New mechanistic insight into the oxygen reduction reaction on Ruddlesden–Popper cathodes for intermediate-temperature solid oxide fuel cells

Li, Wenyuan; Guan, Bo; Zhang, Xinxin; Yan, Jianhua; Zhou, Yue; Liu, Xingbo

doi:10.1039/C6CP00056H

New mechanistic insight into the oxygen reduction reaction on Ruddlesden–Popper cathodes for intermediate-temperature solid oxide fuel cells

Journal Article · Thu Feb 25 00:00:00 EST 2016 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/C6CP00056H· OSTI ID:1267277

Li, Wenyuan ^[1]; Guan, Bo ^[2]; Zhang, Xinxin ^[2]; Yan, Jianhua ^[2]; Zhou, Yue ^[2]; Liu, Xingbo ^[2]

West Virginia Univ., Morgantown, WV (United States); West Virginia University
West Virginia Univ., Morgantown, WV (United States)

Ruddlesden–Popper (R–P) phase materials have been investigated widely as cathode candidates for IT-SOFCs. However, widespread application of R–P phase cathodes demands further improvement in electrode activity whose progress is hindered by the limited information in the oxygen reduction reaction (ORR). The ORR mechanism for the R–P phase is therefore investigated in this paper using (LaSr)₂NiO_4±δ as an example. Accurate characterization of the surface oxygen exchange process is realized by developing thin and dense polycrystalline LSNO layers via a versatile spray-modified pressing method we invented before to avoid perceptible bulk diffusion contribution, surface enrichment and geometry complication. Hence, the governing factors of the ORR are identified as oxygen adsorption and incorporation based on the findings in reaction orders from electrochemical impedance spectroscopy (EIS), stoichiometry-related chemical capacitance and intrinsic anisotropic properties.

View Accepted Manuscript (DOE)

Research Organization:: West Virginia Univ., Morgantown, WV (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0009675

OSTI ID:: 1267277

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 12 Vol. 18; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (67)

