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Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance

Journal Article · · Nature (London)
DOI:https://doi.org/10.1038/nature13970· OSTI ID:1286827
 [1];  [1];  [1];  [1];  [1]
  1. Drexel Univ., Philadelphia, PA (United States). Department of Materials Science and Engineering, and A. J. Drexel Nanomaterials Institute
Safe and powerful energy storage devices are becoming increasingly important. Charging times of seconds to minutes, with power densities exceeding those of batteries, can in principle be provided by electrochemical capacitors—in particular, pseudocapacitors. Recent research has focused mainly on improving the gravimetric performance of the electrodes of such systems, but for portable electronics and vehicles volume is at a premium. The best volumetric capacitances of carbon-based electrodes are around 300 farads per cubic centimetre; hydrated ruthenium oxide can reach capacitances of 1,000 to 1,500 farads per cubic centimetre with great cyclability, but only in thin films. Recently, electrodes made of two-dimensional titanium carbide (Ti3C2, a member of the ‘MXene’ family), produced by etching aluminium from titanium aluminium carbide (Ti3AlC2, a ‘MAX’ phase) in concentrated hydrofluoric acid, have been shown to have volumetric capacitances of over 300 farads per cubic centimetre. In this paper, we report a method of producing this material using a solution of lithium fluoride and hydrochloric acid. The resulting hydrophilic material swells in volume when hydrated, and can be shaped like clay and dried into a highly conductive solid or rolled into films tens of micrometres thick. Additive-free films of this titanium carbide ‘clay’ have volumetric capacitances of up to 900 farads per cubic centimetre, with excellent cyclability and rate performances. In addition, this capacitance is almost twice that of our previous report, and our synthetic method also offers a much faster route to film production as well as the avoidance of handling hazardous concentrated hydrofluoric acid.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1286827
Alternate ID(s):
OSTI ID: 1210702
OSTI ID: 1387371
Journal Information:
Nature (London), Journal Name: Nature (London) Journal Issue: 7529 Vol. 516; ISSN 0028-0836
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

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Ecotoxicological assessment of Ti 3 C 2 T x (MXene) using a zebrafish embryo model journal January 2018
Phase transition and in situ construction of lateral heterostructure of 2D superconducting α/β Mo 2 C with sharp interface by electron beam irradiation journal January 2017
A binder-free NiCo 2 O 4 nanosheet/3D elastic N-doped hollow carbon nanotube sponge electrode with high volumetric and gravimetric capacitances for asymmetric supercapacitors journal January 2017
2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes) journal January 2017
Ratiometric photoluminescence sensing based on Ti 3 C 2 MXene quantum dots as an intracellular pH sensor journal January 2018
3D assembly of Ti 3 C 2 -MXene directed by water/oil interfaces journal January 2018
The influence of surface functionalization on thermal transport and thermoelectric properties of MXene monolayers journal January 2018
Free-standing Ti 3 C 2 T x electrode with ultrahigh volumetric capacitance journal January 2017
Enhanced thermal properties of poly(vinylidene fluoride) composites with ultrathin nanosheets of MXene journal January 2017
Construction of cost-effective bimetallic nanoparticles on titanium carbides as a superb catalyst for promoting hydrolysis of ammonia borane journal January 2018
Ti 3 C 2 MXene: a promising microwave absorbing material journal January 2018
Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers journal January 2017
Recent progresses in high-energy-density all pseudocapacitive-electrode-materials-based asymmetric supercapacitors journal January 2017
Ti 2 CO 2 MXene: a highly active and selective photocatalyst for CO 2 reduction journal January 2017
An easily manipulated protocol for patterning of MXenes on paper for planar micro-supercapacitors journal January 2017
Recent advances in ternary two-dimensional materials: synthesis, properties and applications journal January 2017
Graphene-coupled Ti 3 C 2 MXenes-derived TiO 2 mesostructure: promising sodium-ion capacitor anode with fast ion storage and long-term cycling journal January 2018
Electronic properties and applications of MXenes: a theoretical review journal January 2017
Dynamic charge acceptance and hydrogen evolution of a new MXene additive in advanced lead-acid batteries via a rapid screening three-electrode method journal January 2018
Alkali-induced crumpling of Ti 3 C 2 T x (MXene) to form 3D porous networks for sodium ion storage journal January 2018
