Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas

Alia, Shaun M.; Hurst, Katherine E.; Kocha, Shyam S.; Pivovar, Bryan S.

doi:10.1149/2.0071611jes

Title: Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas

Journal Article · Thu Jun 02 00:00:00 EDT 2016 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0071611jes· OSTI ID:1290786

Alia, Shaun M. ^[1]; Hurst, Katherine E. ^[1]; Kocha, Shyam S. ^[1]; Pivovar, Bryan S. ^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States). Chemical and Materials Science Center

Determining the surface areas of electrocatalysts is critical for separating the key properties of area-specific activity and electrochemical surface area from mass activity. Hydrogen underpotential deposition and carbon monoxide oxidation are typically used to evaluate iridium (Ir) surface areas, but are ineffective on oxides and can be sensitive to surface oxides formed on Ir metals. Mercury underpotential deposition is presented in this study as an alternative, able to produce reasonable surface areas on Ir and Ir oxide nanoparticles, and able to produce similar surface areas prior to and following characterization in oxygen evolution. Reliable electrochemical surface areas allow for comparative studies of different catalyst types and the characterization of advanced oxygen evolution catalysts. Lastly, they also enable the study of catalyst degradation in durability testing, both areas of increasing importance within electrolysis and electrocatalysis.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08GO28308; SC0007471

OSTI ID:: 1290786

Report Number(s):: NREL/JA-5900-66914

Journal Information:: Journal of the Electrochemical Society, Vol. 163, Issue 11; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 59 works

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References (38)