A Novel Electrode Material for Symmetrical SOFCs Liu, Qiang; Dong, Xihui; Xiao, Guoliang Advanced Materials, Vol. 22, Issue 48, p. 5478-5482 https://doi.org/10.1002/adma.201001044	journal	October 2010
Towards the Next Generation of Solid Oxide Fuel Cells Operating Below 600 °C with Chemically Stable Proton-Conducting Electrolytes Fabbri, Emiliana; Bi, Lei; Pergolesi, Daniele Advanced Materials, Vol. 24, Issue 2 https://doi.org/10.1002/adma.201103102	journal	September 2011
A New Model Describing Solid Oxide Fuel Cell Cathode Kinetics: Model Thin Film SrTi1-xFexO3-δ Mixed Conducting Oxides-a Case Study Jung, WooChul; Tuller, Harry L. Advanced Energy Materials, Vol. 1, Issue 6 https://doi.org/10.1002/aenm.201100164	journal	September 2011
A Performance Study of Solid Oxide Fuel Cells With BaZr0.1Ce0.7Y0.2O3-δ Electrolyte Developed by Spray-Modified Pressing Method Guan, B.; Lü, Z.; Wang, G. Fuel Cells, Vol. 12, Issue 1 https://doi.org/10.1002/fuce.201100109	journal	February 2012
A comparison of the transport properties of La2−xSrxNi1−yFeyO4+δ where 0 Skinner, S. J.; Kilner, J. A. Ionics, Vol. 5, Issue 3-4 https://doi.org/10.1007/BF02375836	journal	May 1999
Recent developments in Ruddlesden–Popper nickelate systems for solid oxide fuel cell cathodes Amow, G.; Skinner, S. J. Journal of Solid State Electrochemistry, Vol. 10, Issue 8 https://doi.org/10.1007/s10008-006-0127-x	journal	April 2006
Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review: II. Electrochemical behavior vs. materials science aspects Tsipis, Ekaterina V.; Kharton, Vladislav V. Journal of Solid State Electrochemistry, Vol. 12, Issue 11 https://doi.org/10.1007/s10008-008-0611-6	journal	July 2008
Oxygen transport in La2-x Sr x NiO4+δ: membrane permeation and defect chemical modelling Schroeder, M.; Dragan, M. -A. Journal of Materials Science, Vol. 42, Issue 6 https://doi.org/10.1007/s10853-006-0739-7	journal	February 2007
Non-stoichiometry, Fermi energy and work function of (La,Sr)MnO3. I. Theoretical model Bak, T.; Nowotny, J.; Rekas, M. Journal of Physics and Chemistry of Solids, Vol. 62, Issue 4 https://doi.org/10.1016/S0022-3697(00)00230-4	journal	April 2001
Oxygen diffusion and surface exchange in La2−xSrxNiO4+δ Skinner, S. Solid State Ionics, Vol. 135, Issue 1-4 https://doi.org/10.1016/S0167-2738(00)00388-X	journal	November 2000
Characterization of LSMâ€“YSZ composite electrode by ac impedance spectroscopy Kim, J. Solid State Ionics, Vol. 143, Issue 3-4 https://doi.org/10.1016/S0167-2738(01)00877-3	journal	July 2001
Solid oxide fuel cells for stationary, mobile, and military applications Singhal, S. Solid State Ionics, Vol. 152-153 https://doi.org/10.1016/S0167-2738(02)00349-1	journal	December 2002
Mass transport in La2Ni1−xCoxO4+δ oxides with the K2NiF4 structure Kilner, J. Solid State Ionics, Vol. 154-155 https://doi.org/10.1016/S0167-2738(02)00506-4	journal	December 2002
Oxygen electrode reaction on Nd₂NiO_4+δ cathode materials: impedance spectroscopy study Mauvy, F.; Bassat, J.-M.; Boehm, E. Solid State Ionics, Vol. 158, Issue 1-2, p. 17-28 https://doi.org/10.1016/S0167-2738(02)00689-6	journal	February 2003
Oxides of the AMO3 and A2MO4-type: structural stability, electrical conductivity and thermal expansion Al Daroukh, M. Solid State Ionics, Vol. 158, Issue 1-2 https://doi.org/10.1016/S0167-2738(02)00773-7	journal	February 2003
Oxygen nonstoichiometry and electrical conductivity of the solid solutions La2−xSrxNiOy (0≤x≤0.5) Vashook, V. V.; Tolochko, S. P.; Yushkevich, I. I. Solid State Ionics, Vol. 110, Issue 3-4 https://doi.org/10.1016/S0167-2738(98)00134-9	journal	July 1998
On the correlation of macroscopic and microscopic rate constants in solid state chemistry Maier, J. Solid State Ionics, Vol. 112, Issue 3-4 https://doi.org/10.1016/S0167-2738(98)00152-0	journal	October 1998
