Materials Data on LiC2S2N(O2F3)2 by Materials Project
LiN(CF3SO2)2 crystallizes in the orthorhombic Pccn space group. The structure is one-dimensional and consists of four ammonia molecules; eight fluoroform molecules; and two Li(SO2)2 ribbons oriented in the (0, 1, 0) direction. In each Li(SO2)2 ribbon, Li1+ is bonded in a tetrahedral geometry to four O2- atoms. There are two shorter (1.98 Å) and two longer (2.03 Å) Li–O bond lengths. S2+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both S–O bond lengths are 1.45 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one Li1+ and one S2+ atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one Li1+ and one S2+ atom.
- Research Organization:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Contributing Organization:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1269820
- Report Number(s):
- mp-557395
- Country of Publication:
- United States
- Language:
- English
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