Visible Light Assisted Photocatalytic Hydrogen Generation by Ta2O5/Bi2O3, TaON/Bi2O3, and Ta3N5/Bi2O3 Composites

Adhikari, Shiba; Hood, Zachary D.; More, Karren Leslie; Ivanov, Ilia N.; Zhang, Lifeng; Gross, Michael; Lachgar, Abdou

doi:10.1039/C5RA06563A

Visible Light Assisted Photocatalytic Hydrogen Generation by Ta₂O₅/Bi₂O₃, TaON/Bi₂O₃, and Ta₃N₅/Bi₂O₃ Composites

Journal Article · Mon Jun 15 00:00:00 UTC 2015 · RSC Advances

DOI:https://doi.org/10.1039/C5RA06563A· OSTI ID:1265786

Adhikari, Shiba ^[1]; Hood, Zachary D. ^[2]; More, Karren Leslie ^[2]; Ivanov, Ilia N. ^[2]; Zhang, Lifeng ^[3]; Gross, Michael ^[1]; Lachgar, Abdou ^[1]

Wake Forest Univ., Winston-Salem, MA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
North Carolina A&T State Univ., Greensboro, NC (United States)

Composites comprised of two semiconducting materials with suitable band gaps and band positions have been reported to be effective at enhancing photocatalytic activity in the visible light region of the electromagnetic spectrum. Here, we report the synthesis, complete structural and physical characterizations, and photocatalytic performance of a series of semiconducting oxide composites. UV light active tantalum oxide (Ta2O5) and visible light active tantalum oxynitride (TaON) and tantalum nitride (Ta₃N₅) were synthesized, and their composites with Bi₂O₃ were prepared in situ using benzyl alcohol as solvent. The composite prepared using equimolar amounts of Bi₂O₃ and Ta₂O₅ leads to the formation of the ternary oxide, bismuth tantalate (BiTaO₄) upon calcination at 1000 °C. The composites and single phase bismuth tantalate formed were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET) surface area measurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis diffuse reflectance spectroscopy, and photoluminescence. The photocatalytic activities of the catalysts were evaluated for generation of hydrogen using aqueous methanol solution under visible light irradiation (λ ≥ 420 nm). The results show that as-prepared composite photocatalysts extend the light absorption range and restrict photogenerated charge-carrier recombination, resulting in enhanced photocatalytic activity compared to individual phases. The mechanism for the enhanced photocatalytic activity for the heterostructured composites is elucidated based on observed activity, band positions calculations, and photoluminescence data.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1265786

Journal Information:: RSC Advances, Journal Name: RSC Advances Journal Issue: 68 Vol. 5; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (63)