Fundamental issues in modeling of mixed ionic-electronic conductors (MIECs) Liu, Meilin; Winnick, Jack Solid State Ionics, Vol. 118, Issue 1-2 https://doi.org/10.1016/S0167-2738(98)00451-2	journal	March 1999
Composition and conductivity of some nickelates Vashook, V. V.; Yushkevich, I. I.; Kokhanovsky, L. V. Solid State Ionics, Vol. 119, Issue 1-4 https://doi.org/10.1016/S0167-2738(98)00478-0	journal	April 1999
The polarization of mixed conducting SOFC cathodes: Effects of surface reaction coefficient, ionic conductivity and geometry Fleig, J.; Maier, J. Journal of the European Ceramic Society, Vol. 24, Issue 6 https://doi.org/10.1016/S0955-2219(03)00561-2	journal	January 2004
Oxygen transport properties of La2Ni1−xCuxO4+δ mixed conducting oxides Boehm, E.; Bassat, J. -M.; Steil, M. C. Solid State Sciences, Vol. 5, Issue 7 https://doi.org/10.1016/S1293-2558(03)00091-8	journal	July 2003
Oxygen ionic conductivity of La2NiO4+ via interstitial oxygen defect Jeon, S. -Y.; Choi, M. -B.; Im, H. -N. Journal of Physics and Chemistry of Solids, Vol. 73, Issue 5 https://doi.org/10.1016/j.jpcs.2012.01.006	journal	May 2012
Cathode reaction models and performance analysis of Sm0.5Sr0.5CoO3−δ–BaCe0.8Sm0.2O3−δ composite cathode for solid oxide fuel cells with proton conducting electrolyte He, Fei; Wu, Tianzhi; Peng, Ranran Journal of Power Sources, Vol. 194, Issue 1 https://doi.org/10.1016/j.jpowsour.2009.04.053	journal	October 2009
H2 oxidation on doped yttrium chromites/yttrium stabilized zirconia anode of solid oxide fuel cell Li, Wenyuan; Gong, Mingyang; Liu, Xingbo Journal of Power Sources, Vol. 241 https://doi.org/10.1016/j.jpowsour.2013.04.107	journal	November 2013
Lattice structure, sintering behavior and electrochemical performance of La1.7Ca0.3Ni1−xCuxO4+δ as cathode material for intermediate-temperature solid oxide fuel cell Shen, Yongna; Zhao, Hailei; Świerczek, Konrad Journal of Power Sources, Vol. 240 https://doi.org/10.1016/j.jpowsour.2013.05.025	journal	October 2013
Oxygen nonstoichiometry in (M = Cu, Co) under oxidizing conditions Naumovich, E. N.; Patrakeev, M. V.; Kharton, V. V. Solid State Sciences, Vol. 7, Issue 11 https://doi.org/10.1016/j.solidstatesciences.2005.08.005	journal	November 2005
Oxygen diffusion and transport properties in non-stoichiometric LnNiO oxides Boehm, E.; Bassat, J.; Dordor, P. Solid State Ionics, Vol. 176, Issue 37-38 https://doi.org/10.1016/j.ssi.2005.06.033	journal	November 2005
Impedance spectroscopic study on well-defined (La,Sr)(Co,Fe)O3−δ model electrodes Baumann, F.; Fleig, J.; Habermeier, H. Solid State Ionics, Vol. 177, Issue 11-12 https://doi.org/10.1016/j.ssi.2006.02.045	journal	April 2006
Measurement of oxygen transport kinetics in epitaxial La2NiO4+δ thin films by electrical conductivity relaxation Kim, G.; Wang, S.; Jacobson, A. Solid State Ionics, Vol. 177, Issue 17-18 https://doi.org/10.1016/j.ssi.2006.07.013	journal	July 2006
The polarization resistance of mixed conducting SOFC cathodes: A comparative study using thin film model electrodes Baumann, F. S.; Maier, J.; Fleig, J. Solid State Ionics, Vol. 179, Issue 21-26 https://doi.org/10.1016/j.ssi.2008.02.059	journal	September 2008
Oxygen nonstoichiometry and defect equilibrium in La2−xSrxNiO4+δ Nakamura, Takashi; Yashiro, Keiji; Sato, Kazuhisa Solid State Ionics, Vol. 180, Issue 4-5 https://doi.org/10.1016/j.ssi.2009.01.013	journal	April 2009
Transport properties and defect analysis of La1.9Sr0.1NiO4+δ Li, Zuoan; Haugsrud, Reidar; Smith, Jens B. Solid State Ionics, Vol. 180, Issue 26-27 https://doi.org/10.1016/j.ssi.2009.08.011	journal	October 2009
Development of lanthanum nickelate as a cathode for use in intermediate temperature solid oxide fuel cells Sayers, R.; Rieu, M.; Lenormand, P. Solid State Ionics, Vol. 192, Issue 1 https://doi.org/10.1016/j.ssi.2010.02.014	journal	June 2011
Oxygen bulk diffusion and surface exchange in Sr-substituted La2NiO4+δ Li, Zuoan; Haugsrud, Reidar; Norby, Truls Solid State Ionics, Vol. 184, Issue 1 https://doi.org/10.1016/j.ssi.2010.10.009	journal	March 2011