High-capacitance Ti 3 C 2 T x MXene obtained by etching submicron Ti 3 AlC 2 grains grown in molten salt journal January 2018
MXene-supported Co 3 O 4 quantum dots for superior lithium storage and oxygen evolution activities journal January 2019
Modified MXene: promising electrode materials for constructing Ohmic contacts with MoS 2 for electronic device applications journal January 2018
Two-dimensional stable transition metal carbides (MnC and NbC) with prediction and novel functionalizations journal January 2018
Preparation of 2D material dispersions and their applications journal January 2018
Two-dimensional materials for miniaturized energy storage devices: from individual devices to smart integrated systems journal January 2018
Topochemical synthesis of 2D materials journal January 2018
Liquid catalysts: an innovative solution to 2D materials in CVD processes journal January 2018
2D MXene-containing polymer electrolytes for all-solid-state lithium metal batteries journal January 2019
Oxidized Ti 3 C 2 MXene nanosheets for dye-sensitized solar cells journal January 2018
Anchoring ultrafine RhNi nanoparticles on titanium carbides/manganese oxide as an efficient catalyst for hydrogen generation from hydrous hydrazine journal January 2018
Binder-free 2D titanium carbide (MXene)/carbon nanotube composites for high-performance lithium-ion capacitors journal January 2018
Bipolar magnetic semiconductors among intermediate states during the conversion from Sc 2 C(OH) 2 to Sc 2 CO 2 MXene journal January 2018
A nanoporous MXene film enables flexible supercapacitors with high energy storage journal January 2018
Inherent electrochemistry and charge transfer properties of few-layered two-dimensional Ti 3 C 2 T x MXene journal January 2018
Polyoxometalate-coupled MXene nanohybrid via poly(ionic liquid) linkers and its electrode for enhanced supercapacitive performance journal January 2018
Fluorescent Ti 3 C 2 MXene quantum dots for an alkaline phosphatase assay and embryonic stem cell identification based on the inner filter effect journal January 2018
3D Ti 3 C 2 T x aerogels with enhanced surface area for high performance supercapacitors journal January 2018
A generalized strategy for the synthesis of two-dimensional metal oxide nanosheets based on a thermoregulated phase transition journal January 2019
Tailoring Ti 3 C 2 T x nanosheets to tune local conductive network as an environmentally friendly material for highly efficient electromagnetic interference shielding journal January 2019
NiMoO 4 nanorod deposited carbon sponges with ant-nest-like interior channels for high-performance pseudocapacitors journal January 2018
A novel MnO 2 /MXene composite prepared by electrostatic self-assembly and its use as an electrode for enhanced supercapacitive performance journal January 2019
A novel lithium-ion hybrid capacitor based on an aerogel-like MXene wrapped Fe 2 O 3 nanosphere anode and a 3D nitrogen sulphur dual-doped porous carbon cathode journal January 2018
Ni-modified Ti 3 C 2 MXene with enhanced microwave absorbing ability journal January 2018
Concisely modularized assembling of graphene-based thin films with promising electrode performance journal January 2019
Adsorptive environmental applications of MXene nanomaterials: a review journal January 2018
Antibacterial properties of electrospun Ti 3 C 2 T z (MXene)/chitosan nanofibers journal January 2018
Polypyrrole–MXene coated textile-based flexible energy storage device journal January 2018
High-throughput theoretical optimization of the hydrogen evolution reaction on MXenes by transition metal modification journal January 2018
Highly efficient photoelectrocatalytic reduction of CO 2 on the Ti 3 C 2 /g-C 3 N 4 heterojunction with rich Ti 3+ and pyri-N species journal January 2018
Selective gas diffusion in two-dimensional MXene lamellar membranes: insights from molecular dynamics simulations journal January 2018
Binder-free bonding of modularized MXene thin films into thick film electrodes for on-chip micro-supercapacitors with enhanced areal performance metrics journal January 2018
A hydrophobic surface enabled salt-blocking 2D Ti 3 C 2 MXene membrane for efficient and stable solar desalination journal January 2018
Ti 3 C 2 MXene as an excellent anode material for high-performance microbial fuel cells journal January 2018
Transition metal modification and carbon vacancy promoted Cr 2 CO 2 (MXenes): a new opportunity for a highly active catalyst for the hydrogen evolution reaction journal January 2018
Synthesis, stabilization and applications of 2-dimensional 1T metallic MoS 2 journal January 2018
Enhanced electrocatalytic activity by chemical nitridation of two-dimensional titanium carbide MXene for hydrogen evolution journal January 2018
