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Title: Graphene-carbon nanotube hybrid materials and use as electrodes

Abstract

Provided are methods of making graphene-carbon nanotube hybrid materials. Such methods generally include: (1) associating a graphene film with a substrate; (2) applying a catalyst and a carbon source to the graphene film; and (3) growing carbon nanotubes on the graphene film. The grown carbon nanotubes become covalently linked to the graphene film through carbon-carbon bonds that are located at one or more junctions between the carbon nanotubes and the graphene film. In addition, the grown carbon nanotubes are in ohmic contact with the graphene film through the carbon-carbon bonds at the one or more junctions. The one or more junctions may include seven-membered carbon rings. Also provided are the formed graphene-carbon nanotube hybrid materials.

Inventors:
; ; ; ;
Publication Date:
Research Org.:
WILLIAM MARSH RICE UNIVERSITY, Houston, TX (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1326803
Patent Number(s):
9,455,094
Application Number:
14/358,864
Assignee:
WILLIAM MARSH RICE UNIVERSITY (Houston, TX) GFO
DOE Contract Number:  
FC36-05GO15073; FA9550-12-1-0035
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 Nov 19
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats

Tour, James M., Zhu, Yu, Li, Lei, Yan, Zheng, and Lin, Jian. Graphene-carbon nanotube hybrid materials and use as electrodes. United States: N. p., 2016. Web.
Tour, James M., Zhu, Yu, Li, Lei, Yan, Zheng, & Lin, Jian. Graphene-carbon nanotube hybrid materials and use as electrodes. United States.
Tour, James M., Zhu, Yu, Li, Lei, Yan, Zheng, and Lin, Jian. Tue . "Graphene-carbon nanotube hybrid materials and use as electrodes". United States. doi:. https://www.osti.gov/servlets/purl/1326803.
@article{osti_1326803,
title = {Graphene-carbon nanotube hybrid materials and use as electrodes},
author = {Tour, James M. and Zhu, Yu and Li, Lei and Yan, Zheng and Lin, Jian},
abstractNote = {Provided are methods of making graphene-carbon nanotube hybrid materials. Such methods generally include: (1) associating a graphene film with a substrate; (2) applying a catalyst and a carbon source to the graphene film; and (3) growing carbon nanotubes on the graphene film. The grown carbon nanotubes become covalently linked to the graphene film through carbon-carbon bonds that are located at one or more junctions between the carbon nanotubes and the graphene film. In addition, the grown carbon nanotubes are in ohmic contact with the graphene film through the carbon-carbon bonds at the one or more junctions. The one or more junctions may include seven-membered carbon rings. Also provided are the formed graphene-carbon nanotube hybrid materials.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 27 00:00:00 EDT 2016},
month = {Tue Sep 27 00:00:00 EDT 2016}
}

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Works referenced in this record:

Synthesis of a Pillared Graphene Nanostructure: A Counterpart of Three-Dimensional Carbon Architectures
journal, September 2010

  • Paul, Rajat Kanti; Ghazinejad, Maziar; Penchev, Miroslav
  • Small, Vol. 6, Issue 20, p. 2309-2313
  • DOI: 10.1002/smll.201000525

A Three-Dimensional Carbon Nanotube/Graphene Sandwich and Its Application as Electrode in Supercapacitors
journal, August 2010

  • Fan, Zhuangjun; Yan, Jun; Zhi, Linjie
  • Advanced Materials, Vol. 22, Issue 33, p. 3723-3728
  • DOI: 10.1002/adma.201001029

Versatile Carbon Hybrid Films Composed of Vertical Carbon Nanotubes Grown on Mechanically Compliant Graphene Films
journal, March 2010

  • Lee, Duck Hyun; Kim, Ji Eun; Han, Tae Hee
  • Advanced Materials, Vol. 22, Issue 11, p. 1247-1252
  • DOI: 10.1002/adma.200903063

Carbon nanotubes: properties and application
journal, January 2004


Pillared Graphene A New 3-D Network Nanostructure for Enhanced Hydrogen Storage
journal, October 2008

  • Dimitrakakis, Georgios K.; Tylianakis, Emmanuel; Froudakis, George E.
  • Nano Letters, Vol. 8, Issue 10, p. 3166-3170
  • DOI: 10.1021/nl801417w

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004


Carbon-Based Supercapacitors Produced by Activation of Graphene
journal, May 2011


Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils
journal, May 2009


Ultrahigh electron mobility in suspended graphene
journal, June 2008

  • Bolotin, K. I.; Sikes, K. J.; Jiang, Z.
  • Solid State Communications, Vol. 146, Issue 9-10, p. 351-355
  • DOI: 10.1016/j.ssc.2008.02.024

Growth of Bilayer Graphene on Insulating Substrates
journal, October 2011

  • Yan, Zheng; Peng, Zhiwei; Sun, Zhengzong
  • ACS Nano, Vol. 5, Issue 10, p. 8187-8192
  • DOI: 10.1021/nn202829y

Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon
journal, August 2010

  • Pech, David; Brunet, Magali; Durou, Hugo
  • Nature Nanotechnology, Vol. 5, Issue 9, p. 651-654
  • DOI: 10.1038/nnano.2010.162

Superior Thermal Conductivity of Single-Layer Graphene
journal, March 2008

  • Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong
  • Nano Letters, Vol. 8, Issue 3, p. 902-907
  • DOI: 10.1021/nl0731872

Enhanced field emission from multi-walled carbon nanotubes grown on pure copper substrate
journal, April 2010


Aligned Carbon Nanotube‚ąíPolymer Hybrid Architectures for Diverse Flexible Electronic Applications
journal, February 2006

  • Jung, Yung Joon; Kar, Swastik; Talapatra, Saikat
  • Nano Letters, Vol. 6, Issue 3, p. 413-418
  • DOI: 10.1021/nl052238x

Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition
journal, April 2011

  • Chen, Zongping; Ren, Wencai; Gao, Libo
  • Nature Materials, Vol. 10, Issue 6, p. 424-428
  • DOI: 10.1038/nmat3001

One-step synthesis of a graphene-carbon nanotube hybrid decorated by magnetic nanoparticles
journal, July 2012


Printable Thin Film Supercapacitors Using Single-Walled Carbon Nanotubes
journal, May 2009

  • Kaempgen, Martti; Chan, Candace K.; Ma, J.
  • Nano Letters, Vol. 9, Issue 5, p. 1872-1876
  • DOI: 10.1021/nl8038579