In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor

Palm, Brett B.; Campuzano-Jost, Pedro; Ortega, Amber M.; Day, Douglas A.; Kaser, Lisa; Jud, Werner; Karl, Thomas; Hansel, Armin; Hunter, James F.; Cross, Eben S.; Kroll, Jesse H.; Peng, Zhe; Brune, William H.; Jimenez, Jose L.

doi:10.5194/acp-16-2943-2016

Title: In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor

Journal Article · Tue Mar 08 00:00:00 EST 2016 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-16-2943-2016· OSTI ID:1240759

;

; Ortega, Amber M.;

; Kaser, Lisa;

;

; Hunter, James F.; Cross, Eben S.;

;

An oxidation flow reactor (OFR) is a vessel inside which the concentration of a chosen oxidant can be increased for the purpose of studying SOA formation and aging by that oxidant. During the BEACHON-RoMBAS (Bio-hydro-atmosphere interactions of Energy, Aerosols, Carbon, H₂O, Organics & Nitrogen–Rocky Mountain Biogenic Aerosol Study) field campaign, ambient pine forest air was oxidized by OH radicals in an OFR to measure the amount of SOA that could be formed from the real mix of ambient SOA precursor gases, and how that amount changed with time as precursors changed. High OH concentrations and short residence times allowed for semicontinuous cycling through a large range of OH exposures ranging from hours to weeks of equivalent (eq.) atmospheric aging. A simple model is derived and used to account for the relative timescales of condensation of low-volatility organic compounds (LVOCs) onto particles; condensational loss to the walls; and further reaction to produce volatile, non-condensing fragmentation products. More SOA production was observed in the OFR at nighttime (average 3 µg m^–3 when LVOC fate corrected) compared to daytime (average 0.9 µg m^–3 when LVOC fate corrected), with maximum formation observed at 0.4–1.5 eq. days of photochemical aging. SOA formation followed a similar diurnal pattern to monoterpenes, sesquiterpenes, and toluene+p-cymene concentrations, including a substantial increase just after sunrise at 07:00 local time. Higher photochemical aging (>10 eq. days) led to a decrease in new SOA formation and a loss of preexisting OA due to heterogeneous oxidation followed by fragmentation and volatilization. When comparing two different commonly used methods of OH production in OFRs (OFR185 and OFR254-70), similar amounts of SOA formation were observed. We recommend the OFR185 mode for future forest studies. Concurrent gas-phase measurements of air after OH oxidation illustrate the decay of primary VOCs, production of small oxidized organic compounds, and net production at lower ages followed by net consumption of terpenoid oxidation products as photochemical age increased. New particle formation was observed in the reactor after oxidation, especially during times when precursor gas concentrations and SOA formation were largest. Approximately 4.4 times more SOA was formed in the reactor from OH oxidation than could be explained by the VOCs measured in ambient air. To our knowledge this is the first time that this has been shown when comparing VOC concentrations with SOA formation measured at the same time, rather than comparing measurements made at different times. Several recently developed instruments have quantified ambient semivolatile and intermediate-volatility organic compounds (S/IVOCs) that were not detected by a proton transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS). An SOA yield of 18–58 % from those compounds can explain the observed SOA formation. S/IVOCs were the only pool of gas-phase carbon that was large enough to explain the observed SOA formation. This work suggests that these typically unmeasured gases play a substantial role in ambient SOA formation. Our results allow ruling out condensation sticking coefficients much lower than 1. Lastly, these measurements help clarify the magnitude of potential SOA formation from OH oxidation in forested environments and demonstrate methods for interpretation of ambient OFR measurements.

View Journal Article

Cite

Export

Save

Research Organization:: Univ. of Colorado, Boulder, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: SC0011105

OSTI ID:: 1240759

Alternate ID(s):: OSTI ID: 1268269

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Vol. 16 Journal Issue: 5; ISSN 1680-7324

Publisher:: Copernicus Publications, EGUCopyright Statement

Country of Publication:: Germany

Language:: English

Citation Metrics:

Cited by: 98 works

Citation information provided by
Web of Science

References (99)

