Long-range antiferromagnetic order in malonate-based compounds Na2M(H2C3O4)2·2H2O (M = Mn, Fe, Co, Ni)

Rousse, G.; Radtke, G.; Klein, Y.; Ahouari, H.

doi:10.1039/c5dt04527d

Title: Long-range antiferromagnetic order in malonate-based compounds Na₂M(H₂C₃O₄)₂·2H₂O (M = Mn, Fe, Co, Ni)

Journal Article · Fri Dec 18 00:00:00 EST 2015 · Dalton Transactions

DOI:https://doi.org/10.1039/c5dt04527d· OSTI ID:1324790

Rousse, G. ^[1]; Radtke, G. ^[2]; Klein, Y. ^[2]; Ahouari, H. ^[3]

Collège de France, Paris (France); Réseau sur le Stockage Electrochimique de l'Energie (RS2E) (France); Sorbonne Univ., Paris (France)
Sorbonne Univ., Paris (France)
Centre National de la Recherche Scientifique (CNRS), Amiens (France)

In this work, the recently discovered metal-malonate compounds of formulae Na₂M(H₂C₃O₄)₂·2H₂O with M = Mn, Fe, Co, Ni are investigated for their magnetic properties. While the Cu-based material is a weak ferromagnet, all other members present antiferromagnetic interactions. Neutron powder diffraction experiments reveal the establishment of a long range magnetic order at low temperature in the Pbca Shubnikov magnetic group. The magnetic structures are characterized by antiferromagnetic layers perpendicular to [001]. These layers are stacked antiparallel (M = Fe) or parallel (M = Mn, Ni) in the (a, c) plane. Magnetic moments are collinear to b for the former and to c for the latter. The M = Co malonate exhibits a non-collinear magnetic structure intermediate between the two latter, with components along b and c. Density functional theory calculations indicate that the dominant magnetic interaction, J₁, occurs along a malonate group via a carboxylate and links two transition metals within the same layer, while other interactions (inter- or intra-layer) are much weaker, so that these compounds present the dominant characteristics of 2D-antiferromagnets.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE; Grand Equipement National de Calcul Intensif

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1324790

Journal Information:: Dalton Transactions, Vol. 45, Issue 6; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 4 works

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Title: Long-range antiferromagnetic order in malonate-based compounds Na2M(H2C3O4)2·2H2O (M = Mn, Fe, Co, Ni)

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Title: Long-range antiferromagnetic order in malonate-based compounds Na₂M(H₂C₃O₄)₂·2H₂O (M = Mn, Fe, Co, Ni)