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Title: Lawrence Livermore National Laboratory offsite hazardous waste shipment data validation report

Technical Report ·
DOI:https://doi.org/10.2172/130620· OSTI ID:130620

The U.S. Department of Energy Headquarters requested this report to verify that Lawrence Livermore National Laboratory (LLNL) properly categorized hazardous waste shipped offsite from 1984 to 1991. LLNL categorized the waste shipments by the new guidelines provided on the definition of radioactive waste. For this validation, waste that has had no radioactivity added by DOE operations is nonradioactive. Waste to which DOE operations has added or concentrated any radioactivity is radioactive. This report documents findings from the review of available LLNL hazardous waste shipment information and summarizes the data validation strategy. The report discusses administrative and radiological control procedures in place at LLNL during the data validation period. It also describes sampling and analysis and surface survey procedures used in determining radionuclide concentrations for offsite release of hazardous waste shipments. The evaluation team reviewed individual items on offsite hazardous waste shipments and classified them, using the DOE-HQ waste category definitions. LLNL relied primarily on generator knowledge to classify wastes. Very little radioanalytical information exists on hazardous wastes shipped from LLNL. Slightly greater than one-half of those hazardous waste items for which the documentation included radioanalytical data showed concentrations of radioactivity higher than the LLNL release criteria used from 1989 to 1991. Based on this small amount of available radioanalytical data, very little (less than one percent) of the hazardous waste generated at the LLNL main site can be shown to contain DOE added radioactivity. LLNL based the criteria on the limit of analytical sensitivity for gross alpha and gross beta measurements and the background levels of tritium. Findings in this report are based on information and documentation on the waste handling procedures in place before the start of the hazardous waste shipping moratorium in May 1991.

Research Organization:
EG and G Idaho, Inc., Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC07-94ID13223
OSTI ID:
130620
Report Number(s):
DOE/LLW-227; ON: DE96002364; TRN: 96:000115
Resource Relation:
Other Information: PBD: Sep 1995
Country of Publication:
United States
Language:
English