135Cs/137Cs isotopic composition of environmental samples across Europe: Environmental transport and source term emission applications

Snow, Mathew S.; Snyder, Darin C.

doi:10.1016/j.jenvrad.2015.10.025

Title: ¹³⁵Cs/¹³⁷Cs isotopic composition of environmental samples across Europe: Environmental transport and source term emission applications

Journal Article · Mon Nov 02 00:00:00 EST 2015 · Journal of Environmental Radioactivity

DOI:https://doi.org/10.1016/j.jenvrad.2015.10.025· OSTI ID:1294348

Snow, Mathew S. ^[1]; Snyder, Darin C. ^[1]

Idaho National Lab. (INL), Idaho Falls, ID (United States)

¹³⁵Cs/¹³⁷Cs isotopic analyses represent an important tool for studying the fate and transport of radiocesium in the environment; in this work the ¹³⁵Cs/¹³⁷Cs isotopic composition in environmental samples taken from across Europe is reported. Surface soil and vegetation samples from western Russia, Ukraine, Austria, and Hungary show consistent aged thermal fission product ¹³⁵Cs/¹³⁷Cs isotope ratios of 0.58 ± 0.01 (age corrected to 1/1/15), with the exception of one sample of soil-moss from Hungary which shows an elevated ¹³⁵Cs/¹³⁷Cs ratio of 1.78 ± 0.12. With the exception of the outlier sample from Hungary, surface soil/vegetation data are in quantitative agreement with values previously reported for soils within the Chernobyl exclusion zone, suggesting that radiocesium at these locations is primarily composed of homogenous airborne deposition from Chernobyl. Seawater samples taken from the Irish Sea show ¹³⁵Cs/¹³⁷Cs isotope ratios of 1.22 ± 0.11 (age corrected to 1/1/15), suggesting aged thermal fission product Cs discharged from Sellafield. Furthermore, the differences in ¹³⁵Cs/¹³⁷Cs isotope ratios between Sellafield, Chernobyl, and global nuclear weapons testing fallout indicate that ¹³⁵Cs/¹³⁷Cs isotope ratios can be utilized to discriminate between and track radiocesium transport from different nuclear production source terms, including major emission sources in Europe.

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Research Organization:: Idaho National Lab. (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: 2012-DN-130-NF0001-02; AC07-05ID14517

OSTI ID:: 1294348

Alternate ID(s):: OSTI ID: 1397678

Report Number(s):: INL/JOU-15-36733; PII: S0265931X15301417

Journal Information:: Journal of Environmental Radioactivity, Vol. 151, Issue P1; ISSN 0265-931X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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References (24)