Influence of the synthesis method on the electrochemical properties of bilayer electrodes based on La2NiO4+δ and LaNi0.6Fe0.4O3−δ Pikalova, E. Yu.; Bogdanovich, N. M.; Kolchugin, A. A. Solid State Ionics, Vol. 288 https://doi.org/10.1016/j.ssi.2016.01.014	journal	May 2016
Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes ^† Adler, Stuart B. Chemical Reviews, Vol. 104, Issue 10 https://doi.org/10.1021/cr020724o	journal	October 2004
What Are Batteries, Fuel Cells, and Supercapacitors? Winter, Martin; Brodd, Ralph J. Chemical Reviews, Vol. 104, Issue 10, p. 4245-4270 https://doi.org/10.1021/cr020730k	journal	October 2004
Direct oxidation of hydrocarbons in a solid-oxide fuel cell Park, Seungdoo; Vohs, John M.; Gorte, Raymond J. Nature, Vol. 404, Issue 6775 https://doi.org/10.1038/35005040	journal	March 2000
Anisotropic oxygen diffusion properties in epitaxial thin films of La ₂ NiO _4+δ Burriel, Monica; Garcia, Gemma; Santiso, Jose J. Mater. Chem., Vol. 18, Issue 4 https://doi.org/10.1039/B711341B	journal	January 2008
Interstitialcy diffusion of oxygen in tetragonal La ₂ CoO ₄ ₊ δ Kushima, Akihiro; Parfitt, David; Chroneos, Alexander Phys. Chem. Chem. Phys., Vol. 13, Issue 6 https://doi.org/10.1039/C0CP01603A	journal	January 2011
Isothermal Onsager matrices and acceptor size effect on mass/charge transport properties of La_1.9A_0.1NiO_3.95+δ (A = Ca, Sr) Kim, Hong-Seok; Yoo, Han-Ill Phys. Chem. Chem. Phys., Vol. 16, Issue 31 https://doi.org/10.1039/C3CP55228D	journal	January 2014
Effect of Sr substituted La_2−xSr_xNiO_4+δ (x = 0, 0.2, 0.4, 0.6, and 0.8) on oxygen stoichiometry and oxygen transport properties Inprasit, T.; Wongkasemjit, S.; Skinner, S. J. RSC Advances, Vol. 5, Issue 4 https://doi.org/10.1039/C4RA11672K	journal	January 2015
The determining factor for interstitial oxygen formation in Ruddlesden–Popper type La ₂ NiO ₄ -based oxides Nakamura, Takashi; Oike, Ryo; Ling, Yihan Physical Chemistry Chemical Physics, Vol. 18, Issue 3 https://doi.org/10.1039/C5CP05993C	journal	January 2016
Oxygen migration in La2NiO4 + δ Minervini, Licia; Grimes, Robin W.; Kilner, John A. Journal of Materials Chemistry, Vol. 10, Issue 10 https://doi.org/10.1039/b004212i	journal	January 2000
Intermediate temperature solid oxide fuel cells Brett, Daniel J. L.; Atkinson, Alan; Brandon, Nigel P. Chemical Society Reviews, Vol. 37, Issue 8 https://doi.org/10.1039/b612060c	journal	January 2008
Impedance studies of dense polycrystalline thin films of La2NiO4+? Kim, Gun Tae; Wang, Shuangyan; Jacobson, Allan J. Journal of Materials Chemistry, Vol. 17, Issue 13 https://doi.org/10.1039/b616101d	journal	January 2007
Electronic state of oxygen nonstoichiometric La2−xSrxNiO4+δ at high temperatures Nakamura, Takashi; Yashiro, Keiji; Sato, Kazuhisa Physical Chemistry Chemical Physics, Vol. 11, Issue 17 https://doi.org/10.1039/b823364k	journal	January 2009
Defect-chemical analysis of the nonstoichiometry, conductivity and thermopower of La2NiO4+δ Kim, Hong-Seok; Yoo, Han-Ill Physical Chemistry Chemical Physics, Vol. 12, Issue 18 https://doi.org/10.1039/b918329a	journal	January 2010
Advances in layered oxide cathodes for intermediate temperature solid oxide fuel cells Tarancón, Albert; Burriel, Mónica; Santiso, José Journal of Materials Chemistry, Vol. 20, Issue 19 https://doi.org/10.1039/b922430k	journal	January 2010
Molecular dynamics study of oxygen diffusion in Pr2NiO4+δ Parfitt, David; Chroneos, Alexander; Kilner, John A. Physical Chemistry Chemical Physics, Vol. 12, Issue 25 https://doi.org/10.1039/c001809k	journal	January 2010
Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations Chroneos, Alexander; Yildiz, Bilge; Tarancón, Albert Energy & Environmental Science, Vol. 4, Issue 8 https://doi.org/10.1039/c0ee00717j	journal	January 2011
