Alternative Alkaline Conditioning of Amidoxime Based Adsorbent for Uranium Extraction from Seawater

Das, S.; Liao, W. -P.; Flicker Byers, M.; Tsouris, C.; Janke, C. J.; Mayes, R. T.; Schneider, E.; Kuo, L. -J.; Wood, J. R.; Gill, G. A.; Dai, S.

doi:10.1021/acs.iecr.5b03210

Alternative Alkaline Conditioning of Amidoxime Based Adsorbent for Uranium Extraction from Seawater

Journal Article · Wed Apr 20 00:00:00 EDT 2016 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.5b03210· OSTI ID:1327096

Das, S.; Liao, W. -P.; Flicker Byers, M.; Tsouris, C.; Janke, C. J.; Mayes, R. T.; Schneider, E.; Kuo, L. -J.; Wood, J. R.; Gill, G. A.; Dai, S.

Alkaline conditioning of the amidoxime based adsorbents is a significant step in the preparation of the adsorbent for uranium uptake from seawater. The effects of various alkaline conditioning parameters such as the type of alkaline reagent, reaction temperature, and reaction time were investigated with respect to uranium adsorption capacity from simulated seawater (spiked with 8 ppm uranium) and natural seawater (from Sequim Bay, WA). An adsorbent (AF1) was prepared at the Oak Ridge National Laboratory by radiation-induced graft polymerization (RIGP) with acrylonitrile and itaconic acid onto high-surface-area polyethylene fibers. For the AF1 adsorbent, sodium hydroxide emerged as a better reagent for alkaline conditioning over potassium hydroxide, which has typically been used in previous studies, because of higher uranium uptake capacity and lower cost over the other candidate alkaline reagents investigated in this study. Use of sodium hydroxide in place of potassium hydroxide is shown to result in a 21-30% decrease in the cost of uranium recovery.

Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1327096

Report Number(s):: PNNL-SA--120372; AF5855000

Journal Information:: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 15 Vol. 55; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (31)

