Synergistic Effects of Mixing Sulfone and Ionic Liquid as Safe Electrolytes for Lithium Sulfur Batteries

Liao, Chen; Guo, Bingkun; Sun, Xiao-Guang; Dai, Sheng

doi:10.1002/cssc.201402800

Title: Synergistic Effects of Mixing Sulfone and Ionic Liquid as Safe Electrolytes for Lithium Sulfur Batteries

Journal Article · Wed Nov 26 00:00:00 EST 2014 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201402800· OSTI ID:1265459

Liao, Chen ^[1]; Guo, Bingkun ^[2]; Sun, Xiao-Guang ^[2]; Dai, Sheng ^[3]

Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

A strategy of mixing both an ionic liquid and sulfone is reported to give synergistic effects of reducing viscosity, increasing ionic conductivity, reducing polysulfide dissolution, and improving safety. The mixtures of ionic liquids and sulfones also show distinctly different physicochemical properties, including thermal properties and crystallization behavior. By using these electrolytes, lithium sulfur batteries assembled with lithium and mesoporous carbon composites show a reversible specific capacity of 1265 mAhg-¹ (second cycle) by using 40% 1.0 M lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) in N-methyl-Npropylpyrrolidinium bis(trifluoromethylsulfonyl)imide with 60% 1.0 M LiTFSI in methylisopropylsulfone in the first cycle. This capacity is slightly lower than that obtained in pure 1.0 M LiTFSI as the sulfone electrolyte; however, it exhibits excellent cycling stability and remains as high as 655 mAhg¹ even after 50 cycles. This strategy provides a method to alleviate polysulfide dissolution and redox shuttle phenomena, at the same time, with improved ionic conductivity.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1265459

Journal Information:: ChemSusChem, Vol. 8, Issue 2; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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References (22)

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Graphene-Based Nanocomposites for Energy Storage Ji, Liwen; Meduri, Praveen; Agubra, Victor Advanced Energy Materials, Vol. 6, Issue 16 https://doi.org/10.1002/aenm.201502159	journal	June 2016
Halide-Free Synthesis of Hydrochalcogenide Ionic Liquids of the Type [Cation][HE] (E=S, Se, Te) Finger, Lars H.; Sundermeyer, Jörg Chemistry - A European Journal, Vol. 22, Issue 12 https://doi.org/10.1002/chem.201504577	journal	February 2016
A hybrid ionic liquid-based electrolyte for high-performance lithium–sulfur batteries Lu, Hai; Zhu, Yan; Zheng, Bin New Journal of Chemistry, Vol. 44, Issue 2 https://doi.org/10.1039/c9nj03790j	journal	January 2020
A Rational Balance Design of Hybrid Electrolyte Based on Ionic Liquid and Fluorinated Ether in Lithium Sulfur Batteries Lu, Hai; Chen, Zhen; Yuan, Yan Journal of The Electrochemical Society, Vol. 166, Issue 12 https://doi.org/10.1149/2.0321912jes	journal	January 2019
Efficient Electrolytes for Lithiumâ€“Sulfur Batteries Angulakshmi, Natarajan; Stephan, Arul Manuel Frontiers in Energy Research, Vol. 3 https://doi.org/10.3389/fenrg.2015.00017	journal	May 2015
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