Prussian Blue MgLi Hybrid Batteries

Sun, Xiaoqi; Duffort, Victor; Nazar, Linda F.

doi:10.1002/advs.201600044

Title: Prussian Blue MgLi Hybrid Batteries

Journal Article · Fri Apr 15 00:00:00 EDT 2016 · Advanced Science

DOI:https://doi.org/10.1002/advs.201600044· OSTI ID:1290301

Sun, Xiaoqi ^[1]; Duffort, Victor ^[1]; Nazar, Linda F. ^[1]

Department of Chemistry University of Waterloo 200 University Ave W Waterloo Ontario N2L 3G1 Canada

The major advantage of Mg batteries relies on their promise of employing an Mg metal negative electrode, which offers much higher energy density compared to graphitic carbon. However, the strong coulombic interaction of Mg ²⁺ ions with anions leads to their sluggish diffusion in the solid state, which along with a high desolvation energy, hinders the development of positive electrode materials. To circumvent this limitation, Mg metal negative electrodes can be used in hybrid systems by coupling an Li ⁺ insertion cathode through a dual salt electrolyte. Two “high voltage” Prussian blue analogues (average 2.3 V vs Mg/Mg ²⁺ ; 3.0 V vs Li/Li ⁺ ) are investigated as cathode materials and the influence of structural water is shown. Their electrochemical profiles, presenting two voltage plateaus, are explained based on the two unique Fe bonding environments. Structural water has a beneficial impact on the cell voltage. Capacities of 125 mAh g ⁻¹ are obtained at a current density of 10 mA g ⁻¹ (≈C/10), while stable performance up to 300 cycles is demonstrated at 200 mA g ⁻¹ (≈2C). The hybrid cell design is a step toward building a safe and high density energy storage system.

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Sponsoring Organization:: USDOE

OSTI ID:: 1290301

Alternate ID(s):: OSTI ID: 1341091

Journal Information:: Advanced Science, Journal Name: Advanced Science Vol. 3 Journal Issue: 8; ISSN 2198-3844

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 77 works

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References (51)