Chelating Polymers for Recovery of Uranium from Seawater∗ Kabay, Nalan; Egawa, Hiroaki Separation Science and Technology, Vol. 29, Issue 1 https://doi.org/10.1080/01496399408002473	journal	January 1994
Preparation and performance of amidoxime fiber adsorbents for recovery of uranium from seawater Kago, Tokihiro; Goto, Akira; Kusakabe, Katsuki Industrial & Engineering Chemistry Research, Vol. 31, Issue 1 https://doi.org/10.1021/ie00001a029	journal	January 1992
Recovery of uranium from sea water. IV. Influence of crosslinking reagent of the uranium adsorption of macroreticular chelating resin containing amidoxime groups Egawa, Hiroaki; Nakayama, Morio; Nonaka, Takamasa Journal of Applied Polymer Science, Vol. 33, Issue 6 https://doi.org/10.1002/app.1987.070330613	journal	May 1987
A New Type of Amidoxime-Group-Containing Adsorbent for the Recovery of Uranium from Seawater. III. Recycle Use of Adsorbent Omichi, H.; Katakai, A.; Sugo, T. Separation Science and Technology, Vol. 21, Issue 6-7 https://doi.org/10.1080/01496398608056135	journal	August 1986
Exchanges of Uranium(VI) Species in Amidoxime-Functionalized Sorbents Das, Sadananda; Pandey, Ashok K.; Athawale, Anjali A. The Journal of Physical Chemistry B, Vol. 113, Issue 18 https://doi.org/10.1021/jp8097928	journal	April 2009
The Adsorption Properties and Kinetics of Uranium(VI) with a Novel Fibrous and Polymeric Adsorbent Containing Amidoxime Chelating Functional Group from Seawater Zhang, Anyun; Uchiyama, Gunzo; Asakura, Toshihide Separation Science and Technology, Vol. 38, Issue 8 https://doi.org/10.1081/SS-120019411	journal	January 2003
Macroporous monoliths for trace metal extraction from seawater Yue, Yanfeng; Mayes, Richard T.; Gill, Gary RSC Advances, Vol. 5, Issue 62 https://doi.org/10.1039/C5RA02131F	journal	January 2015
Preparation of Amidoxime-Fiber Adsorbents Based on Poly(Methacrylonitrile) for Recovery of Uranium from Seawater∗ Kabay, Nalan Separation Science and Technology, Vol. 29, Issue 3 https://doi.org/10.1080/01496399408002489	journal	February 1994
Uptake of Uranium from Seawater by Amidoxime-Based Polymeric Adsorbent: Field Experiments, Modeling, and Updated Economic Assessment Kim, Jungseung; Tsouris, Costas; Oyola, Yatsandra Industrial & Engineering Chemistry Research, Vol. 53, Issue 14 https://doi.org/10.1021/ie4039828	journal	March 2014
Recovery of uranium from seawater. XII. Preparation and characterization of lightly crosslinked highly porous chelating resins containing amidoxime groups Egawa, Hiroaki; Kabay, Nalan; Shuto, Taketomi Journal of Applied Polymer Science, Vol. 46, Issue 1 https://doi.org/10.1002/app.1992.070460113	journal	September 1992
Chemical Speciation of Uranium(VI) in Marine Environments: Complexation of Calcium and Magnesium Ions with [(UO ₂ )(CO ₃ ) ₃ ] ⁴⁻ and the Effect on the Extraction of Uranium from Seawater Endrizzi, Francesco; Rao, Linfeng Chemistry - A European Journal, Vol. 20, Issue 44 https://doi.org/10.1002/chem.201403262	journal	September 2014
Complexation of uranium( vi ) with glutarimidoxioxime: thermodynamic and computational studies Endrizzi, Francesco; Melchior, Andrea; Tolazzi, Marilena Dalton Transactions, Vol. 44, Issue 31 https://doi.org/10.1039/C5DT00261C	journal	January 2015
Predicting Stability Constants for Uranyl Complexes Using Density Functional Theory Vukovic, Sinisa; Hay, Benjamin P.; Bryantsev, Vyacheslav S. Inorganic Chemistry, Vol. 54, Issue 8 https://doi.org/10.1021/acs.inorgchem.5b00264	journal	March 2015
Carbonate–H ₂ O ₂ leaching for sequestering uranium from seawater Pan, Horng-Bin; Liao, Weisheng; Wai, Chien M. Dalton Trans., Vol. 43, Issue 28 https://doi.org/10.1039/c3dt53404a	journal	January 2014
Acidity of the Amidoxime Functional Group in Aqueous Solution: A Combined Experimental and Computational Study Mehio, Nada; Lashely, Mark A.; Nugent, Joseph W. The Journal of Physical Chemistry B, Vol. 119, Issue 8 https://doi.org/10.1021/jp512778x	journal	February 2015
Dynamic-State Adsorption and Elution Behaviour of Uranium(VI) Ions from Seawater by a Fibrous and Porous Adsorbent Containing Amidoxime Chelating Functional Groups Zhang, Anyun; Uchiyama, Gunzo; Asakura, Toshihide Adsorption Science & Technology, Vol. 21, Issue 8 https://doi.org/10.1260/026361703773581812	journal	October 2003
The extraction of uranium by amidoximated orlon Katragadda, S. Talanta, Vol. 45, Issue 2 https://doi.org/10.1016/S0039-9140(97)00128-8	journal	December 1997
The Cost of Recovering Uranium from Seawater by a Braided Polymer Adsorbent System Schneider, Erich; Sachde, Darshan Science & Global Security, Vol. 21, Issue 2 https://doi.org/10.1080/08929882.2013.798993	journal	May 2013
The adsorption mechanism of uranium(VI) from seawater on a macroporous fibrous polymeric adsorbent containing amidoxime chelating functional group Zhang, Anyun; Asakura, Toshihide; Uchiyama, Gunzo Reactive and Functional Polymers, Vol. 57, Issue 1 https://doi.org/10.1016/j.reactfunctpolym.2003.07.005	journal	November 2003
pH Effect on the uranium adsorption from seawater by a macroporous fibrous polymeric material containing amidoxime chelating functional group Zhang, Anyun; Uchiyama, Gunzo; Asakura, Toshihide Reactive and Functional Polymers, Vol. 63, Issue 2 https://doi.org/10.1016/j.reactfunctpolym.2005.02.015	journal	May 2005
Chemical aspects of uranium recovery from seawater by amidoximated electron-beam-grafted polypropylene membranes Das, Sadananda; Pandey, A. K.; Athawale, Anjali Desalination, Vol. 232, Issue 1-3, p. 243-253 https://doi.org/10.1016/j.desal.2007.09.019	journal	November 2008
Quantifying the binding strength of U( vi ) with phthalimidedioxime in comparison with glutarimidedioxime Sun, Xiaoqi; Tian, Guoxin; Xu, Chao Dalton Trans., Vol. 43, Issue 2 https://doi.org/10.1039/C3DT52206G	journal	January 2014
Recovery of Uranium from Seawater: A Review of Current Status and Future Research Needs Kim, Jungseung; Tsouris, Costas; Mayes, Richard T. Separation Science and Technology, Vol. 48, Issue 3 https://doi.org/10.1080/01496395.2012.712599	journal	January 2013
Structural clues to UO ₂ ²⁺ /VO ₂ ⁺ competition in seawater extraction using amidoxime-based extractants Kelley, Steven P.; Barber, Patrick S.; Mullins, Peter H. K. Chem. Commun., Vol. 50, Issue 83 https://doi.org/10.1039/C4CC06370H	journal	January 2014
Characterization of Uranium Uptake Kinetics from Seawater in Batch and Flow-Through Experiments Kim, Jungseung; Oyola, Yatsandra; Tsouris, Costas Industrial & Engineering Chemistry Research, Vol. 52, Issue 27 https://doi.org/10.1021/ie400587f	journal	June 2013
Complexation of calcium and magnesium with glutarimidedioxime: Implications for the extraction of uranium from seawater Leggett, Christina J.; Rao, Linfeng Polyhedron, Vol. 95 https://doi.org/10.1016/j.poly.2015.04.004	journal	July 2015
Biomimetic Mineralization of Uranium by Metabolically-Inactive Shrimp Shell Griggs, C. S.; Barber, P. S.; Kelley, S. P. Crystal Growth & Design, Vol. 14, Issue 12 https://doi.org/10.1021/cg5015576	journal	October 2014
Surface modification of ionic liquid-spun chitin fibers for the extraction of uranium from seawater: seeking the strength of chitin and the chemical functionality of chitosan Barber, Patrick S.; Kelley, Steven P.; Griggs, Chris S. Green Chem., Vol. 16, Issue 4 https://doi.org/10.1039/c4gc00092g	journal	January 2014
Recovery System for Uranium from Seawater with Fibrous Adsorbent and Its Preliminary Cost Estimation. [海水ウラン捕集のコスト評価と実用化に向けての技術課題] Sugo, Takanobu; Tamada, Masao; Seguchi, Tadao Journal of the Atomic Energy Society of Japan / Atomic Energy Society of Japan, Vol. 43, Issue 10 https://doi.org/10.3327/jaesj.43.1010	journal	January 2001
Development of a Kelp-Type Structure Module in a Coastal Ocean Model to Assess the Hydrodynamic Impact of Seawater Uranium Extraction Technology Wang, Taiping; Khangaonkar, Tarang; Long, Wen Journal of Marine Science and Engineering, Vol. 2, Issue 1 https://doi.org/10.3390/jmse2010081	journal	February 2014
Uranium recovery from seawater: development of fiber adsorbents prepared via atom-transfer radical polymerization Saito, Tomonori; Brown, Suree; Chatterjee, Sabornie J. Mater. Chem. A, Vol. 2, Issue 35 https://doi.org/10.1039/C4TA03276D	journal	January 2014