Enhanced Photocatalytic Hydrogen Generation Using Polymorphic Macroporous TaON Tsang, Min-Ying; Pridmore, Natalie E.; Gillie, Lisa J. Advanced Materials, Vol. 24, Issue 25 https://doi.org/10.1002/adma.201201193	journal	June 2012
Conduction and Valence Band Positions of Ta2O5, TaON, and Ta3N5 by UPS and Electrochemical Methods. Chun, Wang-Jae; Ishikawa, Akio; Fujisawa, Hideki ChemInform, Vol. 34, Issue 21 https://doi.org/10.1002/chin.200321011	journal	May 2003
Photophysical and Photocatalytic Properties of AgInW2O8. Tang, Junwang; Zou, Zhigang; Ye, Jinhua ChemInform, Vol. 35, Issue 10 https://doi.org/10.1002/chin.200410012	journal	March 2004
Crystal Structures and Photocatalysis of the Triclinic Polymorphs of BiNbO4 and BiTaO4. Muktha, B.; Darriet, J.; Madras, Giridhar ChemInform, Vol. 38, Issue 13 https://doi.org/10.1002/chin.200713003	journal	March 2007
Mesoporous Carbon Nitride-Tungsten Oxide Composites for Enhanced Photocatalytic Hydrogen Evolution Kailasam, Kamalakannan; Fischer, Anna; Zhang, Guigang ChemSusChem, Vol. 8, Issue 8 https://doi.org/10.1002/cssc.201403278	journal	March 2015
Photocatalytic and photophysical properties of a novel series of solid photocatalysts, BiTa1−Nb O4 (0⩽x⩽1) Zou, Zhigang; Ye, Jinhua; Sayama, Kazuhiro Chemical Physics Letters, Vol. 343, Issue 3-4 https://doi.org/10.1016/S0009-2614(01)00702-3	journal	August 2001
Photocatalytic and photoelectrochemical properties of titania–chloroplatinate(IV) Burgeth, Gerald; Kisch, Horst Coordination Chemistry Reviews, Vol. 230, Issue 1-2 https://doi.org/10.1016/S0010-8545(02)00095-4	journal	August 2002
Preparation of bismuth oxide/titania composite particles and their photocatalytic activity to degradation of 4-chlorophenol Xu, Jing-jing; Chen, Min-dong; Fu, De-gang Transactions of Nonferrous Metals Society of China, Vol. 21, Issue 2 https://doi.org/10.1016/S1003-6326(11)60719-X	journal	February 2011
Size dependency of nanocrystalline TiO2 on its optical property and photocatalytic reactivity exemplified by 2-chlorophenol Lin, H.; Huang, C.; Li, W. Applied Catalysis B: Environmental, Vol. 68, Issue 1-2 https://doi.org/10.1016/j.apcatb.2006.07.018	journal	October 2006
A review on the visible light active titanium dioxide photocatalysts for environmental applications Pelaez, Miguel; Nolan, Nicholas T.; Pillai, Suresh C. Applied Catalysis B: Environmental, Vol. 125 https://doi.org/10.1016/j.apcatb.2012.05.036	journal	August 2012
Synthesis, sintering and characterisation of TaON materials Matizamhuka, W. R.; Sigalas, I.; Herrmann, M. Ceramics International, Vol. 34, Issue 6 https://doi.org/10.1016/j.ceramint.2007.04.005	journal	August 2008
Photocatalytic activity of zinc modified Bi2O3 Hameed, Abdul; Gombac, Valentina; Montini, Tiziano Chemical Physics Letters, Vol. 483, Issue 4-6 https://doi.org/10.1016/j.cplett.2009.10.087	journal	December 2009
Tailoring the band structure of β-Bi2O3 by co-doping for realized photocatalytic hydrogen generation Li, Min; Li, Feng; Yin, Peng Gang Chemical Physics Letters, Vol. 601 https://doi.org/10.1016/j.cplett.2014.03.091	journal	May 2014
Advances in visible light responsive titanium oxide-based photocatalysts for CO2 conversion to hydrocarbon fuels Tahir, Muhammad; Amin, NorAishah Saidina Energy Conversion and Management, Vol. 76 https://doi.org/10.1016/j.enconman.2013.07.046	journal	December 2013
Fabrication of CdS nanowires decorated with TiO2 nanoparticles for photocatalytic hydrogen production under visible light irradiation Jang, J.; Kim, H.; Joshi, U. International Journal of Hydrogen Energy, Vol. 33, Issue 21 https://doi.org/10.1016/j.ijhydene.2008.07.105	journal	November 2008
Facile fabrication of Bi2O3/TiO2-xNx nanocomposites for excellent visible light driven photocatalytic hydrogen evolution Naik, Brundabana; Martha, Satyabadi; Parida, K. M. International Journal of Hydrogen Energy, Vol. 36, Issue 4 https://doi.org/10.1016/j.ijhydene.2010.11.104	journal	February 2011
