Size-dependent phase transition in methylammonium lead iodide perovskite microplate crystals

Li, Dehui; Wang, Gongming; Cheng, Hung -Chieh; Chen, Chih -Yen; Wu, Hao; Liu, Yuan; Huang, Yu; Duan, Xiangfeng

doi:10.1038/ncomms11330

Size-dependent phase transition in methylammonium lead iodide perovskite microplate crystals

Journal Article · Thu Apr 21 00:00:00 EDT 2016 · Nature Communications

DOI:https://doi.org/10.1038/ncomms11330· OSTI ID:1270965

Li, Dehui ^[1]; Wang, Gongming ^[2]; Cheng, Hung -Chieh ^[3]; Chen, Chih -Yen ^[4]; Wu, Hao ^[3]; Liu, Yuan ^[3]; Huang, Yu ^[5]; Duan, Xiangfeng ^[2]

Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry; Univ. of California, Los Angeles, CA (United States)
Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry, CA Nanosystems Inst.
Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering
Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry
Univ. of California, Los Angeles, CA (United States). CA Nanosystems Inst., Dept. of Materials Science and Engineering

Methylammonium lead iodide perovskite has attracted considerable recent interest for solution processable solar cells and other optoelectronic applications. The orthorhombic-to-tetragonal phase transition in perovskite can significantly alter its optical, electrical properties and impact the corresponding applications. Here, we report a systematic investigation of the size-dependent orthorhombic-to-tetragonal phase transition using a combined temperature-dependent optical, electrical transport and transmission electron microscopy study. Our studies of individual perovskite microplates with variable thicknesses demonstrate that the phase transition temperature decreases with reducing microplate thickness. The sudden decrease of mobility around phase transition temperature and the presence of hysteresis loops in the temperature-dependent mobility confirm that the orthorhombic-to-tetragonal phase transition is a first-order phase transition. Lastly, our findings offer significant fundamental insight on the temperature-and size-dependent structural, optical and charge transport properties of perovskite materials, and can greatly impact future exploration of novel electronic and optoelectronic devices from these materials.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0008055

OSTI ID:: 1270965

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 7; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Substrate effects on photoluminescence and low temperature phase transition of methylammonium lead iodide hybrid perovskite thin films Shojaee, S. A.; Harriman, T. A.; Han, G. S. Applied Physics Letters, Vol. 111, Issue 2 https://doi.org/10.1063/1.4993761	journal	July 2017
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Computational screening of methylammonium based halide perovskites with bandgaps suitable for perovskite-perovskite tandem solar cells Kar, M.; Körzdörfer, T. The Journal of Chemical Physics, Vol. 149, Issue 21 https://doi.org/10.1063/1.5037535	journal	December 2018
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Phase-transition–induced p-n junction in single halide perovskite nanowire Kong, Qiao; Lee, Woochul; Lai, Minliang Proceedings of the National Academy of Sciences, Vol. 115, Issue 36 https://doi.org/10.1073/pnas.1806515115	journal	August 2018
Fabrication of single phase 2D homologous perovskite microplates by mechanical exfoliation Li, Junze; Wang, Jun; Zhang, Yingjun 2D Materials, Vol. 5, Issue 2 https://doi.org/10.1088/2053-1583/aaa5d4	journal	January 2018
Cation effect on excitons in perovskite nanocrystals from single-dot photoluminescence of C H 3 N H 3 Pb I 3 Liu, Lige; Pevere, Federico; Zhang, Feng Physical Review B, Vol. 100, Issue 19 https://doi.org/10.1103/physrevb.100.195430	journal	November 2019
Nontrivial strength of van der Waals epitaxial interaction in soft perovskites Wang, Yiping; Gao, Lei; Yang, Yunbo Physical Review Materials, Vol. 2, Issue 7 https://doi.org/10.1103/physrevmaterials.2.076002	journal	July 2018
Understanding charge transport in lead iodide perovskite thin-film field-effect transistors Senanayak, Satyaprasad P.; Yang, Bingyan; Thomas, Tudor H. Science Advances, Vol. 3, Issue 1 https://doi.org/10.1126/sciadv.1601935	journal	January 2017
Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites Wu, Xiaoxi; Tan, Liang Z.; Shen, Xiaozhe Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1602388	journal	July 2017
A general printing approach for scalable growth of perovskite single-crystal films Gu, Zhenkun; Huang, Zhandong; Li, Chang Science Advances, Vol. 4, Issue 6 https://doi.org/10.1126/sciadv.aat2390	journal	June 2018
Understanding charge transport in lead iodide perovskite thin-film field-effect transistors Senanayak, Satyaprasad; Yang, B.; Thomas, Tudor Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.7594	text	January 2017
Emerging Characterizing Techniques in the Fine Structure Observation of Metal Halide Perovskite Crystal Shen, Kongchao; Hu, Jinping; Liang, Zhaofeng Crystals, Vol. 8, Issue 6 https://doi.org/10.3390/cryst8060232	journal	May 2018

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Size-dependent phase transition in methylammonium lead iodide perovskite microplate crystals

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