Compositions comprising free-standing two-dimensional nanocrystals

Barsoum, Michel W.; Gogotsi, Yury; Abdelmalak, Michael Naguib; Mashtalir, Olha

Compositions comprising free-standing two-dimensional nanocrystals

Patent · 16 August 2016

OSTI ID:1298046

Barsoum, Michel W.; Gogotsi, Yury; Abdelmalak, Michael Naguib; Mashtalir, Olha

The present invention is directed to compositions comprising free standing and stacked assemblies of two dimensional crystalline solids, and methods of making the same.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-05CH11231

Assignee:: Drexel University (Philadelphia, PA)

Patent Number(s):: 9,416,011

Application Number:: 14/881,261

OSTI ID:: 1298046

Country of Publication:: United States

Language:: English

References (30)

Vibrational behavior of the M n + 1 A X n phases from first-order Raman scattering ( M = Ti , V , Cr , A = Si , X = C , N ) Spanier, Jonathan E.; Gupta, Surojit; Amer, Maher Physical Review B, Vol. 71, Issue 1 https://doi.org/10.1103/PhysRevB.71.012103	journal	January 2005
High-Quality Thin Graphene Films from Fast Electrochemical Exfoliation Su, Ching-Yuan; Lu, Ang-Yu; Xu, Yanping ACS Nano, Vol. 5, Issue 3 https://doi.org/10.1021/nn200025p	journal	February 2011
Synthesis of a new graphene-like transition metal carbide by de-intercalating Ti₃AlC₂ Chang, Fangyuan; Li, Changsheng; Yang, Jin Materials Letters, Vol. 109, p. 295-298 https://doi.org/10.1016/j.matlet.2013.07.102	journal	October 2013
Microstructure and phase transformation of Ti₃AC₂ (A = Al, Si) in hydrofluoric acid solution Chen, Beibei; Chang, Fangyuan; Yang, Jin Crystal Research and Technology, Vol. 49, Issue 10, p. 813-819 https://doi.org/10.1002/crat.201400189	journal	August 2014
Unique Lead Adsorption Behavior of Activated Hydroxyl Group in Two-Dimensional Titanium Carbide Peng, Qiuming; Guo, Jianxin; Zhang, Qingrui Journal of the American Chemical Society, Vol. 136, Issue 11 https://doi.org/10.1021/ja500506k	journal	March 2014
Graphene-based composite materials Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B. Nature, Vol. 442, Issue 7100, p. 282-286 https://doi.org/10.1038/nature04969	journal	July 2006
The Topotactic Transformation of Ti₃SiC₂ into a Partially Ordered Cubic Ti ( C _0.67Si_0.06 ) Phase by the Diffusion of Si into Molten Cryolite Barsoum, M. W.; El‐Raghy, T.; Farber, L. Journal of The Electrochemical Society, Vol. 146, Issue 10, p. 3919-3923 https://doi.org/10.1149/1.1392573	journal	January 1999
Room-Temperature Deintercalation and Self-Extrusion of Ga from Cr₂GaN Barsoum, M. W.; Farber, L. Science, Vol. 284, Issue 5416, p. 937-939 https://doi.org/10.1126/science.284.5416.937	journal	May 1999
Carbon nanoscrolls produced from acceptor-type graphite intercalation compounds Savoskin, Michael V.; Mochalin, Vadym N.; Yaroshenko, Alexander P. Carbon, Vol. 45, Issue 14, p. 2797-2800 https://doi.org/10.1016/j.carbon.2007.09.031	journal	November 2007
MXene: a promising transition metal carbide anode for lithium-ion batteries Naguib, Michael; Come, Jérémy; Dyatkin, Boris Electrochemistry Communications, Vol. 16, Issue 1, p. 61-64 https://doi.org/10.1016/j.elecom.2012.01.002	journal	March 2012
Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials Coleman, J. N.; Lotya, M.; O'Neill, A. Science, Vol. 331, Issue 6017, p. 568-571 https://doi.org/10.1126/science.1194975	journal	February 2011
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang Nature, Vol. 516, Issue 7529 https://doi.org/10.1038/nature13970	journal	November 2014
Two-Dimensional Transition Metal Carbides Naguib, Michael; Mashtalir, Olha; Carle, Joshua ACS Nano, Vol. 6, Issue 2 https://doi.org/10.1021/nn204153h	journal	January 2012
