Polymer composites prepared by low-temperature post-irradiation polymerization of C2 F4 in the presence of graphene-like material: synthesis and characterization

Shulga, Yury M.; Vasilets, Victor N.; Kiryukhin, Dmitry P.; Voylov, Dmitry N.; Sokolov, Alexei P.

doi:10.1039/C4RA09074H

Title: Polymer composites prepared by low-temperature post-irradiation polymerization of C₂ F₄ in the presence of graphene-like material: synthesis and characterization

Journal Article · Tue Jan 06 00:00:00 EST 2015 · RSC Advances

DOI:https://doi.org/10.1039/C4RA09074H· OSTI ID:1265454

Shulga, Yury M. ^[1]; Vasilets, Victor N. ^[2]; Kiryukhin, Dmitry P. ^[3]; Voylov, Dmitry N. ^[4]; Sokolov, Alexei P. ^[4]

Russian Academy of Sciences (RAS), Moscow (Russian Federation) Inst. of Problems of Chemical Physics; National Univ. of Science and Technology MISIS, Moscow (Russian Federation)
Russian Academy of Sciences (RAS), Moscow (Russian Federation) Inst. of Energy Problems of Chemical Physics
Russian Academy of Sciences (RAS), Moscow (Russian Federation) Inst. of Problems of Chemical Physics
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Polymer polytetrafluoroethylene (PTFE) microwave exfoliated graphene oxide (MEGO) composites containing up to 80 wt% PTFE were prepared by low-temperature post-irradiation polymerization of C2F4 in the presence of the graphene-like material. Composites were characterized by FTIR, NMR, XPS, SEM, TGA, XRD, broadband dielectric spectroscopy and DSC techniques. The melting point of PTFE in the composite (332.5 °C) was higher than that of pure PTFE by 8.8 C. The measured values of the melting enthalpy (ΔH_m 51.5 and 45.4 J g1) were used to calculate the extent of crystallinity in the PTFE and PTFE MEGO composite (0.63 and 0.55, respectively). No CF3 end groups typical of commercial PTFE have been detected in the PTFE MEGO composites.

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: AC05-00OR22725

OSTI ID:: 1265454

Journal Information:: RSC Advances, Vol. 5, Issue 13; ISSN 2046-2069

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (46)