Kinetics, products, and mechanisms of secondary organic aerosol formation Ziemann, Paul J.; Atkinson, Roger Chemical Society Reviews, Vol. 41, Issue 19 https://doi.org/10.1039/c2cs35122f	journal	January 2012
Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation Krechmer, Jordan E.; Coggon, Matthew M.; Massoli, Paola Environmental Science & Technology, Vol. 49, Issue 17 https://doi.org/10.1021/acs.est.5b02031	journal	July 2015
Total OH reactivity measurements in ambient air in a southern Rocky mountain ponderosa pine forest during BEACHON-SRM08 summer campaign Nakashima, Yoshihiro; Kato, Shungo; Greenberg, Jim Atmospheric Environment, Vol. 85 https://doi.org/10.1016/j.atmosenv.2013.11.042	journal	March 2014
Characterization of ambient aerosols in Mexico City during the MCMA-2003 campaign with Aerosol Mass Spectrometry: results from the CENICA Supersite Salcedo, D.; Onasch, T. B.; Dzepina, K. Atmospheric Chemistry and Physics, Vol. 6, Issue 4 https://doi.org/10.5194/acp-6-925-2006	journal	January 2006
Reversible addition of the OH radical to p -cymene in the gas phase: multiple adduct formation. Part 2 Alarcón, Paulo; Bohn, Birger; Zetzsch, Cornelius Phys. Chem. Chem. Phys., Vol. 16, Issue 32 https://doi.org/10.1039/C4CP02073A	journal	January 2014
Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010 Hayes, P. L.; Carlton, A. G.; Baker, K. R. Atmospheric Chemistry and Physics, Vol. 15, Issue 10 https://doi.org/10.5194/acp-15-5773-2015	journal	January 2015
Speciated measurements of semivolatile and intermediate volatility organic compounds (S/IVOCs) in a pine forest during BEACHON-RoMBAS 2011 Chan, A. W. H.; Kreisberg, N. M.; Hohaus, T. Atmospheric Chemistry and Physics, Vol. 16, Issue 2 https://doi.org/10.5194/acp-16-1187-2016	journal	January 2016
Missing peroxy radical sources within a summertime ponderosa pine forest Wolfe, G. M.; Cantrell, C.; Kim, S. Atmospheric Chemistry and Physics, Vol. 14, Issue 9 https://doi.org/10.5194/acp-14-4715-2014	journal	January 2014
Semicontinuous measurements of gas–particle partitioning of organic acids in a ponderosa pine forest using a MOVI-HRToF-CIMS Yatavelli, R. L. N.; Stark, H.; Thompson, S. L. Atmospheric Chemistry and Physics, Vol. 14, Issue 3 https://doi.org/10.5194/acp-14-1527-2014	journal	January 2014
Fast airborne aerosol size and chemistry measurements above Mexico City and Central Mexico during the MILAGRO campaign DeCarlo, P. F.; Dunlea, E. J.; Kimmel, J. R. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-4027-2008	journal	January 2008
Undisturbed and disturbed above canopy ponderosa pine emissions: PTR-TOF-MS measurements and MEGAN 2.1 model results Kaser, L.; Karl, T.; Guenther, A. Atmospheric Chemistry and Physics, Vol. 13, Issue 23 https://doi.org/10.5194/acp-13-11935-2013	journal	January 2013
Gas-Phase Tropospheric Chemistry of Volatile Organic Compounds: 1. Alkanes and Alkenes Atkinson, R. Journal of Physical and Chemical Reference Data, Vol. 26, Issue 2 https://doi.org/10.1063/1.556012	journal	March 1997
Role of sulphuric acid, ammonia and galactic cosmic rays in atmospheric aerosol nucleation Kirkby, Jasper; Curtius, Joachim; Almeida, João Nature, Vol. 476, Issue 7361 https://doi.org/10.1038/nature10343	journal	August 2011
Inter-comparison of laboratory smog chamber and flow reactor systems on organic aerosol yield and composition Bruns, E. A.; El Haddad, I.; Keller, A. Atmospheric Measurement Techniques, Vol. 8, Issue 6 https://doi.org/10.5194/amt-8-2315-2015	journal	January 2015
Evaluation of HO _x sources and cycling using measurement-constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem Kim, S.; Wolfe, G. M.; Mauldin, L. Atmospheric Chemistry and Physics, Vol. 13, Issue 4 https://doi.org/10.5194/acp-13-2031-2013	journal	January 2013
