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Materials Data on SbRhO4 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1282557· OSTI ID:1282557
RhSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent RhO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Rh–O bond lengths are 2.05 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with eight equivalent RhO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two shorter (2.01 Å) and four longer (2.05 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to two equivalent Rh3+ and one Sb5+ atom. In the second O2- site, O2- is bonded in a trigonal planar geometry to one Rh3+ and two equivalent Sb5+ atoms.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1282557
Report Number(s):
mp-675025
Country of Publication:
United States
Language:
English

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