Observation of a new high-temperature transition in polytetrafluoroethylene Khanna, Yash P.; Chomyn, Georgette; Kumar, Rakesh Macromolecules, Vol. 23, Issue 9 https://doi.org/10.1021/ma00211a015	journal	April 1990
Graphene-Based Polymer Composites and Their Applications Das, Tapan K.; Prusty, Smita Polymer-Plastics Technology and Engineering, Vol. 52, Issue 4 https://doi.org/10.1080/03602559.2012.751410	journal	March 2013
Suppression of wear in graphene polymer composites Kandanur, Sashi S.; Rafiee, Mohammad A.; Yavari, Fazel Carbon, Vol. 50, Issue 9 https://doi.org/10.1016/j.carbon.2011.10.038	journal	August 2012
Preparation and utility of a self-lubricating & anti-wear graphene oxide/nano-polytetrafluoroethylene hybrid Huang, Ting; Li, Tongsheng; Xin, Yuanshi RSC Adv., Vol. 4, Issue 38 https://doi.org/10.1039/C4RA01964D	journal	January 2014
Evolution of Surface Functional Groups in a Series of Progressively Oxidized Graphite Oxides Szabó, Tamás; Berkesi, Ottó; Forgó, Péter Chemistry of Materials, Vol. 18, Issue 11 https://doi.org/10.1021/cm060258+	journal	May 2006
Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite Cote, Laura J.; Cruz-Silva, Rodolfo; Huang, Jiaxing Journal of the American Chemical Society, Vol. 131, Issue 31, p. 11027-11032 https://doi.org/10.1021/ja902348k	journal	August 2009
Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets Lomeda, Jay R.; Doyle, Condell D.; Kosynkin, Dmitry V. Journal of the American Chemical Society, Vol. 130, Issue 48 https://doi.org/10.1021/ja806499w	journal	December 2008
Impact of Atomic Oxygen on the Structure of Graphene Formed on Ir(111) and Pt(111) Vinogradov, N. A.; Schulte, K.; Ng, M. L. The Journal of Physical Chemistry C, Vol. 115, Issue 19 https://doi.org/10.1021/jp111962k	journal	April 2011
The surface analytical characterization of carbon fibers functionalized by H2SO4/HNO3 treatment Zhang, Gaixia; Sun, Shuhui; Yang, Dequan Carbon, Vol. 46, Issue 2 https://doi.org/10.1016/j.carbon.2007.11.002	journal	February 2008
Analysis of reversible melting in polytetrafluoroethylene Radusch, H. -J. Journal of Thermal Analysis and Calorimetry, Vol. 79, Issue 3 https://doi.org/10.1007/s10973-005-0586-9	journal	February 2005
The melting temperature of polytetrafluoroethylene Khanna, Y. P. Journal of Materials Science Letters, Vol. 7, Issue 8 https://doi.org/10.1007/BF00723770	journal	August 1988
Recent advances in graphene based polymer composites Kuilla, Tapas; Bhadra, Sambhu; Yao, Dahu Progress in Polymer Science, Vol. 35, Issue 11 https://doi.org/10.1016/j.progpolymsci.2010.07.005	journal	November 2010
Crystalline Homopolymer-Copolymer Blends: Poly(tetrafluoroethylene)-Poly(tetrafluoroethylene-co-perfluoroalkylvinyl ether) Runt, J.; Jin, L.; Talibuddin, S. Macromolecules, Vol. 28, Issue 8 https://doi.org/10.1021/ma00112a025	journal	April 1995
The chemistry of graphene oxide Dreyer, Daniel R.; Park, Sungjin; Bielawski, Christopher W. Chem. Soc. Rev., Vol. 39, Issue 1 https://doi.org/10.1039/B917103G	journal	January 2010
Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy Yang, Dongxing; Velamakanni, Aruna; Bozoklu, Gülay Carbon, Vol. 47, Issue 1 https://doi.org/10.1016/j.carbon.2008.09.045	journal	January 2009
Graphene−Metal Particle Nanocomposites Xu, Chao; Wang, Xin; Zhu, Junwu The Journal of Physical Chemistry C, Vol. 112, Issue 50 https://doi.org/10.1021/jp807989b	journal	November 2008
Study on wear and friction behavior of graphite flake-filled PTFE composites Goyal, R. K.; Yadav, M. Journal of Applied Polymer Science, Vol. 127, Issue 4 https://doi.org/10.1002/app.37707	journal	May 2012
Graphene Oxide Papers Modified by Divalent Ions—Enhancing Mechanical Properties via Chemical Cross-Linking Park, Sungjin; Lee, Kyoung-Seok; Bozoklu, Gulay ACS Nano, Vol. 2, Issue 3 https://doi.org/10.1021/nn700349a	journal	March 2008
Synthesis of Water Soluble Graphene Si, Yongchao; Samulski, Edward T. Nano Letters, Vol. 8, Issue 6 https://doi.org/10.1021/nl080604h	journal	June 2008
Many-electron singularity in X-ray photoemission and X-ray line spectra from metals Doniach, S.; Sunjic, M. Journal of Physics C: Solid State Physics, Vol. 3, Issue 2 https://doi.org/10.1088/0022-3719/3/2/010	journal	February 1970
Carbon-Based Supercapacitors Produced by Activation of Graphene Zhu, Y.; Murali, S.; Stoller, M. D. Science, Vol. 332, Issue 6037, p. 1537-1541 https://doi.org/10.1126/science.1200770	journal	May 2011
Evolution of Electrical, Chemical, and Structural Properties of Transparent and Conducting Chemically Derived Graphene Thin Films Mattevi, Cecilia; Eda, Goki; Agnoli, Stefano Advanced Functional Materials, Vol. 19, Issue 16 https://doi.org/10.1002/adfm.200900166	journal	August 2009
Chemical structure and physical properties of radiation-induced crosslinking of polytetrafluoroethylene Oshima, Akihiro; Ikeda, Shigetoshi; Katoh, Etsuko Radiation Physics and Chemistry, Vol. 62, Issue 1 https://doi.org/10.1016/S0969-806X(01)00420-0	journal	July 2001
Manganosite–microwave exfoliated graphene oxide composites for asymmetric supercapacitor device applications Antiohos, Dennis; Pingmuang, Kanlaya; Romano, Mark S. Electrochimica Acta, Vol. 101 https://doi.org/10.1016/j.electacta.2012.10.007	journal	July 2013