Pu-239+240 and Cs-137 in Montenegro soil: their correlation and origin Antovic, Nevenka M.; Vukotic, Perko; Svrkota, Nikola Journal of Environmental Radioactivity, Vol. 110 https://doi.org/10.1016/j.jenvrad.2012.02.001	journal	August 2012
Radionuclide activity concentrations in two species of reptiles from the Chernobyl exclusion zone Barnett, C. L.; Gaschak, S.; Beresford, N. A. Radioprotection, Vol. 44, Issue 5 https://doi.org/10.1051/radiopro/20095099	journal	January 2009
Radioactive fallout in Norway from atmospheric nuclear weapons tests Bergan, Tone D. Journal of Environmental Radioactivity, Vol. 60, Issue 1-2 https://doi.org/10.1016/S0265-931X(01)00103-5	journal	January 2002
Maximum reasonable radioxenon releases from medical isotope production facilities and their effect on monitoring nuclear explosions Bowyer, Theodore W.; Kephart, Rosara; Eslinger, Paul W. Journal of Environmental Radioactivity, Vol. 115 https://doi.org/10.1016/j.jenvrad.2012.07.018	journal	January 2013
Impacts of the Fukushima Nuclear Power Plants on Marine Radioactivity Buesseler, Ken; Aoyama, Michio; Fukasawa, Masao Environmental Science & Technology, Vol. 45, Issue 23 https://doi.org/10.1021/es202816c	journal	December 2011
Accumulation of radiocesium by mushrooms in the environment: a literature review Duff, Martine C.; Ramsey, Mary Lou Journal of Environmental Radioactivity, Vol. 99, Issue 6 https://doi.org/10.1016/j.jenvrad.2007.11.017	journal	June 2008
Radiation Doses from Hanford Site Releases to the Atmosphere and the Columbia River Farris, W. T.; Napier, B. A.; Ikenberry, T. A. Health Physics, Vol. 71, Issue 4 https://doi.org/10.1097/00004032-199610000-00016	journal	January 1996
Regional transport of radioxenon released from the Chalk River Laboratories medical isotope facility Johnson, Christine; Lowrey, Justin; Biegalski, Steven Journal of Radioanalytical and Nuclear Chemistry, Vol. 305, Issue 1 https://doi.org/10.1007/s10967-015-4077-6	journal	March 2015
Investigating uranium distribution in surface sediments and waters: a case study of contamination from the Juniper Uranium Mine, Stanislaus National Forest, CA Kayzar, Theresa M.; Villa, Adam C.; Lobaugh, Megan L. Journal of Environmental Radioactivity, Vol. 136 https://doi.org/10.1016/j.jenvrad.2014.04.018	journal	October 2014
Radionuclide Ratios in Precipitation on the Territory of Belarus After the Chernobyl Accident: Calculation from Gamma-Spectrometric Measurements on Soil in May–July 1986 Khrushchinskii, A. A.; Kuten’, S. A.; Minenko, V. F. Atomic Energy, Vol. 117, Issue 2 https://doi.org/10.1007/s10512-014-9902-4	journal	December 2014
First detection of fallout Cs-135 and potential applications of ratios Lee, Typhoon; Teh-Lung, Ku; Hsiao-Ling, Lu Geochimica et Cosmochimica Acta, Vol. 57, Issue 14 https://doi.org/10.1016/0016-7037(93)90555-B	journal	July 1993
Deposition of gamma emitters from Chernobyl accident and their transfer in lichen–soil columns Lehto, Jukka; Paatero, Jussi; Pehrman, Reijo Journal of Environmental Radioactivity, Vol. 99, Issue 10 https://doi.org/10.1016/j.jenvrad.2008.05.003	journal	October 2008
Sellafield waste radionuclides in Irish sea intertidal and salt marsh sediments MacKenzie, Angus B.; Scott, Roger D. Environmental Geochemistry and Health, Vol. 15, Issue 2-3 https://doi.org/10.1007/BF02627835	journal	September 1993
Plutonium and Americium Contamination near a Transuranic Storage Area in Southeastern Idaho Markham, O. D.; Puphal, K. W.; Filer, T. D. Journal of Environmental Quality, Vol. 7, Issue 3 https://doi.org/10.2134/jeq1978.00472425000700030026x	journal	July 1978
Further studies of the distribution of technetium-99 and caesium-137 in UK and European coastal waters McCubbin, David; Leonard, Kinson S.; Brown, Juan Continental Shelf Research, Vol. 22, Issue 10 https://doi.org/10.1016/S0278-4343(02)00021-3	journal	June 2002
Modeling of 137Cs migration in soils using an 80-year soil archive: role of fertilizers and agricultural amendments Monna, F.; van Oort, F.; Hubert, P. Journal of Environmental Radioactivity, Vol. 100, Issue 1 https://doi.org/10.1016/j.jenvrad.2008.09.009	journal	January 2009
Joint U.S./Russian Studies of Population Exposures Resulting From Nuclear Production Activities in the Southern Urals Napier, Bruce A. Health Physics, Vol. 106, Issue 2 https://doi.org/10.1097/HP.0000000000000033	journal	January 2014
Determination of 135Cs and 137Cs in environmental samples: A review Russell, B. C.; Croudace, Ian W.; Warwick, Phil E. Analytica Chimica Acta, Vol. 890 https://doi.org/10.1016/j.aca.2015.06.037	journal	August 2015
Analysis of cesium isotope compositions in environmental samples by thermal ionization mass spectrometry – 1. A preliminary study for source analysis of radioactive contamination in Fukushima prefecture: Fukushima NPP Accident Related Paper Shibahara, Yuji; Kubota, Takumi; Fujii, Toshiyuki Journal of Nuclear Science and Technology, Vol. 51, Issue 5 https://doi.org/10.1080/00223131.2014.891954	journal	March 2014
¹³⁷ Cs Activities and ¹³⁵ Cs/ ¹³⁷ Cs Isotopic Ratios from Soils at Idaho National Laboratory: A Case Study for Contaminant Source Attribution in the Vicinity of Nuclear Facilities Snow, Mathew S.; Snyder, Darin C.; Clark, Sue B. Environmental Science & Technology, Vol. 49, Issue 5 https://doi.org/10.1021/es5058852	journal	February 2015
Method for ultra-trace cesium isotope ratio measurements from environmental samples using thermal ionization mass spectrometry Snow, Mathew S.; Snyder, Darin C.; Mann, Nick R. International Journal of Mass Spectrometry, Vol. 381-382 https://doi.org/10.1016/j.ijms.2015.03.006	journal	May 2015
Radioactive cesium isotope ratios as a tool for determining dispersal and re-dispersal mechanisms downwind from the Nevada Nuclear Security Site Snyder, Darin C.; Delmore, James E.; Tranter, Troy Journal of Environmental Radioactivity, Vol. 110 https://doi.org/10.1016/j.jenvrad.2012.01.019	journal	August 2012
Preliminary evaluation of 135Cs/137Cs as a forensic tool for identifying source of radioactive contamination Taylor, V. F.; Evans, R. D.; Cornett, R. J. Journal of Environmental Radioactivity, Vol. 99, Issue 1 https://doi.org/10.1016/j.jenvrad.2007.07.006	journal	January 2008
¹³⁵ Cs/ ¹³⁷ Cs Isotopic Ratio as a New Tracer of Radiocesium Released from the Fukushima Nuclear Accident Zheng, Jian; Tagami, Keiko; Bu, Wenting Environmental Science & Technology, Vol. 48, Issue 10 https://doi.org/10.1021/es500403h	journal	May 2014

