Materials Data on V5Si3 by Materials Project

Dataset · Wed Jul 15 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1275731· OSTI ID:1275731

The Materials Project

V5Si3 crystallizes in the hexagonal P6_3/mcm space group. The structure is three-dimensional. there are two inequivalent V+2.40+ sites. In the first V+2.40+ site, V+2.40+ is bonded to five equivalent Si4- atoms to form a mixture of distorted corner and edge-sharing VSi5 trigonal bipyramids. There are a spread of V–Si bond distances ranging from 2.46–2.65 Å. In the second V+2.40+ site, V+2.40+ is bonded in a 6-coordinate geometry to two equivalent V+2.40+ and six equivalent Si4- atoms. Both V–V bond lengths are 2.42 Å. All V–Si bond lengths are 2.50 Å. Si4- is bonded in a 9-coordinate geometry to nine V+2.40+ atoms.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1275731
• Report Number(s): mp-570483
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
V5Si3
Si-V