Intercalation and exfoliation routes to graphite nanoplatelets Viculis, Lisa M.; Mack, Julia J.; Mayer, Oren M. Journal of Materials Chemistry, Vol. 15, Issue 9 https://doi.org/10.1039/B413029D	journal	January 2005
The corrosion behavior of Ti₃SiC₂ in common acids and dilute NaOH Travaglini, J.; Barsoum, M. W.; Jovic, V. Corrosion Science, Vol. 45, Issue 6, p. 1313-1327 https://doi.org/10.1016/S0010-938X(02)00227-5	journal	June 2003
Low temperature thermal expansion, high temperature electrical conductivity, and mechanical properties of Nb₄AlC₃ ceramic synthesized by spark plasma sintering Hu, Chunfeng; Sakka, Yoshio; Tanaka, Hidehiko Journal of Alloys and Compounds, Vol. 487, Issue 1-2, p. 675-681 https://doi.org/10.1016/j.jallcom.2009.08.036	journal	November 2009
The M_n+1AX_n phases: Materials science and thin-film processing Eklund, Per; Beckers, Manfred; Jansson, Ulf Thin Solid Films, Vol. 518, Issue 8, p. 1851-1878 https://doi.org/10.1016/j.tsf.2009.07.184	journal	February 2010
The structure of multilayered titania nanotubes based on delaminated anatase Mogilevsky, Gregory; Chen, Qiang; Kleinhammes, Alfred Chemical Physics Letters, Vol. 460, Issue 4-6, p. 517-520 https://doi.org/10.1016/j.cplett.2008.06.063	journal	July 2008
Are MXenes Promising Anode Materials for Li Ion Batteries? Computational Studies on Electronic Properties and Li Storage Capability of Ti ₃ C ₂ and Ti ₃ C ₂ X ₂ (X = F, OH) Monolayer Tang, Qing; Zhou, Zhen; Shen, Panwen Journal of the American Chemical Society, Vol. 134, Issue 40 https://doi.org/10.1021/ja308463r	journal	September 2012
New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries Naguib, Michael; Halim, Joseph; Lu, Jun Journal of the American Chemical Society, Vol. 135, Issue 43 https://doi.org/10.1021/ja405735d	journal	October 2013
XPS studies of amino acids adsorbed on titanium dioxide surfaces Schmidt, Martin; Steinemann, Samuel G. Fresenius' Journal of Analytical Chemistry, Vol. 341, Issue 5-6 https://doi.org/10.1007/BF00321947	journal	January 1991
Lithium Intercalation in Porous Carbon Electrodes Tran, T. D.; Feikert, J.; Pekala, R. W. MRS Proceedings, Vol. 393 https://doi.org/10.1557/PROC-393-327	journal	January 1995
A Chemical Route to Carbon Nanoscrolls Viculis, L. M. Science, Vol. 299, Issue 5611 https://doi.org/10.1126/science.1078842	journal	February 2003
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
A study of the synthetic methods and properties of graphenes Rao, C. N. R.; Subrahmanyam, K. S.; Ramakrishna Matte, H. S. S. Science and Technology of Advanced Materials, Vol. 11, Issue 5 https://doi.org/10.1088/1468-6996/11/5/054502	journal	October 2010
MXene: A New Family of Promising Hydrogen Storage Medium Hu, Qianku; Sun, Dandan; Wu, Qinghua The Journal of Physical Chemistry A, Vol. 117, Issue 51 https://doi.org/10.1021/jp409585v	journal	December 2013
Two-dimensional Sc₂C: A reversible and high-capacity hydrogen storage material predicted by first-principles calculations Hu, Qianku; Wang, Haiyan; Wu, Qinghua International Journal of Hydrogen Energy, Vol. 39, Issue 20, p. 10606-10612 https://doi.org/10.1016/j.ijhydene.2014.05.037	journal	July 2014
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W. Advanced Materials, Vol. 26, Issue 7, p. 992-1005 https://doi.org/10.1002/adma.201304138	journal	December 2013
Synthesis and Characterization of a Remarkable Ceramic: Ti3SiC2 Barsoum, Michel W.; El-Raghy, Tamer Journal of the American Ceramic Society, Vol. 79, Issue 7 https://doi.org/10.1111/j.1151-2916.1996.tb08018.x	journal	July 1996
Synthesis and Characterization of Ti3AlC2 Tzenov, Nikolay V.; Barsoum, Michel W. Journal of the American Ceramic Society, Vol. 83, Issue 4 https://doi.org/10.1111/j.1151-2916.2000.tb01281.x	journal	April 2000

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