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Fukushima Daiichi reactor source term attribution using cesium isotope ratios from contaminated environmental samples: ¹³⁵ Cs/ ¹³⁷ Cs isotopic analyses Snow, Mathew S.; Snyder, Darin C.; Delmore, James E. Rapid Communications in Mass Spectrometry, Vol. 30, Issue 4 https://doi.org/10.1002/rcm.7468	journal	January 2016
Ultra-trace determination of the ¹³⁵ Cs/ ¹³⁷ Cs isotopic ratio by thermal ionization mass spectrometry with application to Fukushima marine sediment samples Bu, Wenting; Tang, Lei; Liu, Xuemei Journal of Analytical Atomic Spectrometry, Vol. 34, Issue 2 https://doi.org/10.1039/c8ja00380g	journal	January 2019
135Cs activity and 135Cs/137Cs atom ratio in environmental samples before and after the Fukushima Daiichi Nuclear Power Plant accident Yang, Guosheng; Tazoe, Hirofumi; Yamada, Masatoshi Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep24119	journal	April 2016
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Cs-135
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chernobyl
sellafield
attribution

Title: 135Cs/137Cs isotopic composition of environmental samples across Europe: Environmental transport and source term emission applications

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Title: ¹³⁵Cs/¹³⁷Cs isotopic composition of environmental samples across Europe: Environmental transport and source term emission applications