Secondary organic aerosol formation and primary organic aerosol oxidation from biomass-burning smoke in a flow reactor during FLAME-3 Ortega, A. M.; Day, D. A.; Cubison, M. J. Atmospheric Chemistry and Physics, Vol. 13, Issue 22 https://doi.org/10.5194/acp-13-11551-2013	journal	January 2013
Single-particle mass spectrometry of tropospheric aerosol particles: TROPOSPHERIC AEROSOL PARTICLES Murphy, D. M.; Cziczo, D. J.; Froyd, K. D. Journal of Geophysical Research: Atmospheres, Vol. 111, Issue D23 https://doi.org/10.1029/2006JD007340	journal	September 2006
Intermediate-Volatility Organic Compounds: A Large Source of Secondary Organic Aerosol Zhao, Yunliang; Hennigan, Christopher J.; May, Andrew A. Environmental Science & Technology, Vol. 48, Issue 23 https://doi.org/10.1021/es5035188	journal	November 2014
The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US Knote, C.; Hodzic, A.; Jimenez, J. L. Atmospheric Chemistry and Physics, Vol. 15, Issue 1 https://doi.org/10.5194/acp-15-1-2015	journal	January 2015
Formation of Sulphuric acid Aerosols and Cloud Condensation Nuclei: an Expression for Significant Nucleation and Model Comprarison Pirjola, Liisa; Kulmala, Markku; Wilck, Martin Journal of Aerosol Science, Vol. 30, Issue 8 https://doi.org/10.1016/S0021-8502(98)00776-9	journal	September 1999
Mass Accommodation Coefficient of H ₂ SO ₄ Vapor on Aqueous Sulfuric Acid Surfaces and Gaseous Diffusion Coefficient of H ₂ SO ₄ in N ₂ /H ₂ O Pöschl, Ulrich; Canagaratna, Manjula; Jayne, John T. The Journal of Physical Chemistry A, Vol. 102, Issue 49 https://doi.org/10.1021/jp982809s	journal	December 1998
High Natural Aerosol Loading over Boreal Forests Tunved, P. Science, Vol. 312, Issue 5771 https://doi.org/10.1126/science.1123052	journal	April 2006
An absorption model of gas/particle partitioning of organic compounds in the atmosphere Pankow, James F. Atmospheric Environment, Vol. 28, Issue 2 https://doi.org/10.1016/1352-2310(94)90093-0	journal	January 1994
Introducing the concept of Potential Aerosol Mass (PAM) Kang, E.; Root, M. J.; Toohey, D. W. Atmospheric Chemistry and Physics, Vol. 7, Issue 22 https://doi.org/10.5194/acp-7-5727-2007	journal	January 2007
Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes: UBIQUITY AND DOMINANCE OF OXYGENATED OA Zhang, Q.; Jimenez, J. L.; Canagaratna, M. R. Geophysical Research Letters, Vol. 34, Issue 13 https://doi.org/10.1029/2007GL029979	journal	July 2007
An environmental chamber investigation of chlorine-enhanced ozone formation in Houston, Texas Tanaka, Paul L. Journal of Geophysical Research, Vol. 108, Issue D18 https://doi.org/10.1029/2002JD003314	journal	January 2003
Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer DeCarlo, Peter F.; Kimmel, Joel R.; Trimborn, Achim Analytical Chemistry, Vol. 78, Issue 24 https://doi.org/10.1021/ac061249n	journal	December 2006
Selective measurements of isoprene and 2-methyl-3-buten-2-ol based on NO ⁺ ionization mass spectrometry Karl, T.; Hansel, A.; Cappellin, L. Atmospheric Chemistry and Physics, Vol. 12, Issue 24 https://doi.org/10.5194/acp-12-11877-2012	journal	January 2012
A large source of low-volatility secondary organic aerosol Ehn, Mikael; Thornton, Joel A.; Kleist, Einhard Nature, Vol. 506, Issue 7489 https://doi.org/10.1038/nature13032	journal	February 2014
Characterization of aerosol photooxidation flow reactors: heterogeneous oxidation, secondary organic aerosol formation and cloud condensation nuclei activity measurements Lambe, A. T.; Ahern, A. T.; Williams, L. R. Atmospheric Measurement Techniques, Vol. 4, Issue 3 https://doi.org/10.5194/amt-4-445-2011	journal	January 2011