Enhancing SOFC cathode performance by surface modification through infiltration Ding, Dong; Li, Xiaxi; Lai, Samson Yuxiu Energy & Environmental Science, Vol. 7, Issue 2 https://doi.org/10.1039/c3ee42926a	journal	January 2014
Oxygen in Catalysis on Transition Metal Oxides Bielański, A.; Haber, J. Catalysis Reviews, Vol. 19, Issue 1 https://doi.org/10.1080/03602457908065099	journal	January 1979
Structure of the interstitial oxygen defect in La 2 NiO 4 + δ Jorgensen, J. D.; Dabrowski, B.; Pei, Shiyou Physical Review B, Vol. 40, Issue 4 https://doi.org/10.1103/PhysRevB.40.2187	journal	August 1989
Impedance Spectroscopy as a Tool for Chemical and Electrochemical Analysis of Mixed Conductors: A Case Study of Ceria Lai, Wei; Haile, Sossina M. Journal of the American Ceramic Society, Vol. 88, Issue 11 https://doi.org/10.1111/j.1551-2916.2005.00740.x	journal	November 2005
Lowering the Temperature of Solid Oxide Fuel Cells Wachsman, E. D.; Lee, K. T. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1204090	journal	November 2011
Perovskite Oxides: Materials Science in Catalysis Voorhoeve, R. J. H.; Johnson, D. W.; Remeika, J. P. Science, Vol. 195, Issue 4281 https://doi.org/10.1126/science.195.4281.827	journal	March 1977
Electrochemistry of Mixed Oxygen Ion and Electron Conducting Electrodes in Solid Electrolyte Cells Chueh, William C.; Haile, Sossina M. Annual Review of Chemical and Biomolecular Engineering, Vol. 3, Issue 1 https://doi.org/10.1146/annurev-chembioeng-073009-101000	journal	July 2012
Impedance of Solid Oxide Fuel Cell LSM/YSZ Composite Cathodes Jørgensen, M. J.; Mogensen, M. Journal of The Electrochemical Society, Vol. 148, Issue 5 https://doi.org/10.1149/1.1360203	journal	January 2001
Treatment of the Impedance of Mixed Conductors Equivalent Circuit Model and Explicit Approximate Solutions Jamnik, J. Journal of The Electrochemical Society, Vol. 146, Issue 11 https://doi.org/10.1149/1.1392611	journal	January 1999
Electrode Properties of Sr‐Doped LaMnO3 on Yttria‐Stabilized Zirconia: II. Electrode Kinetics van Heuveln, F. H.; Bouwmeester, H. J. M. Journal of The Electrochemical Society, Vol. 144, Issue 1 https://doi.org/10.1149/1.1837375	journal	January 1997
Strong Performance Improvement of La[sub 0.6]Sr[sub 0.4]Co[sub 0.8]Fe[sub 0.2]O[sub 3−δ] SOFC Cathodes by Electrochemical Activation Baumann, Frank S.; Fleig, Jürgen; Konuma, Mitsuharu Journal of The Electrochemical Society, Vol. 152, Issue 10 https://doi.org/10.1149/1.2034529	journal	January 2005
Electrode properties of Ln₂NiO_4 + δ ( Ln = La , Nd , Pr ) AC Impedance and DC Polarization Studies Mauvy, Fabrice; Lalanne, Cécile; Bassat, Jean-Marc Journal of The Electrochemical Society, Vol. 153, Issue 8, p. A1547-A1553 https://doi.org/10.1149/1.2207059	journal	January 2006
Quantitative Comparison of Mixed Conducting SOFC Cathode Materials by Means of Thin Film Model Electrodes Baumann, F. S.; Fleig, J.; Cristiani, G. Journal of The Electrochemical Society, Vol. 154, Issue 9 https://doi.org/10.1149/1.2752974	journal	January 2007
Oxygen Reduction Reaction Kinetics in Sr-Doped La ₂ NiO _4+δ Ruddlesden-Popper Phase as Cathode for Solid Oxide Fuel Cells Guan, Bo; Li, Wenyuan; Zhang, Hui Journal of The Electrochemical Society, Vol. 162, Issue 7 https://doi.org/10.1149/2.0541507jes	journal	January 2015
Characterization of Doped Yttrium Chromites as Electrodes for Solid Oxide Fuel Cell by Impedance Method Li, Wenyuan; Gong, Mingyang; Liu, Xingbo Journal of The Electrochemical Society, Vol. 161, Issue 4 https://doi.org/10.1149/2.096404jes	journal	January 2014
Properties of La2−xPrxNiO4 cathode for intermediate-temperature solid oxide fuel cells Nishimoto, Shunsuke; Takahashi, Suguru; Kameshima, Yoshikazu Journal of the Ceramic Society of Japan, Vol. 119, Issue 1387 https://doi.org/10.2109/jcersj2.119.246	journal	January 2011

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