Heterojunctioned BiOCl/Bi2O3, a new visible light photocatalyst Chai, Seung Yong; Kim, Yong Joo; Jung, Myong Hak Journal of Catalysis, Vol. 262, Issue 1 https://doi.org/10.1016/j.jcat.2008.12.020	journal	February 2009
Visible light photocatalytic degradation of dyes by bismuth oxide-reduced graphene oxide composites prepared via microwave-assisted method Liu, Xinjuan; Pan, Likun; Lv, Tian Journal of Colloid and Interface Science, Vol. 408 https://doi.org/10.1016/j.jcis.2013.07.045	journal	October 2013
Roles of TaON and Ta3N5 in the visible-Fenton-like degradation of atrazine Du, Yingxun; Zhao, Lu; Zhang, Yuanyuan Journal of Hazardous Materials, Vol. 267 https://doi.org/10.1016/j.jhazmat.2013.12.042	journal	February 2014
Design of a direct Z-scheme photocatalyst: Preparation and characterization of Bi2O3/g-C3N4 with high visible light activity Zhang, Jinfeng; Hu, Yingfei; Jiang, Xiaoliang Journal of Hazardous Materials, Vol. 280 https://doi.org/10.1016/j.jhazmat.2014.08.055	journal	September 2014
Recent progress on photocatalytic and photoelectrochemical water splitting under visible light irradiation Abe, Ryu Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Vol. 11, Issue 4 https://doi.org/10.1016/j.jphotochemrev.2011.02.003	journal	December 2010
Photocatalytic water splitting using semiconductor particles: History and recent developments Maeda, Kazuhiko Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Vol. 12, Issue 4 https://doi.org/10.1016/j.jphotochemrev.2011.07.001	journal	December 2011
Crystal structures and photocatalysis of the triclinic polymorphs of BiNbO4 and BiTaO4 Muktha, B.; Darriet, J.; Madras, Giridhar Journal of Solid State Chemistry, Vol. 179, Issue 12 https://doi.org/10.1016/j.jssc.2006.08.032	journal	December 2006
Preparation and visible light photocatalytic activity of Bi2O3/Bi2WO6 heterojunction photocatalysts Gui, Ming-Sheng; Zhang, Wei-De; Su, Qing-Xi Journal of Solid State Chemistry, Vol. 184, Issue 8 https://doi.org/10.1016/j.jssc.2011.05.057	journal	August 2011
A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production Ni, Meng; Leung, Michael K. H.; Leung, Dennis Y. C. Renewable and Sustainable Energy Reviews, Vol. 11, Issue 3 https://doi.org/10.1016/j.rser.2005.01.009	journal	April 2007
Electrodeposited p-type Cu2O as photocatalyst for H2 evolution from water reduction in the presence of WO3 Hu, Che-Chia; Nian, Jun-Nan; Teng, Hsisheng Solar Energy Materials and Solar Cells, Vol. 92, Issue 9 https://doi.org/10.1016/j.solmat.2008.03.012	journal	September 2008
Photocatalytic and photophysical properties of a novel series of solid photocatalysts, BiTa1−Nb O4 (0⩽x⩽1) Zou, Zhigang; Ye, Jinhua; Sayama, Kazuhiro Chemical Physics Letters, Vol. 343, Issue 3-4 https://doi.org/10.1016/s0009-2614(01)00702-3	journal	August 2001
Photocatalytic and photoelectrochemical properties of titania–chloroplatinate(IV) Burgeth, Gerald; Kisch, Horst Coordination Chemistry Reviews, Vol. 230, Issue 1-2 https://doi.org/10.1016/s0010-8545(02)00095-4	journal	August 2002
Preparation of bismuth oxide/titania composite particles and their photocatalytic activity to degradation of 4-chlorophenol Xu, Jing-jing; Chen, Min-dong; Fu, De-gang Transactions of Nonferrous Metals Society of China, Vol. 21, Issue 2 https://doi.org/10.1016/s1003-6326(11)60719-x	journal	February 2011
Enhancement of Visible-Light Photocatalysis by Coupling with Narrow-Band-Gap Semiconductor: A Case Study on Bi ₂ S ₃ /Bi ₂ WO ₆ Zhang, Zhijie; Wang, Wenzhong; Wang, Lu ACS Applied Materials & Interfaces, Vol. 4, Issue 2 https://doi.org/10.1021/am2017199	journal	January 2012