Effect of NO<sub>x</sub> level on secondary organic aerosol (SOA) formation from the photooxidation of terpenes Ng, N. L.; Chhabra, P. S.; Chan, A. W. H. Atmospheric Chemistry and Physics, Vol. 7, Issue 19 https://doi.org/10.5194/acp-7-5159-2007	journal	January 2007
Secondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than expected Volkamer, Rainer; Jimenez, Jose L.; San Martini, Federico Geophysical Research Letters, Vol. 33, Issue 17 https://doi.org/10.1029/2006GL026899	journal	January 2006
Compilation and evaluation of gas phase diffusion coefficients of reactive trace gases in the atmosphere: Volume 2. Diffusivities of organic compounds, pressure-normalised mean free paths, and average Knudsen numbers for gas uptake calculations Tang, M. J.; Shiraiwa, M.; Pöschl, U. Atmospheric Chemistry and Physics, Vol. 15, Issue 10 https://doi.org/10.5194/acp-15-5585-2015	journal	January 2015
Comprehensive characterization of atmospheric organic carbon at a forested site Hunter, James F.; Day, Douglas A.; Palm, Brett B. Nature Geoscience, Vol. 10, Issue 10 https://doi.org/10.1038/ngeo3018	journal	September 2017
Effect of oxidant concentration, exposure time, and seed particles on secondary organic aerosol chemical composition and yield Lambe, A. T.; Chhabra, P. S.; Onasch, T. B. Atmospheric Chemistry and Physics, Vol. 15, Issue 6 https://doi.org/10.5194/acp-15-3063-2015	journal	January 2015
Effects of Molecular Structure on Aerosol Yields from OH Radical-Initiated Reactions of Linear, Branched, and Cyclic Alkanes in the Presence of NO _x Lim, Yong B.; Ziemann, Paul J. Environmental Science & Technology, Vol. 43, Issue 7 https://doi.org/10.1021/es803389s	journal	April 2009
Gas and aerosol wall losses in Teflon film smog chambers McMurry, Peter H.; Grosjean, Daniel. Environmental Science & Technology, Vol. 19, Issue 12 https://doi.org/10.1021/es00142a006	journal	December 1985
Anthropogenic and Natural Radiative Forcing Climate Change 2013 – The Physical Science Basis https://doi.org/10.1017/CBO9781107415324.018	book	June 2014
Online measurements of the emissions of intermediate-volatility and semi-volatile organic compounds from aircraft Cross, E. S.; Hunter, J. F.; Carrasquillo, A. J. Atmospheric Chemistry and Physics, Vol. 13, Issue 15 https://doi.org/10.5194/acp-13-7845-2013	journal	January 2013
Development and Characterization of a Fast-Stepping/Scanning Thermodenuder for Chemically-Resolved Aerosol Volatility Measurements Huffman, J. Alex; Ziemann, Paul J.; Jayne, John T. Aerosol Science and Technology, Vol. 42, Issue 5 https://doi.org/10.1080/02786820802104981	journal	March 2008
Modeling the Processing of Aerosol and Trace Gases in Clouds and Fogs Ervens, Barbara Chemical Reviews, Vol. 115, Issue 10 https://doi.org/10.1021/cr5005887	journal	February 2015
Health Effects of Fine Particulate Air Pollution: Lines that Connect Pope, C. Arden; Dockery, Douglas W. Journal of the Air & Waste Management Association, Vol. 56, Issue 6 https://doi.org/10.1080/10473289.2006.10464485	journal	June 2006
Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 1: measurement and simulation of organic aerosol evolution Grieshop, A. P.; Logue, J. M.; Donahue, N. M. Atmospheric Chemistry and Physics, Vol. 9, Issue 4 https://doi.org/10.5194/acp-9-1263-2009	journal	January 2009
Modeling organic aerosols in a megacity: potential contribution of semi-volatile and intermediate volatility primary organic compounds to secondary organic aerosol formation Hodzic, A.; Jimenez, J. L.; Madronich, S. Atmospheric Chemistry and Physics, Vol. 10, Issue 12 https://doi.org/10.5194/acp-10-5491-2010	journal	January 2010
Airborne measurement of OH reactivity during INTEX-B Mao, J.; Ren, X.; Brune, W. H. Atmospheric Chemistry and Physics, Vol. 9, Issue 1 https://doi.org/10.5194/acp-9-163-2009	journal	January 2009