Direct Electrochemistry of Glucose Oxidase and Biosensing for Glucose Based on Graphene Shan, Changsheng; Yang, Huafeng; Song, Jiangfeng Analytical Chemistry, Vol. 81, Issue 6, p. 2378-2382 https://doi.org/10.1021/ac802193c	journal	March 2009
Gaseous products of thermo- and photo-reduction of graphite oxide Shulga, Y. M.; Martynenko, V. M.; Muradyan, V. E. Chemical Physics Letters, Vol. 498, Issue 4-6 https://doi.org/10.1016/j.cplett.2010.08.056	journal	October 2010
Initial Stages of Oxidation on Graphitic Surfaces: Photoemission Study and Density Functional Theory Calculations Barinov, Alexei; Malcioǧlu, O. Bariş; Fabris, Stefano The Journal of Physical Chemistry C, Vol. 113, Issue 21 https://doi.org/10.1021/jp902051d	journal	April 2009
Atomic oxygen functionalization of double walled C nanotubes Larciprete, R.; Gardonio, S.; Petaccia, L. Carbon, Vol. 47, Issue 11 https://doi.org/10.1016/j.carbon.2009.05.008	journal	September 2009
Melting and crystallization behavior of poly(tetrafluoroethylene). New method for molecular weight measurement of poly(tetrafluoroethylene) using a differential scanning calorimeter Suwa, Takeshi; Takehisa, Masaaki; Machi, Sueo Journal of Applied Polymer Science, Vol. 17, Issue 11 https://doi.org/10.1002/app.1973.070171102	journal	November 1973
Preparation of Graphitic Oxide Hummers, William S.; Offeman, Richard E. Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339 https://doi.org/10.1021/ja01539a017	journal	March 1958
Investigation of adhesion wear of filled polytetrafluoroethylene by ESCA, AES and XRD Deli, Gong; Bing, Zhang; Qun-Ji, Xue Wear, Vol. 137, Issue 1 https://doi.org/10.1016/0043-1648(90)90015-3	journal	April 1990
Core-level XPS spectra of fullerene, highly oriented pyrolitic graphite, and glassy carbon Leiro, J. A.; Heinonen, M. H.; Laiho, T. Journal of Electron Spectroscopy and Related Phenomena, Vol. 128, Issue 2-3 https://doi.org/10.1016/S0368-2048(02)00284-0	journal	February 2003
Polymerization of Tetrafluoroethylene in a Hybrid Carbon Dioxide/Aqueous Medium Romack, T. J.; Kipp, B. E.; DeSimone, J. M. Macromolecules, Vol. 28, Issue 24 https://doi.org/10.1021/ma00128a066	journal	November 1995
Atomic Force and Scanning Tunneling Microscopy Imaging of Graphene Nanosheets Derived from Graphite Oxide Paredes, J. I.; Villar-Rodil, S.; Solís-Fernández, P. Langmuir, Vol. 25, Issue 10 https://doi.org/10.1021/la804216z	journal	May 2009
The Fabrication, Properties, and Uses of Graphene/Polymer Composites Du, Jinhong; Cheng, Hui-Ming Macromolecular Chemistry and Physics, Vol. 213, Issue 10-11 https://doi.org/10.1002/macp.201200029	journal	May 2012
Low-temperature radiation chemistry Kiryukhin, D. P. High Energy Chemistry, Vol. 45, Issue 3 https://doi.org/10.1134/S0018143911030076	journal	May 2011
Kinetic calorimetry in the study of the mechanism of low-temperature chemical reactions Barkalov, I. M.; Kiryukhin, D. P. International Reviews in Physical Chemistry, Vol. 13, Issue 2 https://doi.org/10.1080/01442359409353299	journal	September 1994
Solid state 19F NMR determination of new structure formation in FEP following radiolysis at 300 and 363K Forsythe, J. S.; Hill, D. J. T.; Mohajerani, S. Radiation Physics and Chemistry, Vol. 60, Issue 4-5 https://doi.org/10.1016/S0969-806X(01)00182-7	journal	January 2001
Oxygen reduction on rotating porous cylinder of modified reticulated vitreous carbon Awad, Mohamed Ismail; Saleh, Mahmoud M.; Ohsaka, Takeo Journal of Solid State Electrochemistry, Vol. 12, Issue 3 https://doi.org/10.1007/s10008-007-0385-2	journal	July 2007
Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors Zhu, Yanwu; Murali, Shanthi; Stoller, Meryl D. Carbon, Vol. 48, Issue 7 https://doi.org/10.1016/j.carbon.2010.02.001	journal	June 2010
X-ray photoelectron spectroscopic studies of carbon-fibre surfaces. Part 4.—The effect of electrochemical treatment in nitric acid Kozlowski, Carol; Sherwood, Peter M. A. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 80, Issue 8 https://doi.org/10.1039/f19848002099	journal	January 1984
Radiation induced crosslinking of polytetrafluoroethylene Oshima, Akihiro; Tabata, Yoneho; Kudoh, Hisaaki Radiation Physics and Chemistry, Vol. 45, Issue 2 https://doi.org/10.1016/0969-806X(94)E0009-8	journal	February 1995
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Lee, C.; Wei, X.; Kysar, J. W. Science, Vol. 321, Issue 5887, p. 385-388 https://doi.org/10.1126/science.1157996	journal	July 2008
Thermal stability of graphite oxide Jeong, Hae-Kyung; Lee, Yun Pyo; Jin, Mei Hua Chemical Physics Letters, Vol. 470, Issue 4-6 https://doi.org/10.1016/j.cplett.2009.01.050	journal	March 2009
Preparation and characterization of graphene oxide paper Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J. Nature, Vol. 448, Issue 7152, p. 457-460 https://doi.org/10.1038/nature06016	journal	July 2007
Dual Path Mechanism in the Thermal Reduction of Graphene Oxide Larciprete, Rosanna; Fabris, Stefano; Sun, Tao Journal of the American Chemical Society, Vol. 133, Issue 43 https://doi.org/10.1021/ja205168x	journal	November 2011