Light-Induced Redox Reactions in Nanocrystalline Systems Hagfeldt, Anders.; Graetzel, Michael. Chemical Reviews, Vol. 95, Issue 1 https://doi.org/10.1021/cr00033a003	journal	January 1995
Nitrogen-Doped Titanium Dioxide as Visible-Light-Sensitive Photocatalyst: Designs, Developments, and Prospects Asahi, Ryoji; Morikawa, Takeshi; Irie, Hiroshi Chemical Reviews, Vol. 114, Issue 19 https://doi.org/10.1021/cr5000738	journal	May 2014
Facile Fabrication of an Efficient Oxynitride TaON Photoanode for Overall Water Splitting into H ₂ and O ₂ under Visible Light Irradiation Abe, Ryu; Higashi, Masanobu; Domen, Kazunari Journal of the American Chemical Society, Vol. 132, Issue 34 https://doi.org/10.1021/ja1016552	journal	September 2010
Highly Stable Water Splitting on Oxynitride TaON Photoanode System under Visible Light Irradiation Higashi, Masanobu; Domen, Kazunari; Abe, Ryu Journal of the American Chemical Society, Vol. 134, Issue 16 https://doi.org/10.1021/ja302059g	journal	April 2012
Hematite/Si Nanowire Dual-Absorber System for Photoelectrochemical Water Splitting at Low Applied Potentials Mayer, Matthew T.; Du, Chun; Wang, Dunwei Journal of the American Chemical Society, Vol. 134, Issue 30 https://doi.org/10.1021/ja3051734	journal	July 2012
Conduction and Valence Band Positions of Ta ₂ O ₅ , TaON, and Ta ₃ N ₅ by UPS and Electrochemical Methods Chun, Wang-Jae; Ishikawa, Akio; Fujisawa, Hideki The Journal of Physical Chemistry B, Vol. 107, Issue 8 https://doi.org/10.1021/jp027593f	journal	February 2003
Photophysical and Photocatalytic Properties of AgInW ₂ O ₈ Tang, Junwang; Zou, Zhigang; Ye, Jinhua The Journal of Physical Chemistry B, Vol. 107, Issue 51 https://doi.org/10.1021/jp0359891	journal	December 2003
Structure and Photocatalytic Activity of Ti _{1- x} M _x O _2±δ (M = W, V, Ce, Zr, Fe, and Cu) Synthesized by Solution Combustion Method Nagaveni, K.; Hegde, M. S.; Madras, Giridhar The Journal of Physical Chemistry B, Vol. 108, Issue 52 https://doi.org/10.1021/jp047917v	journal	December 2004
Photocatalytic Activities of Heterojunction Semiconductors Bi ₂ O ₃ /BaTiO ₃ : A Strategy for the Design of Efficient Combined Photocatalysts Lin, Xinping; Xing, Jingcheng; Wang, Wendeng The Journal of Physical Chemistry C, Vol. 111, Issue 49 https://doi.org/10.1021/jp073955d	journal	December 2007
Visible-Light Photocatalytic Degradation of BiTaO ₄ Photocatalyst and Mechanism of Photocorrosion Suppression Shi, Rui; Lin, Jie; Wang, Yajun The Journal of Physical Chemistry C, Vol. 114, Issue 14 https://doi.org/10.1021/jp9101866	journal	March 2010
Design of Porous Silica Supported Tantalum Oxide Hollow Spheres Showing Enhanced Photocatalytic Activity Sharma, Manu; Das, Debashree; Baruah, Arabinda Langmuir, Vol. 30, Issue 11 https://doi.org/10.1021/la500167a	journal	March 2014
One-Step Synthesis of the Nanostructured AgI/BiOI Composites with Highly Enhanced Visible-Light Photocatalytic Performances Cheng, Hefeng; Huang, Baibiao; Dai, Ying Langmuir, Vol. 26, Issue 9 https://doi.org/10.1021/la903943s	journal	May 2010
Electrochemical Photolysis of Water at a Semiconductor Electrode Fujishima, Akira; Honda, Kenichi Nature, Vol. 238, Issue 5358, p. 37-38 https://doi.org/10.1038/238037a0	journal	July 1972
Heterogeneous photocatalyst materials for water splitting Kudo, Akihiko; Miseki, Yugo Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B800489G	journal	January 2009
Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting Osterloh, Frank E. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35266D	journal	January 2013
Semiconductor heterojunction photocatalysts: design, construction, and photocatalytic performances Wang, Huanli; Zhang, Lisha; Chen, Zhigang Chemical Society Reviews, Vol. 43, Issue 15 https://doi.org/10.1039/C4CS00126E	journal	January 2014