Kinetics of oxygen evolution and dissolution on platinum electrodes Damjanovic, A.; Dey, A.; Bockris, J. O'M. Electrochimica Acta, Vol. 11, Issue 7 https://doi.org/10.1016/0013-4686(66)87056-1	journal	July 1966
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes Sheng, Wenchao; Gasteiger, Hubert A.; Shao-Horn, Yang Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3483106	journal	January 2010
Molecular Insight in Structure and Activity of Highly Efficient, Low-Ir Ir–Ni Oxide Catalysts for Electrochemical Water Splitting (OER) Reier, Tobias; Pawolek, Zarina; Cherevko, Serhiy Journal of the American Chemical Society, Vol. 137, Issue 40 https://doi.org/10.1021/jacs.5b07788	journal	September 2015
Oxide-Supported IrNiO _x Core-Shell Particles as Efficient, Cost-Effective, and Stable Catalysts for Electrochemical Water Splitting Nong, Hong Nhan; Oh, Hyung-Suk; Reier, Tobias Angewandte Chemie International Edition, Vol. 54, Issue 10 https://doi.org/10.1002/anie.201411072	journal	January 2015
Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs3003098	journal	July 2012
Oxide-supported Ir nanodendrites with high activity and durability for the oxygen evolution reaction in acid PEM water electrolyzers Oh, Hyung-Suk; Nong, Hong Nhan; Reier, Tobias Chemical Science, Vol. 6, Issue 6 https://doi.org/10.1039/C5SC00518C	journal	January 2015
IrO2/Nb–TiO2 electrocatalyst for oxygen evolution reaction in acidic medium Hu, Wei; Chen, Shengli; Xia, Qinghua International Journal of Hydrogen Energy, Vol. 39, Issue 13 https://doi.org/10.1016/j.ijhydene.2014.02.114	journal	April 2014
Three-dimensional ordered macroporous IrO2 as electrocatalyst for oxygen evolution reaction in acidic medium Hu, Wei; Wang, Yaqin; Hu, Xiaohong Journal of Materials Chemistry, Vol. 22, Issue 13 https://doi.org/10.1039/c2jm16506f	journal	January 2012
Fine-tuning the activity of oxygen evolution catalysts: The effect of oxidation pre-treatment on size-selected Ru nanoparticles Paoli, Elisa Antares; Masini, Federico; Frydendal, Rasmus Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.10.005	journal	March 2016
Bimetallic Ru Electrocatalysts for the OER and Electrolytic Water Splitting in Acidic Media Forgie, Rhys; Bugosh, Greg; Neyerlin, K. C. Electrochemical and Solid-State Letters, Vol. 13, Issue 4 https://doi.org/10.1149/1.3290735	journal	January 2010
The oxygen evolution reaction on platinum, iridium, ruthenium and their alloys at 80°C in acid solutions Miles, M. H.; Klaus, E. A.; Gunn, B. P. Electrochimica Acta, Vol. 23, Issue 6 https://doi.org/10.1016/0013-4686(78)85030-0	journal	June 1978
Electrochemical Equilibria Pourbaix, Marcel; Staehle, Roger W.; Pourbaix, Marcel Lectures on Electrochemical Corrosion, p 83-183 https://doi.org/10.1007/978-1-4684-1806-4_4	book	January 1973
Activity and Durability of Iridium Nanoparticles in the Oxygen Evolution Reaction Alia, S. M.; Pylypenko, S.; Neyerlin, K. C. ECS Transactions, Vol. 69, Issue 17 https://doi.org/10.1149/06917.0883ecst	journal	September 2015
Hydrogen adsorption on platinum, iridium and rhodium electrodes at reduced temperatures and the determination of real surface area Woods, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 49, Issue 2 https://doi.org/10.1016/S0022-0728(74)80229-9	journal	January 1974
Hydrogen adsorption on iridium single-crystal surfaces Furuya, Nagakazu; Koide, Shoichiro Surface Science, Vol. 226, Issue 3 https://doi.org/10.1016/0039-6028(90)90487-S	journal	February 1990
Electrochemical Infrared Studies of Monocrystalline Iridium Surfaces. Part 2: Carbon Monoxide and Nitric Oxide Adsorption on Ir(110) Gómez, Roberto; Weaver, Michael J. Langmuir, Vol. 14, Issue 9 https://doi.org/10.1021/la9711692	journal	April 1998
Iridium Oxide Film Electrodes for Anodic Stripping Voltammetry Hull, Ewa; Piech, Robert; Kubiak, Władysław W. Electroanalysis, Vol. 20, Issue 19 https://doi.org/10.1002/elan.200804295	journal	October 2008
Deposition and Stripping Properties of Mercury on Iridium Electrodes Kounaves, S. P. Journal of The Electrochemical Society, Vol. 133, Issue 12 https://doi.org/10.1149/1.2108457	journal	January 1986
Solid-state Reactions of Mercury with Pure Noble Metals Part 2. Mercury–iridium system Fertonani, F. L.; Milaré, E.; Benedetti, A. V. Journal of Thermal Analysis and Calorimetry, Vol. 67, Issue 2, p. 403-410 https://doi.org/10.1023/A:1013943623673	journal	January 2002
An iridium based mercury film electrode Kounaves, S. P.; Buffle, J. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 239, Issue 1-2 https://doi.org/10.1016/0022-0728(88)80273-0	journal	January 1988
