Magnetic structure of the quasi-one-dimensional La3OsO7 as determined by neutron powder diffraction

Morrow, Ryan; Susner, Michael A.; Sumption, Michael D.; Woodward, Patrick M.

doi:10.1103/PhysRevB.92.134402

Title: Magnetic structure of the quasi-one-dimensional $L a_{3} Os O_{7}$ as determined by neutron powder diffraction

Journal Article · Mon Oct 05 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.92.134402· OSTI ID:1295129

Morrow, Ryan ^[1]; Susner, Michael A. ^[2]; Sumption, Michael D. ^[1]; Woodward, Patrick M. ^[1]

The Ohio State Univ., Columbus, OH (United States)
The Ohio State Univ., Columbus, OH (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Insulating 5d³ La₃OsO₇ and the isostructural hole-doped analog La_2.8Ca_0.2OsO₇ that feature pseudo-one-dimensional zigzag chains of corner-sharing OsO₆ octahedra were synthesized and their magnetic and electrical transport properties characterized. Both of these compounds are insulating antiferromagnets. Moreover, for long range magnetic order between the antiferromagnetic chains we determined with a propagation vector k = 1/2,1/2,1 and T_N = 45 and 33 K the parent and doped materials. An Os⁵⁺ moment of 1.7(1)μ_B for La₃OsO₇ and 1.2(2)μ_B for La_2.8Ca_0.2OsO₇ is refined. The long range magnetic structure is compared to the isostructural compounds La₃RuO₇ and La₃MoO₇, both of which adopt different magnetic structures.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; FG02-95ER40900

OSTI ID:: 1295129

Alternate ID(s):: OSTI ID: 1222856

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 92, Issue 13; ISSN 1098-0121

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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Title: Magnetic structure of the quasi-one-dimensional $L a_{3} Os O_{7}$ as determined by neutron powder diffraction