Carbon-intercalated Ti 3 C 2 T x MXene for high-performance electrochemical energy storage journal January 2018
Ti 3 C 2 T x (T = F, OH) MXene nanosheets: conductive 2D catalysts for ambient electrohydrogenation of N 2 to NH 3 journal January 2018
Recent progress in flexible non-lithium based rechargeable batteries journal January 2019
Heterostructures of Ni–Co–Al layered double hydroxide assembled on V 4 C 3 MXene for high-energy hybrid supercapacitors journal January 2019
2D magnetic titanium carbide MXene for cancer theranostics journal January 2018
Hierarchically structured cellulose aerogels with interconnected MXene networks and their enhanced microwave absorption properties journal January 2018
Topochemical synthesis of phase-pure Mo 2 AlB 2 through staging mechanism journal January 2019
Alkali-induced 3D crinkled porous Ti 3 C 2 MXene architectures coupled with NiCoP bimetallic phosphide nanoparticles as anodes for high-performance sodium-ion batteries journal January 2019
Novel insights into the charge storage mechanism in pseudocapacitive vanadium nitride thick films for high-performance on-chip micro-supercapacitors journal January 2020
Ti n+1 C n MXenes with fully saturated and thermally stable Cl terminations journal January 2019
Mo 2 B, an MBene member with high electrical and thermal conductivities, and satisfactory performances in lithium ion batteries journal January 2020
MXene and MXene-based composites: synthesis, properties and environment-related applications journal January 2020
A highly flexible and multifunctional strain sensor based on a network-structured MXene/polyurethane mat with ultra-high sensitivity and a broad sensing range journal January 2019
Configurable multi-state non-volatile memory behaviors in Ti 3 C 2 nanosheets journal January 2019
Recent advances in micro-supercapacitors journal January 2019
Heterostructure engineering of Co-doped MoS 2 coupled with Mo 2 CT x MXene for enhanced hydrogen evolution in alkaline media journal January 2019
Integrating ultrathin and modified NiCoAl-layered double-hydroxide nanosheets with N-doped reduced graphene oxide for high-performance all-solid-state supercapacitors journal January 2019
A two-dimensional assembly of ultrafine cobalt oxide nanocrystallites anchored on single-layer Ti 3 C 2 T x nanosheets with enhanced lithium storage for Li-ion batteries journal January 2019
Single molybdenum atom anchored on 2D Ti 2 NO 2 MXene as a promising electrocatalyst for N 2 fixation journal January 2019
Monolayer MBenes: prediction of anode materials for high-performance lithium/sodium ion batteries journal January 2019
Ti 3 C 2 MXene quantum dot-encapsulated liposomes for photothermal immunoassays using a portable near-infrared imaging camera on a smartphone journal January 2019
Two-dimensional composite of D-Ti 3 C 2 T x @S@TiO 2 (MXene) as the cathode material for aluminum-ion batteries journal January 2020
Improving the performance of a titanium carbide MXene in supercapacitors by partial oxidation treatment journal January 2020
A high-performance trace level acetone sensor using an indispensable V 4 C 3 T x MXene journal January 2020
Hierarchical Ni 2 P/Cr 2 CT x (MXene) composites with oxidized surface groups as efficient bifunctional electrocatalysts for overall water splitting journal January 2019
Surface nitrogen-modified 2D titanium carbide (MXene) with high energy density for aqueous supercapacitor applications journal January 2019
Two-dimensional Ti 2 CT x MXene membranes with integrated and ordered nanochannels for efficient solvent dehydration journal January 2019
Intercalation and delamination behavior of Ti 3 C 2 T x and MnO 2 /Ti 3 C 2 T x /RGO flexible fibers with high volumetric capacitance journal January 2019
Pursuit of a high-capacity and long-life Mg-storage cathode by tailoring sandwich-structured MXene@carbon nanosphere composites journal January 2019
Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors journal January 2019
Multilayer structured AgNW/WPU-MXene fiber strain sensors with ultrahigh sensitivity and a wide operating range for wearable monitoring and healthcare journal January 2019
Unveiling highly ambient-stable multilayered 1T-MoS 2 towards all-solid-state flexible supercapacitors journal January 2019
Recent advances in exfoliation techniques of layered and non-layered materials for energy conversion and storage journal January 2019
Few-layered Ti 3 C 2 T x MXenes coupled with Fe 2 O 3 nanorod arrays grown on carbon cloth as anodes for flexible asymmetric supercapacitors journal January 2019
Titanium carbide MXenes combined with red-emitting carbon dots as a unique turn-on fluorescent nanosensor for label-free determination of glucose journal January 2019
Ti 3 C 2 T x MXene-derived TiO 2 /C-QDs as oxidase mimics for the efficient diagnosis of glutathione in human serum journal January 2020