Lithium intercalation behavior of iron cyanometallates Imanishi, N.; Morikawa, T.; Kondo, J. Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(98)00228-6	journal	September 1999
Rechargeable Ca-Ion Batteries: A New Energy Storage System Lipson, Albert L.; Pan, Baofei; Lapidus, Saul H. Chemistry of Materials, Vol. 27, Issue 24 https://doi.org/10.1021/acs.chemmater.5b04027	journal	December 2015
Reversible Aluminum-Ion Intercalation in Prussian Blue Analogs and Demonstration of a High-Power Aluminum-Ion Asymmetric Capacitor Li, Zheng; Xiang, Kai; Xing, Wenting Advanced Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aenm.201401410	journal	November 2014
Sodium uptake in cell construction and subsequent in operando electrode behaviour of Prussian blue analogues, Fe[Fe(CN) ₆ ] _1−x · y H ₂ O and FeCo(CN) ₆ Pramudita, James C.; Schmid, Siegbert; Godfrey, Thomas Phys. Chem. Chem. Phys., Vol. 16, Issue 44 https://doi.org/10.1039/C4CP02676D	journal	January 2014
Improved Electrolyte Solutions for Rechargeable Magnesium Batteries Gofer, Yosef; Chusid, Orit; Gizbar, Haim Electrochemical and Solid-State Letters, Vol. 9, Issue 5 https://doi.org/10.1149/1.2186003	journal	January 2006
Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries Wang, Richard Y.; Wessells, Colin D.; Huggins, Robert A. Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl403669a	journal	October 2013
Model study of chloride pitting in 18-8 stainless steel Novakovski, V. M.; Sorokina, A. N. Corrosion Science, Vol. 6, Issue 5 https://doi.org/10.1016/S0010-938X(66)80033-1	journal	January 1966
Spinel compounds as multivalent battery cathodes: a systematic evaluation based on ab initio calculations Liu, Miao; Rong, Ziqin; Malik, Rahul Energy & Environmental Science, Vol. 8, Issue 3 https://doi.org/10.1039/C4EE03389B	journal	January 2015
Electrolytic Conditioning of a Magnesium Aluminum Chloride Complex for Reversible Magnesium Deposition Barile, Christopher J.; Barile, Elizabeth C.; Zavadil, Kevin R. The Journal of Physical Chemistry C, Vol. 118, Issue 48 https://doi.org/10.1021/jp506951b	journal	November 2014
Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries Wu, Xianyong; Deng, Wenwen; Qian, Jiangfeng Journal of Materials Chemistry A, Vol. 1, Issue 35 https://doi.org/10.1039/c3ta12036h	journal	January 2013
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
High performance batteries based on hybrid magnesium and lithium chemistry Cheng, Yingwen; Shao, Yuyan; Zhang, Ji-Guang Chem. Commun., Vol. 50, Issue 68 https://doi.org/10.1039/C4CC03620D	journal	January 2014
Prototype systems for rechargeable magnesium batteries Aurbach, D.; Lu, Z.; Schechter, A. Nature, Vol. 407, Issue 6805, p. 724-727 https://doi.org/10.1038/35037553	journal	October 2000
Facile Method To Synthesize Na-Enriched Na _{1+ x} FeFe(CN) ₆ Frameworks as Cathode with Superior Electrochemical Performance for Sodium-Ion Batteries Li, Wei-Jie; Chou, Shu-Lei; Wang, Jia-Zhao Chemistry of Materials, Vol. 27, Issue 6 https://doi.org/10.1021/cm504091z	journal	March 2015
Sequence of steps in the pitting of aluminum by chloride ions McCafferty, E. Corrosion Science, Vol. 45, Issue 7 https://doi.org/10.1016/S0010-938X(02)00231-7	journal	July 2003
Mg rechargeable batteries: an on-going challenge Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279 https://doi.org/10.1039/c3ee40871j	journal	January 2013
A concept of dual-salt polyvalent-metal storage battery Yagi, Shunsuke; Ichitsubo, Tetsu; Shirai, Yoshimasa J. Mater. Chem. A, Vol. 2, Issue 4 https://doi.org/10.1039/C3TA13668J	journal	January 2014
High Areal Capacity Hybrid Magnesium–Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large-Scale Energy Storage Yoo, Hyun Deog; Liang, Yanliang; Li, Yifei ACS Applied Materials & Interfaces, Vol. 7, Issue 12 https://doi.org/10.1021/acsami.5b01206	journal	March 2015
Mg Desolvation and Intercalation Mechanism at the Mo ₆ S ₈ Chevrel Phase Surface Wan, Liwen F.; Perdue, Brian R.; Apblett, Christopher A. Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b01907	journal	August 2015
The High Performance of Crystal Water Containing Manganese Birnessite Cathodes for Magnesium Batteries Nam, Kwan Woo; Kim, Sangryun; Lee, Soyeon Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/acs.nanolett.5b01109	journal	May 2015
Water in minerals? A peak in the infrared Aines, Roger D.; Rossman, George R. Journal of Geophysical Research: Solid Earth, Vol. 89, Issue B6 https://doi.org/10.1029/JB089iB06p04059	journal	June 1984
A novel rechargeable battery with a magnesium anode, a titanium dioxide cathode, and a magnesium borohydride/tetraglyme electrolyte Su, Shuojian; Huang, Zhenguo; NuLi, Yanna Chemical Communications, Vol. 51, Issue 13 https://doi.org/10.1039/C4CC08774G	journal	January 2015
Electrochemical Stability of Magnesium Battery Current Collectors in a Grignard Reagent-Based Electrolyte Yagi, Shunsuke; Tanaka, Akira; Ichikawa, Yuya Journal of The Electrochemical Society, Vol. 160, Issue 3 https://doi.org/10.1149/2.033303jes	journal	January 2013
Synergetic Role of Li ⁺ during Mg Electrodeposition/Dissolution in Borohydride Diglyme Electrolyte Solution: Voltammetric Stripping Behaviors on a Pt Microelectrode Indicative of Mg–Li Alloying and Facilitated Dissolution Chang, Jinho; Haasch, Richard T.; Kim, Jinwoo ACS Applied Materials & Interfaces, Vol. 7, Issue 4 https://doi.org/10.1021/am507375t	journal	January 2015
Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries Wang, Long; Song, Jie; Qiao, Ruimin Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja510347s	journal	February 2015
A review on the problems of the solid state ions diffusion in cathodes for rechargeable Mg batteries Levi, E.; Levi, M. D.; Chasid, O. Journal of Electroceramics, Vol. 22, Issue 1-3 https://doi.org/10.1007/s10832-007-9370-5	journal	December 2007