Calculating the Electrochemically Active Surface Area of Iridium Oxide in Operating Proton Exchange Membrane Electrolyzers Zhao, Shuai; Yu, Haoran; Maric, Radenka Journal of The Electrochemical Society, Vol. 162, Issue 12 https://doi.org/10.1149/2.0211512jes	journal	January 2015
Determining the Electrochemically Active Area of IrOx Powder Catalysts in an Operating Proton Exchange Membrane Electrolyzer Zhao, S.; Yu, H.; Maric, R. ECS Transactions, Vol. 69, Issue 17 https://doi.org/10.1149/06917.0877ecst	journal	September 2015
Experimental Methods for Quantifying the Activity of Platinum Electrocatalysts for the Oxygen Reduction Reaction Garsany, Yannick; Baturina, Olga A.; Swider-Lyons, Karen E. Analytical Chemistry, Vol. 82, Issue 15 https://doi.org/10.1021/ac100306c	journal	August 2010
Influence of iridium oxide loadings on the performance of PEM water electrolysis cells: Part I–Pure IrO 2 -based anodes Rozain, Caroline; Mayousse, Eric; Guillet, Nicolas Applied Catalysis B: Environmental, Vol. 182 https://doi.org/10.1016/j.apcatb.2015.09.013	journal	March 2016
“Inner” and “outer” active surface of RuO2 electrodes Ardizzone, S.; Fregonara, G.; Trasatti, S. Electrochimica Acta, Vol. 35, Issue 1 https://doi.org/10.1016/0013-4686(90)85068-X	journal	January 1990
Ruthenium dioxide-based film electrodes: III. Effect of chemical composition and surface morphology on oxygen evolution in acid solutions Lodi, G.; Sivieri, E.; De Battisti, A. Journal of Applied Electrochemistry, Vol. 8, Issue 2 https://doi.org/10.1007/BF00617671	journal	March 1978
Electrocatalysis in water electrolysis with solid polymer electrolyte Rasten, Egil; Hagen, Georg; Tunold, Reidar Electrochimica Acta, Vol. 48, Issue 25-26 https://doi.org/10.1016/j.electacta.2003.04.001	journal	November 2003
Impedance of hydrated iridium oxide electrodes Aurian-Blajeni, B.; Beebe, X.; Rauh, R. D. Electrochimica Acta, Vol. 34, Issue 6 https://doi.org/10.1016/0013-4686(89)87112-9	journal	June 1989
In vitro electrical properties for iridium oxide versus titanium nitride stimulating electrodes Weiland, J. D.; Anderson, D. J.; Humayun, M. S. IEEE Transactions on Biomedical Engineering, Vol. 49, Issue 12 https://doi.org/10.1109/TBME.2002.805487	journal	December 2002
Potential-Biased, Asymmetric Waveforms for Charge-Injection With Activated Iridium Oxide (AIROF) Neural Stimulation Electrodes Cogan, S. F.; Troyk, P. R.; Ehrlich, J. IEEE Transactions on Biomedical Engineering, Vol. 53, Issue 2 https://doi.org/10.1109/TBME.2005.862572	journal	February 2006
Charge Injection Properties of Thermally-Prepared Iridium Oxide Films Robblee, Lois S.; Mangaudis, Michael J.; Lasinsky, Ellen D. MRS Proceedings, Vol. 55 https://doi.org/10.1557/PROC-55-303	journal	January 1985
Neural Stimulation and Recording Electrodes Cogan, Stuart F. Annual Review of Biomedical Engineering, Vol. 10, Issue 1, p. 275-309 https://doi.org/10.1146/annurev.bioeng.10.061807.160518	journal	August 2008
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Carbon monoxide electrooxidation on well-characterized platinum-ruthenium alloys Gasteiger, Hubert A.; Markovic, Nenad; Ross, Philip N. The Journal of Physical Chemistry, Vol. 98, Issue 2 https://doi.org/10.1021/j100053a042	journal	January 1994
Measurement of oxygen reduction activities via the rotating disc electrode method: From Pt model surfaces to carbon-supported high surface area catalysts Mayrhofer, K. J. J.; Strmcnik, D.; Blizanac, B. B. Electrochimica Acta, Vol. 53, Issue 7 https://doi.org/10.1016/j.electacta.2007.11.057	journal	February 2008
Mechanism of Carbon Monoxide Electrooxidation on Monocrystalline Gold Surfaces: Identification of a Hydroxycarbonyl Intermediate Edens, Gregory J.; Hamelin, Antoinette; Weaver, Michael J. The Journal of Physical Chemistry, Vol. 100, Issue 6 https://doi.org/10.1021/jp9525604	journal	January 1996
Adsorption of carbon monoxide on a smooth palladium electrode: an in-situ infrared spectroscopic study Kunimatsu, Keiji The Journal of Physical Chemistry, Vol. 88, Issue 11 https://doi.org/10.1021/j150655a005	journal	May 1984
Trace determination of mercury by anodic stripping voltammetry at the rotating gold electrode Bonfil, Y.; Brand, M.; Kirowa-Eisner, E. Analytica Chimica Acta, Vol. 424, Issue 1 https://doi.org/10.1016/S0003-2670(00)01074-6	journal	November 2000

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Title: Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas

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