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The use of silver nanoparticles for the recovery of uranium from seawater by means of biofouling mitigation Byers, Margaret Flicker; Landsberger, Sheldon; Schneider, Erich Sustainable Energy & Fuels, Vol. 2, Issue 10 https://doi.org/10.1039/c8se00228b	journal	January 2018
Symbiotic Aerogel Fibers Made via In-Situ Gelation of Aramid Nanofibers with Polyamidoxime for Uranium Extraction Li, Juan; Wang, Jin; Wang, Wei Molecules, Vol. 24, Issue 9 https://doi.org/10.3390/molecules24091821	journal	May 2019
A Dual‐Surface Amidoximated Halloysite Nanotube for High‐Efficiency Economical Uranium Extraction from Seawater Zhao, Shilei; Yuan, Yihui; Yu, Qiuhan Angewandte Chemie, Vol. 131, Issue 42 https://doi.org/10.1002/ange.201908762	journal	September 2019
Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater Ivanov, Alexander S.; Leggett, Christina J.; Parker, Bernard F. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01443-1	journal	November 2017
A Dual‐Surface Amidoximated Halloysite Nanotube for High‐Efficiency Economical Uranium Extraction from Seawater Zhao, Shilei; Yuan, Yihui; Yu, Qiuhan Angewandte Chemie International Edition, Vol. 58, Issue 42 https://doi.org/10.1002/anie.201908762	journal	September 2019

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