Poly(styrene-graft-hyperbranched polyglycidol): synthesis and solution behavior of a hyperbranched polyelectrolyte

Goodwin, Andrew; Bobade, Sachin; Kang, Nam-Goo; Baskaran, Durairaj; Hong, Kunlun; Mays, Jimmy

doi:10.1039/C4RA11568F

Title: Poly(styrene-graft-hyperbranched polyglycidol): synthesis and solution behavior of a hyperbranched polyelectrolyte

Journal Article · Thu Dec 18 00:00:00 EST 2014 · RSC Advances

DOI:https://doi.org/10.1039/C4RA11568F· OSTI ID:1265451

Goodwin, Andrew ^[1]; Bobade, Sachin ^[1]; Kang, Nam-Goo ^[1]; Baskaran, Durairaj ^[1]; Hong, Kunlun ^[2]; Mays, Jimmy ^[3]

Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

This work presents a three-step synthetic procedure to obtain a hypergrafted copolymer composed of a glassy backbone with flexible branched pendant segments. The desired hypergrafted structure was obtained by using a polyfunctional macroinitiator, linear poly(styreneco- 4-hydroxystyrene), to yield polystyrene-graft-hyperbranched polyglycidol with randomly placed branch junctions. Atomic force microscopy, dynamic light scattering, and viscometry probed the aggregation and viscometric behavior of the polymer in DMF and DMF LiBr solutions. The polymer exhibited polyelectrolyte behavior demonstrated by a large increase in the reduced viscosity prior to neutralization with LiBr salt. Additionally, conformational changes were observed by dynamic light scattering in both the average aggregate size and aggregate population with the addition of LiBr salt.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: AC05-00OR22725

OSTI ID:: 1265451

Journal Information:: RSC Advances, Vol. 5, Issue 8; ISSN 2046-2069

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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