Effect of Dopants on the Adsorption of Carbon Dioxide on Ceria Surfaces

Li, Meijun; Tumuluri, Uma; Wu, Zili; Dai, Sheng

doi:10.1002/cssc.201500899

Effect of Dopants on the Adsorption of Carbon Dioxide on Ceria Surfaces

Journal Article · Fri Sep 25 04:00:00 EDT 2015 · ChemSusChem (Online)

DOI:https://doi.org/10.1002/cssc.201500899· OSTI ID:1286871

Li, Meijun ^[1]; Tumuluri, Uma ^[2]; Wu, Zili ^[2]; Dai, Sheng ^[3]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Here, high-surface-area nanosized CeO₂ and M-doped CeO₂ (M=Cu, La, Zr, and Mg) prepared by a surfactant-templated method were tested for CO₂ adsorption. Cu, La, and Zr are doped into the lattice of CeO₂, whereas Mg is dispersed on the CeO₂ surface. The doping of Cu and La into CeO₂ leads to an increase of the CO₂ adsorption capacity, whereas the doping of Zr has little or no effect. The addition of Mg causes a decrease of the CO₂ adsorption capacity at a low Mg content and a gradual increase at a higher content. The CO₂ adsorption capacity follows the sequence Cu-CeO₂>La-CeO₂>Zr-CeO₂≈CeO₂>Mg-CeO₂ at low dopant contents, in line with the relative amount of defect sites in the samples. It is the defect sites on the surface, not in the bulk of CeO₂, modified by the dopants that play the vital role in CO₂ chemisorption. Lastly, the role of surface oxygen vacancies is further supported by an in situ IR spectroscopic study of the surface chemistry during CO₂ adsorption on the doped CeO₂.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725; SC0012577

OSTI ID:: 1286871

Journal Information:: ChemSusChem (Online), Journal Name: ChemSusChem (Online) Journal Issue: 21 Vol. 8; ISSN 1864-564X

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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