Diffusion of H ₂ SO ₄ in Humidified Nitrogen: Hydrated H ₂ SO ₄ Hanson, D. R.; Eisele, F. The Journal of Physical Chemistry A, Vol. 104, Issue 8 https://doi.org/10.1021/jp993622j	journal	March 2000
Global secondary organic aerosol from isoprene oxidation Henze, Daven K.; Seinfeld, John H. Geophysical Research Letters, Vol. 33, Issue 9 https://doi.org/10.1029/2006GL025976	journal	January 2006
Evaporation kinetics and phase of laboratory and ambient secondary organic aerosol Vaden, T. D.; Imre, D.; Beranek, J. Proceedings of the National Academy of Sciences, Vol. 108, Issue 6 https://doi.org/10.1073/pnas.1013391108	journal	January 2011
Coupled Partitioning, Dilution, and Chemical Aging of Semivolatile Organics Donahue, N. M.; Robinson, A. L.; Stanier, C. O. Environmental Science & Technology, Vol. 40, Issue 8 https://doi.org/10.1021/es052297c	journal	April 2006
Emissions of biogenic volatile organic compounds and subsequent photochemical production of secondary organic aerosol in mesocosm studies of temperate and tropical plant species Wyche, K. P.; Ryan, A. C.; Hewitt, C. N. Atmospheric Chemistry and Physics, Vol. 14, Issue 23 https://doi.org/10.5194/acp-14-12781-2014	journal	January 2014
Rethinking Organic Aerosols: Semivolatile Emissions and Photochemical Aging Robinson, A. L.; Donahue, N. M.; Shrivastava, M. K. Science, Vol. 315, Issue 5816 https://doi.org/10.1126/science.1133061	journal	March 2007
Evaluation of the volatility basis-set approach for the simulation of organic aerosol formation in the Mexico City metropolitan area Tsimpidi, A. P.; Karydis, V. A.; Zavala, M. Atmospheric Chemistry and Physics, Vol. 10, Issue 2 https://doi.org/10.5194/acp-10-525-2010	journal	January 2010
Chemical aging of ambient organic aerosol from heterogeneous reaction with hydroxyl radicals George, I. J.; Slowik, J.; Abbatt, J. P. D. Geophysical Research Letters, Vol. 35, Issue 13 https://doi.org/10.1029/2008GL033884	journal	January 2008
Secondary Organic Aerosol Formation from in-Use Motor Vehicle Emissions Using a Potential Aerosol Mass Reactor Tkacik, Daniel S.; Lambe, Andrew T.; Jathar, Shantanu Environmental Science & Technology, Vol. 48, Issue 19 https://doi.org/10.1021/es502239v	journal	September 2014
Observations of HNO ₃ , ΣAN, ΣPN and NO ₂ fluxes: evidence for rapid HO _x chemistry within a pine forest canopy Farmer, D. K.; Cohen, R. C. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-3899-2008	journal	January 2008
Known and Unexplored Organic Constituents in the Earth's Atmosphere Goldstein, Allen H.; Galbally, Ian E. Environmental Science & Technology, Vol. 41, Issue 5 https://doi.org/10.1021/es072476p	journal	March 2007
Organosulfates as Tracers for Secondary Organic Aerosol (SOA) Formation from 2-Methyl-3-Buten-2-ol (MBO) in the Atmosphere Zhang, Haofei; Worton, David R.; Lewandowski, Michael Environmental Science & Technology, Vol. 46, Issue 17 https://doi.org/10.1021/es301648z	journal	August 2012
Mass spectral characterization of submicron biogenic organic particles in the Amazon Basin Chen, Q.; Farmer, D. K.; Schneider, J. Geophysical Research Letters, Vol. 36, Issue 20 https://doi.org/10.1029/2009GL039880	journal	January 2009
Aerosol fast flow reactor for laboratory studies of new particle formation Ezell, Michael J.; Chen, Haihan; Arquero, Kristine D. Journal of Aerosol Science, Vol. 78 https://doi.org/10.1016/j.jaerosci.2014.08.009	journal	December 2014
Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies Ervens, B.; Turpin, B. J.; Weber, R. J. Atmospheric Chemistry and Physics, Vol. 11, Issue 21 https://doi.org/10.5194/acp-11-11069-2011	journal	January 2011
Emissions and ambient distributions of Biogenic Volatile Organic Compounds (BVOC) in a ponderosa pine ecosystem: interpretation of PTR-MS mass spectra Kim, S.; Karl, T.; Guenther, A. Atmospheric Chemistry and Physics, Vol. 10, Issue 4 https://doi.org/10.5194/acp-10-1759-2010	journal	January 2010
