Effect of Molecular Weight on the Ion Transport Mechanism in Polymerized Ionic Liquids

Fan, Fei; Wang, Weiyu; Holt, Adam P.; Feng, Hongbo; Uhrig, David; Lu, Xinyi; Hong, Tao; Wang, Yangyang; Kang, Nam-Goo; Mays, Jimmy; Sokolov, Alexei P.

doi:10.1021/acs.macromol.6b00714

Effect of Molecular Weight on the Ion Transport Mechanism in Polymerized Ionic Liquids

Journal Article · Tue Jun 07 00:00:00 EDT 2016 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.6b00714· OSTI ID:1271895

Fan, Fei ^[1]; Wang, Weiyu ^[2]; Holt, Adam P. ^[1]; Feng, Hongbo ^[1]; Uhrig, David ^[2]; Lu, Xinyi ^[1]; Hong, Tao ^[1]; Wang, Yangyang ^[2]; Kang, Nam-Goo ^[1]; Mays, Jimmy ^[3]; Sokolov, Alexei P. ^[4]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States) ; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The unique properties of ionic liquids (ILs) have made them promising candidates for electrochemical applications. Polymerization of the corresponding ILs results in a new class of materials called polymerized ionic liquids (PolyILs). Though PolyILs offer the possibility to combine the high conductivity of ILs and the high mechanical strength of polymers, their conductivities are typically much lower than that of the corresponding small molecule ILs. In this study, seven PolyILs were synthesized having degrees of polymerization ranging from 1 to 333, corresponding to molecular weights (MW) from 482 to 160 400 g/mol. Depolarized dynamic light scattering, broadband dielectric spectroscopy, rheology, and differential scanning calorimetry were employed to systematically study the influence of MW on the mechanism of ionic transport and segmental dynamics in these materials. Finally, the modified Walden plot analysis reveals that the ion conductivity transforms from being closely coupled with structural relaxation to being strongly decoupled from it as MW increases.

View Accepted Manuscript (DOE)

Research Organization:: High Temperature Materials Laboratory (HTML); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1271895

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 12 Vol. 49; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Structure and dynamics of short-chain polymerized ionic liquids Wieland, F.; Bocharova, V.; Münzner, P. The Journal of Chemical Physics, Vol. 151, Issue 3 https://doi.org/10.1063/1.5109228	journal	July 2019
Ionoelastomer junctions between polymer networks of fixed anions and cations Kim, Hyeong Jun; Chen, Baohong; Suo, Zhigang Science, Vol. 367, Issue 6479 https://doi.org/10.1126/science.aay8467	journal	February 2020
Block Copolymers: Synthesis, Self-Assembly, and Applications Feng, Hongbo; Lu, Xinyi; Wang, Weiyu Polymers, Vol. 9, Issue 12 https://doi.org/10.3390/polym9100494	journal	October 2017
Decoupling segmental relaxation and ionic conductivity for lithium-ion polymer electrolytes Bresser, Dominic; Lyonnard, S.; Iojoiu, C. Karlsruhe https://doi.org/10.5445/ir/1000097584	text	January 2019

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