Magnetic hardening and coercivity mechanisms in L1{sub o} ordered FePd ferromagnets

Journal Article · Thu Nov 30 23:00:00 EST 1995 · Scripta Metallurgica et Materialia

DOI:https://doi.org/10.1016/0956-716X(95)00413-P· OSTI ID:131465

Klemmer, T; Hoydick, D; Okumura, H; Zhang, B; Soffa, W A ^[1]

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1. Univ. of Pittsburgh, PA (United States). Dept. of Materials Science and Engineering

The tetragonal L1{sub o} family of ferromagnets including the Co-Pt, Fe-Pt, Fe-Pd and Mn-Al alloy systems exhibits high, uniaxial magnetocrystalline anisotropies with first anisotropy constants K{sub 1} {approximately} 10{sup 7}--10{sup 8} ergs/cm{sup 3}. The domain parameters of these materials are similar to the rare earth permanent magnets and the defect structure is dominated by planar faults such as APB`s, stacking faults, and twins. In this study the micromagnetic analysis of Kronmueller has been applied to elucidate the mechanism of coercivity controlling the hysteresis of the polytwinned L1{sub o} FePd equiatomic alloy and the results are consistent with pinning control involving atomically thick, planar defects. Also, Lorentz microscopy has been used to observe the interaction of magnetic domain walls with the planar faults characteristic of these materials. Finally, a thermomechanical treatment involving concomitant ordering and recrystallization is shown to eliminate the well-known polytwinned structures which generally evolve during the formation of the L1{sub o} phase leading to enhanced coercivities. The fundamental structure-property relationships involved are discussed.

• OSTI ID: 131465
• Journal Information: Scripta Metallurgica et Materialia, Journal Name: Scripta Metallurgica et Materialia Journal Issue: 10-11 Vol. 33; ISSN 0956-716X; ISSN SCRMEX
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ALUMINIUM ALLOYS
ANISOTROPY
COBALT ALLOYS
COERCIVE FORCE
CRYSTAL STRUCTURE
DEFECTS
DOMAIN STRUCTURE
HYSTERESIS
INTERMETALLIC COMPOUNDS
IRON ALLOYS
MAGNETIC PROPERTIES
MANGANESE ALLOYS
PALLADIUM ALLOYS
PLATINUM ALLOYS
STACKING FAULTS
TETRAGONAL LATTICES
THERMOMECHANICAL TREATMENTS
TWINNING