Characterization of a large biogenic secondary organic aerosol event from eastern Canadian forests Slowik, J. G.; Stroud, C.; Bottenheim, J. W. Atmospheric Chemistry and Physics, Vol. 10, Issue 6 https://doi.org/10.5194/acp-10-2825-2010	journal	January 2010
The AeroCom evaluation and intercomparison of organic aerosol in global models Tsigaridis, K.; Daskalakis, N.; Kanakidou, M. Atmospheric Chemistry and Physics, Vol. 14, Issue 19 https://doi.org/10.5194/acp-14-10845-2014	journal	January 2014
Gas-Wall Partitioning of Organic Compounds in a Teflon Film Chamber and Potential Effects on Reaction Product and Aerosol Yield Measurements Matsunaga, Aiko; Ziemann ‡, Paul J. Aerosol Science and Technology, Vol. 44, Issue 10 https://doi.org/10.1080/02786826.2010.501044	journal	August 2010
Laboratory studies of the chemical composition and cloud condensation nuclei (CCN) activity of secondary organic aerosol (SOA) and oxidized primary organic aerosol (OPOA) Lambe, A. T.; Onasch, T. B.; Massoli, P. Atmospheric Chemistry and Physics, Vol. 11, Issue 17 https://doi.org/10.5194/acp-11-8913-2011	journal	January 2011
Observations of gas- and aerosol-phase organic nitrates at BEACHON-RoMBAS 2011 Fry, J. L.; Draper, D. C.; Zarzana, K. J. Atmospheric Chemistry and Physics, Vol. 13, Issue 17 https://doi.org/10.5194/acp-13-8585-2013	journal	January 2013
Mass accommodation and uptake coefficients — a quantitative comparison Kulmala, Markku; Wagner, Paul E. Journal of Aerosol Science, Vol. 32, Issue 7 https://doi.org/10.1016/S0021-8502(00)00116-6	journal	July 2001
Secondary organic aerosol formation from photooxidation of naphthalene and alkylnaphthalenes: implications for oxidation of intermediate volatility organic compounds (IVOCs) Chan, A. W. H.; Kautzman, K. E.; Chhabra, P. S. Atmospheric Chemistry and Physics, Vol. 9, Issue 9 https://doi.org/10.5194/acp-9-3049-2009	journal	January 2009
Overview of the Manitou Experimental Forest Observatory: site description and selected science results from 2008 to 2013 Ortega, J.; Turnipseed, A.; Guenther, A. B. Atmospheric Chemistry and Physics, Vol. 14, Issue 12 https://doi.org/10.5194/acp-14-6345-2014	journal	January 2014
Influence of vapor wall loss in laboratory chambers on yields of secondary organic aerosol Zhang, X.; Cappa, C. D.; Jathar, S. H. Proceedings of the National Academy of Sciences, Vol. 111, Issue 16 https://doi.org/10.1073/pnas.1404727111	journal	April 2014
Near-Unity Mass Accommodation Coefficient of Organic Molecules of Varying Structure Julin, Jan; Winkler, Paul M.; Donahue, Neil M. Environmental Science & Technology, Vol. 48, Issue 20 https://doi.org/10.1021/es501816h	journal	October 2014
Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review Atkinson, Roger; Arey, Janet Atmospheric Environment, Vol. 37 https://doi.org/10.1016/S1352-2310(03)00391-1	journal	January 2003
Quantitative estimates of the volatility of ambient organic aerosol Cappa, C. D.; Jimenez, J. L. Atmospheric Chemistry and Physics, Vol. 10, Issue 12 https://doi.org/10.5194/acp-10-5409-2010	journal	January 2010
New particle formation and growth from methanesulfonic acid, trimethylamine and water Chen, Haihan; Ezell, Michael J.; Arquero, Kristine D. Physical Chemistry Chemical Physics, Vol. 17, Issue 20 https://doi.org/10.1039/C5CP00838G	journal	January 2015
Comparison of different real time VOC measurement techniques in a ponderosa pine forest Kaser, L.; Karl, T.; Schnitzhofer, R. Atmospheric Chemistry and Physics, Vol. 13, Issue 5 https://doi.org/10.5194/acp-13-2893-2013	journal	January 2013