O-Vacancy-line defective Ti 2 CO 2 nanoribbons: novel magnetism, tunable carrier mobility, and magnetic device behaviors journal January 2019
Multilayer-structured transparent MXene/PVDF film with excellent dielectric and energy storage performance journal January 2019
Superconductivity of monolayer Mo 2 C: The key role of functional groups journal January 2017
Emergence of ferrimagnetic half-metallicity in two-dimensional MXene Mo 3 N 2 F 2 journal November 2017
Rendering Ti 3 C 2 T x (MXene) monolayers visible journal February 2017
Design of a graphene-based core–shell structure for the improvement of photothermic performance journal October 2019
Polybenzimidazole/Mxene composite membranes for intermediate temperature polymer electrolyte membrane fuel cells journal December 2017
Hydrothermal synthesis of stable metallic 1T phase WS 2 nanosheets for thermoelectric application journal December 2017
High areal capacitance of vanadium oxides intercalated Ti 3 C 2 MXene for flexible supercapacitors with high mass loading journal January 2020
Graphene based 2D-materials for supercapacitors journal July 2015
On the organization and thermal behavior of functional groups on Ti 3 C 2 MXene surfaces in vacuum journal October 2017
On tuning the cytotoxicity of Ti 3 C 2 (MXene) flakes to cancerous and benign cells by post-delamination surface modifications journal February 2020
Excellent air and water stability of two-dimensional black phosphorene/MXene heterostructure journal March 2019
First-principles study of size- and edge-dependent properties of MXene nanoribbons journal March 2016
Stabilization and strengthening effects of functional groups in two-dimensional titanium carbide journal September 2016
Prediction and synthesis of a family of atomic laminate phases with Kagomé-like and in-plane chemical ordering journal July 2017
MXenes stretch hydrogel sensor performance to new limits journal June 2018
Elastic properties of 2D Ti 3 C 2 T x MXene monolayers and bilayers journal June 2018
2D titanium carbide (MXene) for wireless communication journal September 2018
Atomic-level structure engineering of metal oxides for high-rate oxygen intercalation pseudocapacitance journal October 2018
Electromagnetic interference shielding with 2D transition metal carbides (MXenes) journal September 2016
First-principles investigation of the vacancy-related properties of Ta 2 AlC journal June 2019
An Inkjet Printed Ti 3 C 2 -GO Electrode for the Electrochemical Sensing of Hydrogen Peroxide journal January 2018
Review—Two-Dimensional Titanium Carbide MXenes and Their Emerging Applications as Electrochemical Sensors journal January 2020
Review— Recent Exploration of Two-Dimensional MXenes for Gas Sensing: From a Theoretical to an Experimental View journal January 2020
Synergistic Supercritical Water ‘Wet’ Activated Biomass Carbon as High Performances Electrode Materials for Supercapacitor journal January 2018
High-Voltage Symmetric Supercapacitor Based on 2D Titanium Carbide (MXene, Ti 2 CT x )/Carbon Nanosphere Composites in a Neutral Aqueous Electrolyte journal January 2018
Preparation of High-Purity V 2 C MXene and Electrochemical Properties as Li-Ion Batteries journal January 2017
Room Temperature Oxidation of Ti 3 C 2 MXene for Supercapacitor Electrodes journal January 2017
Carbon-Coated SnO 2 /Ti 3 C 2 Composites with Enhanced Lithium Storage Performance journal October 2019
2D/2D Heterojunction of R-scheme Ti3C2 MXene/MoS2 Nanosheets for Enhanced Photocatalytic Performance journal April 2020
Ti 2 AlC-based saturable absorber for passive Q-switching of a fiber laser journal January 2019
2D Ti3C2Tx (MXene)-reinforced polyvinyl alcohol (PVA) nanofibers with enhanced mechanical and electrical properties journal August 2017
Rechargeable Mg–Li hybrid batteries: status and challenges journal September 2016
State of the Art in Alcohol Sensing with 2D Materials text January 2020
Potential-Dependent, Switchable Ion Selectivity in Aqueous Media Using Titanium Disulfide collection January 2018
Measurement and Analysis of Thermal Conductivity of Ti3C2Tx MXene Films journal September 2018
The Synthesis Process and Thermal Stability of V2C MXene journal October 2018
Three-Dimensional Porous Ti3C2Tx-NiO Composite Electrodes with Enhanced Electrochemical Performance for Supercapacitors journal January 2019
Investigation of Enhanced Leaching of Lithium from α-Spodumene Using Hydrofluoric and Sulfuric Acid journal October 2017
Functionalization of MXene Nanosheets for Polystyrene towards High Thermal Stability and Flame Retardant Properties journal June 2019
Laser-sculptured ultrathin transition metal carbide layers for energy storage and energy harvesting applications text January 2019

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