziming; Xue, Qifan Journal of Materials Chemistry A, Vol. 6, Issue 34 https://doi.org/10.1039/c8ta05444d	journal	January 2018
Hydrazinium-assisted stabilisation of methylammonium tin iodide for lead-free perovskite solar cells Tsarev, Sergey; Boldyreva, Aleksandra G.; Luchkin, Sergey Yu. Journal of Materials Chemistry A, Vol. 6, Issue 43 https://doi.org/10.1039/c8ta07699e	journal	January 2018
Band alignment of Pb–Sn mixed triple cation perovskites for inverted solar cells with negligible hysteresis Ji, Long; Zhang, Xiangzhao; Zhang, Ting Journal of Materials Chemistry A, Vol. 7, Issue 15 https://doi.org/10.1039/c8ta11891d	journal	January 2019
A Cu ₃ PS ₄ nanoparticle hole selective layer for efficient inverted perovskite solar cells Yin, Xinxing; McClary, Scott A.; Song, Zhaoning Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/c8ta12100a	journal	January 2019
H/F substituted perovskite compounds with above-room-temperature ferroelasticity: [(CH ₃ ) ₄ P][Cd(SCN) ₃ ] and [(CH ₃ ) ₃ PCH ₂ F][Cd(SCN) ₃ ] Cao, Ying-Jie; Zhou, Lin; Shi, Ping-Ping Chemical Communications, Vol. 55, Issue 58 https://doi.org/10.1039/c9cc03857d	journal	January 2019
Recent progress in flexible–wearable solar cells for self-powered electronic devices Hashemi, Seyyed Alireza; Ramakrishna, Seeram; Aberle, Armin Gerhard Energy & Environmental Science, Vol. 13, Issue 3 https://doi.org/10.1039/c9ee03046h	journal	January 2020
Reduced open-circuit voltage loss for highly efficient low-bandgap perovskite solar cells via suppression of silver diffusion Liu, Meiyue; Chen, Ziming; Yang, Yongchao Journal of Materials Chemistry A, Vol. 7, Issue 29 https://doi.org/10.1039/c9ta04366g	journal	January 2019
A high temperature optic-electric duple switching organic ionic compound: 1,4,7-triazoniacyclononane tetrafluoroborate dichloride Gao, Ji-Xing; Hua, Xiu-Ni; Chen, Xiao-Gang Journal of Materials Chemistry C, Vol. 7, Issue 18 https://doi.org/10.1039/c9tc01661a	journal	January 2019
Tin( iv ) dopant removal through anti-solvent engineering enabling tin based perovskite solar cells with high charge carrier mobilities Bandara, R. M. I.; Jayawardena, K. D. G. I.; Adeyemo, S. O. Journal of Materials Chemistry C, Vol. 7, Issue 27 https://doi.org/10.1039/c9tc02003a	journal	January 2019
Optical response of mixed methylammonium lead iodide and formamidinium tin iodide perovskite thin films Ghimire, Kiran; Zhao, Dewei; Yan, Yanfa AIP Advances, Vol. 7, Issue 7 https://doi.org/10.1063/1.4994211	journal	July 2017
CH ₃ NH ₃ Pb _{1− x} Mg _x I ₃ perovskites as environmentally friendly photovoltaic materials Zhang, Y. D.; Feng, J. AIP Advances, Vol. 8, Issue 1 https://doi.org/10.1063/1.5006241	journal	January 2018
Effects of CuBr addition to CH3NH3PbI3(Cl) perovskite photovoltaic devices Oku, Takeo; Ohishi, Yuya; Tanaka, Hiroki THE IRAGO CONFERENCE 2017: A 360-degree Outlook on Critical Scientific and Technological Challenges for a Sustainable Society, AIP Conference Proceedings https://doi.org/10.1063/1.5021923	conference	January 2018
Quantitative analysis of time-resolved microwave conductivity data Reid, Obadiah G.; Moore, David T.; Li, Zhen Journal of Physics D: Applied Physics, Vol. 50, Issue 49 https://doi.org/10.1088/1361-6463/aa9559	journal	November 2017
Atmospherically induced defects in (FASnI ₃ ) _0.6 (MAPbI _{3−3 x} Cl _{3 x} ) _0.4 perovskites Junda, Maxwell M.; Zhao, Dewei; Subedi, Biwas Journal of Physics D: Applied Physics, Vol. 52, Issue 17 https://doi.org/10.1088/1361-6463/ab05b2	journal	February 2019
Wide-bandgap, low-bandgap, and tandem perovskite solar cells Song, Zhaoning; Chen, Cong; Li, Chongwen Semiconductor Science and Technology, Vol. 34, Issue 9 https://doi.org/10.1088/1361-6641/ab27f7	journal	July 2019
Three-dimensional organic–inorganic hybrid sodium halide perovskite: C ₄ H ₁₂ N ₂ ·NaI ₃ and a hydrogen-bonded supramolecular three-dimensional network in 3C ₄ H ₁₂ N ₂ ·NaI ₄ ·3I·H ₂ O Chen, Xiao-Gang; Gao, Ji-Xing; Hua, Xiu-Ni Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 6 https://doi.org/10.1107/s2053229618006885	journal	May 2018
Promises and challenges of perovskite solar cells Correa-Baena, Juan-Pablo; Saliba, Michael; Buonassisi, Tonio Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam6323	journal	November 2017
Fabrication and Characterization of CH ₃ NH ₃ PbI ₃ Perovskite Solar Cells Added with Polysilanes Oku, Takeo; Nomura, Junya; Suzuki, Atsushi International Journal of Photoenergy, Vol. 2018 https://doi.org/10.1155/2018/8654963	journal	October 2018
Tin(iv) dopant removal through anti-solvent engineering enabling tin based perovskite solar cells with high charge carrier mobilities Bandara, Rmi; Jayawardena, Kdgi; Adeyemo, Stephanie Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.40441	text	January 2019
Controlling the Growth Kinetics and Optoelectronic Properties of 2D/3D Lead–Tin Perovskite Heterojunctions Ruggeri, Edoardo; Anaya, Miguel; Gałkowski, Krzysztof Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.45923	text	January 2019
High Open-Circuit Voltages in Tin-Rich Low-Bandgap Perovskite-Based Planar Heterojunction Photovoltaics Zhao, Baodan; Abdi-Jalebi, M.; Tabachnyk, M. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.6563	text	January 2017
Tailoring metal halide perovskites through metal substitution: Influence on photovoltaic and material properties Klug, Mt; Osherov, A.; Haghighirad, Aa Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.77395	text	January 2017
Vacuum‐Assisted Growth of Low‐Bandgap Thin Films (FA$_{0.8}$MA$_{0.2}$Sn$_{0.5}$Pb$_{0.5}$I$_{3}$) for All‐Perovskite Tandem Solar Cells Abdollahi Nejand, Bahram; Hossain, Ihteaz M.; Jakoby, Marius Karlsruhe https://doi.org/10.5445/ir/1000104357	text	January 2020

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14 SOLAR ENERGY
36 MATERIALS SCIENCE
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Fabrication of efficient low-bandgap perovskite solar cells by combining formamidinium tin iodide with methylammonium lead iodide

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