Molecular Composition and Volatility of Organic Aerosol in the Southeastern U.S.: Implications for IEPOX Derived SOA Lopez-Hilfiker, F. D.; Mohr, C.; D’Ambro, E. L. Environmental Science & Technology, Vol. 50, Issue 5 https://doi.org/10.1021/acs.est.5b04769	journal	February 2016
Aqueous chemistry and its role in secondary organic aerosol (SOA) formation Lim, Y. B.; Tan, Y.; Perri, M. J. Atmospheric Chemistry and Physics, Vol. 10, Issue 21 https://doi.org/10.5194/acp-10-10521-2010	journal	January 2010
Secondary Organic Aerosol Formation from Intermediate-Volatility Organic Compounds: Cyclic, Linear, and Branched Alkanes Tkacik, Daniel S.; Presto, Albert A.; Donahue, Neil M. Environmental Science & Technology, Vol. 46, Issue 16 https://doi.org/10.1021/es301112c	journal	August 2012
Modeling organic aerosols during MILAGRO: importance of biogenic secondary organic aerosols Hodzic, A.; Jimenez, J. L.; Madronich, S. Atmospheric Chemistry and Physics, Vol. 9, Issue 18 https://doi.org/10.5194/acp-9-6949-2009	journal	January 2009
Reactive intermediates revealed in secondary organic aerosol formation from isoprene Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C. Proceedings of the National Academy of Sciences, Vol. 107, Issue 15 https://doi.org/10.1073/pnas.0911114107	journal	December 2009
Evolution of Organic Aerosols in the Atmosphere Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M. Science, Vol. 326, Issue 5959 https://doi.org/10.1126/science.1180353	journal	December 2009
HO _x radical chemistry in oxidation flow reactors with low-pressure mercury lamps systematically examined by modeling Peng, Z.; Day, D. A.; Stark, H. Atmospheric Measurement Techniques, Vol. 8, Issue 11 https://doi.org/10.5194/amt-8-4863-2015	journal	January 2015
Dependence of SOA oxidation on organic aerosol mass concentration and OH exposure: experimental PAM chamber studies Kang, E.; Toohey, D. W.; Brune, W. H. Atmospheric Chemistry and Physics, Vol. 11, Issue 4 https://doi.org/10.5194/acp-11-1837-2011	journal	January 2011
Rapid deposition of oxidized biogenic compounds to a temperate forest Nguyen, Tran B.; Crounse, John D.; Teng, Alex P. Proceedings of the National Academy of Sciences, Vol. 112, Issue 5 https://doi.org/10.1073/pnas.1418702112	journal	January 2015
A continuous photo-oxidation flow reactor for a defined measurement of the SOA formation potential of wood burning emissions Keller, Alejandro; Burtscher, Heinz Journal of Aerosol Science, Vol. 49 https://doi.org/10.1016/j.jaerosci.2012.02.007	journal	July 2012
A single parameter representation of hygroscopic growth and cloud condensation nucleus activity Petters, M. D.; Kreidenweis, S. M. Atmospheric Chemistry and Physics, Vol. 7, Issue 8 https://doi.org/10.5194/acp-7-1961-2007	journal	January 2007
Atmospheric benzenoid emissions from plants rival those from fossil fuels Misztal, P. K.; Hewitt, C. N.; Wildt, J. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep12064	journal	July 2015
Using Elemental Ratios to Predict the Density of Organic Material Composed of Carbon, Hydrogen, and Oxygen Kuwata, Mikinori; Zorn, Soeren R.; Martin, Scot T. Environmental Science & Technology, Vol. 46, Issue 2 https://doi.org/10.1021/es202525q	journal	December 2011
Non-OH chemistry in oxidation flow reactors for the study of atmospheric chemistry systematically examined by modeling Peng, Z.; Day, D. A.; Ortega, A. M. Atmospheric Chemistry and Physics Discussions, Vol. 15, Issue 17 https://doi.org/10.5194/acpd-15-23543-2015	journal	January 2015
The heterogeneous reaction of hydroxyl radicals with sub-micron squalane particles: a model system for understanding the oxidative aging of ambient aerosols Smith, J. D.; Kroll, J. H.; Cappa, C. D. Atmospheric Chemistry and Physics, Vol. 9, Issue 9 https://doi.org/10.5194/acp-9-3209-2009	journal	January 2009