Neutron diffraction study of Prussian Blue, Fe4[Fe(CN)6]3.xH2O. Location of water molecules and long-range magnetic order Herren, F.; Fischer, P.; Ludi, A. Inorganic Chemistry, Vol. 19, Issue 4 https://doi.org/10.1021/ic50206a032	journal	April 1980
Prussian Blues as a Cathode Material for Lithium Ion Batteries Shen, Lian; Wang, Zhaoxiang; Chen, Liquan Chemistry - A European Journal, Vol. 20, Issue 39 https://doi.org/10.1002/chem.201403061	journal	August 2014
Hybrid Mg ²⁺ /Li ⁺ Battery with Long Cycle Life and High Rate Capability Gao, Tao; Han, Fudong; Zhu, Yujie Advanced Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aenm.201401507	journal	November 2014
High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries You, Ya; Wu, Xing-Long; Yin, Ya-Xia Energy Environ. Sci., Vol. 7, Issue 5 https://doi.org/10.1039/C3EE44004D	journal	January 2014
Study of the Fe(CN)3−6/Fe(CN)4−6 redox system on Pt by EMIRS Kunimatsu, K.; Shigematsu, Y.; Uosaki, K. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 262, Issue 1-2 https://doi.org/10.1016/0022-0728(89)80022-1	journal	April 1989
Electrochemically stable cathode current collectors for rechargeable magnesium batteries Cheng, Yingwen; Liu, Tianbiao; Shao, Yuyan J. Mater. Chem. A, Vol. 2, Issue 8 https://doi.org/10.1039/C3TA15113A	journal	January 2014
Conflat Two and Three Electrode Electrochemical Cells Periyapperuma, Kalani; Tran, Tuan T.; Trussler, Simon Journal of The Electrochemical Society, Vol. 161, Issue 14 https://doi.org/10.1149/2.0721414jes	journal	January 2014
Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries Mizrahi, Oren; Amir, Nir; Pollak, Elad Journal of The Electrochemical Society, Vol. 155, Issue 2, p. A103-A109 https://doi.org/10.1149/1.2806175	journal	January 2008
Improving the Electrochemical Performance of the Li ₄ Ti ₅ O ₁₂ Electrode in a Rechargeable Magnesium Battery by Lithium-Magnesium Co-Intercalation Wu, Na; Yang, Zhen-Zhong; Yao, Hu-Rong Angewandte Chemie, Vol. 127, Issue 19 https://doi.org/10.1002/ange.201501005	journal	March 2015
Structural and magnetic properties of $Fe [Fe {(C N)}_{6}] ∙ 4 H_{2} O$ Kumar, Amit; Yusuf, S. M.; Keller, L. Physical Review B, Vol. 71, Issue 5 https://doi.org/10.1103/PhysRevB.71.054414	journal	February 2005
Bimetallic Cyanide-Bridged Coordination Polymers as Lithium Ion Cathode Materials: Core@Shell Nanoparticles with Enhanced Cyclability Asakura, Daisuke; Li, Carissa H.; Mizuno, Yoshifumi Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312160v	journal	February 2013
A Superior Low-Cost Cathode for a Na-Ion Battery Wang, Long; Lu, Yuhao; Liu, Jue Angewandte Chemie, Vol. 125, Issue 7 https://doi.org/10.1002/ange.201206854	journal	January 2013
Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries Lee, Hyun-Wook; Wang, Richard Y.; Pasta, Mauro Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6280	journal	October 2014
Investigation of the Mechanism of Mg Insertion in Birnessite in Nonaqueous and Aqueous Rechargeable Mg-Ion Batteries Sun, Xiaoqi; Duffort, Victor; Mehdi, B. Layla Chemistry of Materials, Vol. 28, Issue 2 https://doi.org/10.1021/acs.chemmater.5b03983	journal	January 2016
Corrosion of magnesium electrolytes: chlorides – the culprit Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G. Energy Environ. Sci., Vol. 6, Issue 2, p. 482-487 https://doi.org/10.1039/C2EE23686A	journal	December 2012
Controlling the Intercalation Chemistry to Design High-Performance Dual-Salt Hybrid Rechargeable Batteries Cho, Jae-Hyun; Aykol, Muratahan; Kim, Soo Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja508463z	journal	November 2014
Removal of Interstitial H ₂ O in Hexacyanometallates for a Superior Cathode of a Sodium-Ion Battery Song, Jie; Wang, Long; Lu, Yuhao Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja512383b	journal	February 2015
Fourier transform infrared photothermal spectroscopic characterization of Prussian blue surface modified electrodes. Counter cation effects Crumbliss, Alvin L.; Lugg, Paul S.; Childers, Jeffrey W. The Journal of Physical Chemistry, Vol. 89, Issue 3 https://doi.org/10.1021/j100249a023	journal	January 1985
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
Dual-Salt Mg-Based Batteries with Conversion Cathodes Zhang, Ye; Xie, Junjie; Han, Yanlin Advanced Functional Materials, Vol. 25, Issue 47 https://doi.org/10.1002/adfm.201503639	journal	November 2015
A Superior Low-Cost Cathode for a Na-Ion Battery Wang, Long; Lu, Yuhao; Liu, Jue Angewandte Chemie International Edition, Vol. 52, Issue 7 https://doi.org/10.1002/anie.201206854	journal	January 2013
Whole powder pattern decomposition methods and applications: A retrospection Le Bail, Armel Powder Diffraction, Vol. 20, Issue 4 https://doi.org/10.1154/1.2135315	journal	December 2005
Electrolyte roadblocks to a magnesium rechargeable battery Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G. Energy & Environmental Science, Vol. 5, Issue 3, p. 5941-5950 https://doi.org/10.1039/c2ee03029b	journal	January 2012
Improving the Electrochemical Performance of the Li ₄ Ti ₅ O ₁₂ Electrode in a Rechargeable Magnesium Battery by Lithium-Magnesium Co-Intercalation Wu, Na; Yang, Zhen-Zhong; Yao, Hu-Rong Angewandte Chemie International Edition, Vol. 54, Issue 19 https://doi.org/10.1002/anie.201501005	journal	March 2015
Spectral Characterization of Redox-Active Prussian blue on Metallated Plasma Polymer Surface Modified Carbon Electrodes Using Photothermal Detection Childers, J. W.; Crumbliss, A. L.; Lugg, P. S. Le Journal de Physique Colloques, Vol. 44, Issue C6 https://doi.org/10.1051/jphyscol:1983645	journal	October 1983

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