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Title: Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides

Abstract

Technetium (Tc) is the lightest element that doesn't occur in nature. At UNLV, our radiochemistry program gives us access to Tc and the ability to make various Tc compounds. Here we describe the preparation and characterization of TcCl4. The Tc atom is found to have a magnetic moment and magnetically orders at low temperature. As discerning trends in the transition metals, of which Tc is one, is important for understanding all transition metal compounds, this research is relevant to understanding these materials.

Authors:
 [1];  [1];  [1];  [2];  [2];  [3];  [3];  [4];  [1]
  1. Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry
  2. Univ. of Nevada, Las Vegas, NV (United States). Harry Reid Center for Environmental Studies
  3. Univ. of Nevada, Las Vegas, NV (United States). Dept. of Physics and Astronomy
  4. Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry; Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Univ. of Nevada, Las Vegas, NV (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1307429
Report Number(s):
DOE-UNLV-05278
Journal ID: ISSN 0020-1669
Grant/Contract Number:  
SC0005278; 47824B
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Inorganic Chemistry
Additional Journal Information:
Journal Volume: 51; Journal Issue: 15; Journal ID: ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Technetium, Magnetism, Transition Metal

Citation Formats

Johnstone, Erik V., Poineau, Frederic, Forster, Paul M., Ma, Longzou, Hartmann, Thomas, Cornelius, Andrew, Antonio, Daniel, Sattelberger, Alfred P., and Czerwinski, Kenneth R. Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides. United States: N. p., 2012. Web. doi:10.1021/ic301011c.
Johnstone, Erik V., Poineau, Frederic, Forster, Paul M., Ma, Longzou, Hartmann, Thomas, Cornelius, Andrew, Antonio, Daniel, Sattelberger, Alfred P., & Czerwinski, Kenneth R. Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides. United States. https://doi.org/10.1021/ic301011c
Johnstone, Erik V., Poineau, Frederic, Forster, Paul M., Ma, Longzou, Hartmann, Thomas, Cornelius, Andrew, Antonio, Daniel, Sattelberger, Alfred P., and Czerwinski, Kenneth R. 2012. "Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides". United States. https://doi.org/10.1021/ic301011c. https://www.osti.gov/servlets/purl/1307429.
@article{osti_1307429,
title = {Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides},
author = {Johnstone, Erik V. and Poineau, Frederic and Forster, Paul M. and Ma, Longzou and Hartmann, Thomas and Cornelius, Andrew and Antonio, Daniel and Sattelberger, Alfred P. and Czerwinski, Kenneth R.},
abstractNote = {Technetium (Tc) is the lightest element that doesn't occur in nature. At UNLV, our radiochemistry program gives us access to Tc and the ability to make various Tc compounds. Here we describe the preparation and characterization of TcCl4. The Tc atom is found to have a magnetic moment and magnetically orders at low temperature. As discerning trends in the transition metals, of which Tc is one, is important for understanding all transition metal compounds, this research is relevant to understanding these materials.},
doi = {10.1021/ic301011c},
url = {https://www.osti.gov/biblio/1307429}, journal = {Inorganic Chemistry},
issn = {0020-1669},
number = 15,
volume = 51,
place = {United States},
year = {2012},
month = {7}
}

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Cited by: 10 works
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Works referenced in this record:

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Works referencing / citing this record:

From Tc VII to Tc I ; facile syntheses of bis-arene complexes [ 99(m) Tc(arene) 2 ] + from pertechnetate
journal, January 2015