Modeling the Radical Chemistry in an Oxidation Flow Reactor: Radical Formation and Recycling, Sensitivities, and the OH Exposure Estimation Equation Li, Rui; Palm, Brett B.; Ortega, Amber M. The Journal of Physical Chemistry A, Vol. 119, Issue 19 https://doi.org/10.1021/jp509534k	journal	November 2014
Size-resolved aerosol composition and its link to hygroscopicity at a forested site in Colorado Levin, E. J. T.; Prenni, A. J.; Palm, B. B. Atmospheric Chemistry and Physics, Vol. 14, Issue 5 https://doi.org/10.5194/acp-14-2657-2014	journal	January 2014
Constraining Particle Evolution from Wall Losses, Coagulation, and Condensation-Evaporation in Smog-Chamber Experiments: Optimal Estimation Based on Size Distribution Measurements Pierce, J. R.; Engelhart, G. J.; Hildebrandt, L. Aerosol Science and Technology, Vol. 42, Issue 12 https://doi.org/10.1080/02786820802389251	journal	October 2008
Effect of NO _x on Secondary Organic Aerosol Concentrations Lane, Timothy E.; Donahue, Neil M.; Pandis, Spyros N. Environmental Science & Technology, Vol. 42, Issue 16 https://doi.org/10.1021/es703225a	journal	August 2008
Photo-Oxidation of Low-Volatility Organics Found in Motor Vehicle Emissions: Production and Chemical Evolution of Organic Aerosol Mass Miracolo, Marissa A.; Presto, Albert A.; Lambe, Andrew T. Environmental Science & Technology, Vol. 44, Issue 5 https://doi.org/10.1021/es902635c	journal	March 2010
Secondary Organic Aerosol Formation from High-NO _x Photo-Oxidation of Low Volatility Precursors: n -Alkanes Presto, Albert A.; Miracolo, Marissa A.; Donahue, Neil M. Environmental Science & Technology, Vol. 44, Issue 6 https://doi.org/10.1021/es903712r	journal	March 2010
Gas-phase products and secondary aerosol yields from the photooxidation of 16 different terpenes Lee, Anita; Goldstein, Allen H.; Kroll, Jesse H. Journal of Geophysical Research, Vol. 111, Issue D17 https://doi.org/10.1029/2006JD007050	journal	January 2006
Real-time measurements of secondary organic aerosol formation and aging from ambient air in an oxidation flow reactor in the Los Angeles area Ortega, A. M.; Hayes, P. L.; Peng, Z. Atmospheric Chemistry and Physics Discussions, Vol. 15, Issue 15 https://doi.org/10.5194/acpd-15-21907-2015	journal	January 2015
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene Paulot, F.; Crounse, J. D.; Kjaergaard, H. G. Science, Vol. 325, Issue 5941 https://doi.org/10.1126/science.1172910	journal	August 2009

Similar Records

Secondary organic aerosol formation from in situ OH, O₃, and NO₃ oxidation of ambient forest air in an oxidation flow reactor

Journal Article · Tue Apr 25 00:00:00 EDT 2017 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1240759

Palm, Brett B.; Campuzano-Jost, Pedro; Day, Douglas A.; +13 more

Real-time measurements of secondary organic aerosol formation and aging from ambient air in an oxidation flow reactor in the Los Angeles area

Journal Article · Wed Jun 15 00:00:00 EDT 2016 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1240759

Ortega, Amber M.; Hayes, Patrick L.; Peng, Zhe; +13 more

Organic peroxy radical chemistry in oxidation flow reactors and environmental chambers and their atmospheric relevance

Journal Article · Tue Jan 22 00:00:00 EST 2019 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1240759

Peng, Zhe; Lee-Taylor, Julia; Orlando, John J.; +2 more

Related Subjects

54 ENVIRONMENTAL SCIENCES
cloud condensation nuclei
mass accommodation coefficient
beachon-rombas 2011
intermediate-volatility
soa formation
sulfuric-acid
mexico-city
chemical-composition
particle formation
radical chemistry

Title: In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor

Citation Formats

References (99)

Similar Records

Related Subjects