Similar Records

Kinetics of a methyl methacrylate polymerization initiated by the stable free radicals in irradiated polytetrafluoroethylene and properties of the resultant graft polymer

Thesis/Dissertation · Thu Jan 01 00:00:00 EST 1987 · OSTI ID:1265454

Donato, K A.E.

Effect of ionizing radiation on the chemical composition, crystalline content and structure, and flow properties of polytetrafluoroethylene. [0. 5 to 0. 8 MeV electron beams]

Journal Article · Thu Oct 01 00:00:00 EDT 1981 · J. Polym. Sci., Polym. Chem. Ed.; (United States) · OSTI ID:1265454

Fisher, W K; Corelli, J C

Cross-linking of polytetrafluoroethylene during room-temperature irradiation

Journal Article · Tue Jan 01 00:00:00 EST 2008 · Journal of Polymer Chemistry Part A: Polymer Chemistry · OSTI ID:1265454

Pugmire, David L; Wetteland, Chris J; Duncan, Wanda S; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Polymer composites prepared by low-temperature post-irradiation polymerization of C2 F4 in the presence of graphene-like material: synthesis and characterization

Citation Formats

References (46)

Similar Records

Related Subjects

Title: Polymer composites prepared by low-temperature post-irradiation polymerization of C₂ F₄ in the presence of graphene-like material: synthesis and characterization