Z-scheme photocatalytic hydrogen production over WO ₃ /g-C ₃ N ₄ composite photocatalysts Katsumata, Hideyuki; Tachi, Yusuke; Suzuki, Tohru RSC Adv., Vol. 4, Issue 41 https://doi.org/10.1039/C4RA02511C	journal	January 2014
The electronic structure of tantalum (oxy)nitrides TaON and Ta3N5 Fang, C. M.; Orhan, E.; de Wijs, G. A. Journal of Materials Chemistry, Vol. 11, Issue 4 https://doi.org/10.1039/b005751g	journal	January 2001
Heterogeneous photocatalyst materials for water splitting Kudo, Akihiko; Miseki, Yugo Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/b800489g	journal	January 2009
Solvothermal and surfactant-free synthesis of crystalline Nb2O5, Ta2O5, HfO2, and Co-doped HfO2 nanoparticles Buha, Jelena; Arčon, Denis; Niederberger, Markus Physical Chemistry Chemical Physics, Vol. 12, Issue 47 https://doi.org/10.1039/c0cp01298j	journal	January 2010
Nontraditional template synthesis of microjagged bismuth oxide: a highly efficient visible light responsive photocatalyst Xu, Zhanglian; Tabata, Isao; Hirogaki, Kazumasa Catalysis Science & Technology, Vol. 1, Issue 3 https://doi.org/10.1039/c1cy00069a	journal	January 2011
Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting Osterloh, Frank E. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/c2cs35266d	journal	January 2013
Fabrication, characterization and mechanism of a novel Z-scheme photocatalyst NaNbO3/WO3 with enhanced photocatalytic activity Shifu, Chen; Lei, Ji; Wenming, Tang Dalton Transactions, Vol. 42, Issue 30 https://doi.org/10.1039/c3dt50699a	journal	January 2013
Semiconductor heterojunction photocatalysts: design, construction, and photocatalytic performances Wang, Huanli; Zhang, Lisha; Chen, Zhigang Chemical Society Reviews, Vol. 43, Issue 15 https://doi.org/10.1039/c4cs00126e	journal	January 2014
Z-scheme photocatalytic hydrogen production over WO ₃ /g-C ₃ N ₄ composite photocatalysts Katsumata, Hideyuki; Tachi, Yusuke; Suzuki, Tohru RSC Adv., Vol. 4, Issue 41 https://doi.org/10.1039/c4ra02511c	journal	January 2014
Preparation and visible light photocatalytic activity of Bi ₂ O ₃ /Bi ₂ WO ₆ heterojunction photocatalysts Yan, C. Y.; Yi, W. T.; Xiong, J. IOP Conference Series: Earth and Environmental Science, Vol. 128 https://doi.org/10.1088/1755-1315/128/1/012086	journal	March 2018
Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides Asahi, R. Science, Vol. 293, Issue 5528 https://doi.org/10.1126/science.1061051	journal	July 2001
Visible-light-driven photocatalytic behavior of tantalum-oxynitride and nitride Takata, T.; Hitoki, G.; Kondo, J. N. Research on Chemical Intermediates, Vol. 33, Issue 1-2 https://doi.org/10.1163/156856707779160898	journal	January 2007
Surface Modification of TaON with Monoclinic ZrO ₂ to Produce a Composite Photocatalyst with Enhanced Hydrogen Evolution Activity under Visible Light Maeda, Kazuhiko; Terashima, Hiroaki; Kase, Kentaro Bulletin of the Chemical Society of Japan, Vol. 81, Issue 8 https://doi.org/10.1246/bcsj.81.927	journal	August 2008
The absolute energy positions of conduction and valence bands of selected semiconducting minerals Xu, Yong; Schoonen, Martin A. A. American Mineralogist, Vol. 85, Issue 3-4 https://doi.org/10.2138/am-2000-0416	journal	March 2000
Hydrogen Production from Semiconductor-based Photocatalysis via Water Splitting Liao, Chi-Hung; Huang, Chao-Wei; Wu, Jeffrey C. S. Catalysts, Vol. 2, Issue 4 https://doi.org/10.3390/catal2040490	journal	October 2012
Heterogeneous Photocatalysis: Recent Advances and Applications Ibhadon, Alex; Fitzpatrick, Paul Catalysts, Vol. 3, Issue 1 https://doi.org/10.3390/catal3010189	journal	March 2013
A Review on Visible Light Active Perovskite-Based Photocatalysts Kanhere, Pushkar; Chen, Zhong Molecules, Vol. 19, Issue 12 https://doi.org/10.3390/molecules191219995	journal	December 2014

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