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Magnetic control of valley pseudospin in monolayer WSe2

Journal Article · · Nature Physics
DOI:https://doi.org/10.1038/nphys3201· OSTI ID:1265429
 [1];  [2];  [1];  [3];  [4];  [4];  [3];  [1];  [2];  [1]
  1. Univ. of Washington, Seattle, WA (United States)
  2. Univ. of Hong Kong, Hong Kong (China)
  3. Univ. of Texas-Dallas, Richardson, TX (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Univ. of Tennessee, Knoxville, TN (United States)
Local energy extrema of the bands in momentum space, or valleys, can endow electrons in solids with pseudo-spin in addition to real spin1-5. In transition metal dichalcogenides this valley pseudo-spin, like real spin, is associated with a magnetic moment1,6 which underlies the valley-dependent circular dichroism6 that allows optical generation of valley polarization7-9, intervalley quantum coherence10, and the valley Hall effect11. However, magnetic manipulation of valley pseudospin via this magnetic moment12-13, analogous to what is possible with real spin, has not been shown before. Here we report observation of the valley Zeeman splitting and magnetic tuning of polarization and coherence of the excitonic valley pseudospin, by performing polarization-resolved magneto-photoluminescence on monolayer WSe2. Our measurements reveal both the atomic orbital and lattice contributions to the valley orbital magnetic moment; demonstrate the deviation of the band edges in the valleys from an exact massive Dirac fermion model; and reveal a striking difference between the magnetic responses of neutral and charged valley excitons which is explained by renormalization of the excitonic spectrum due to strong exchange interactions.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC05-00OR22725; SC0008145; SC0002197
OSTI ID:
1265429
Journal Information:
Nature Physics, Journal Name: Nature Physics Journal Issue: 2 Vol. 11; ISSN 1745-2473
Publisher:
Nature Publishing Group (NPG)Copyright Statement
Country of Publication:
United States
Language:
English

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Valley Polarization by Spin Injection in a Light-Emitting van der Waals Heterojunction journal August 2016
Microsecond dark-exciton valley polarization memory in two-dimensional heterostructures journal February 2018
Evidence for line width and carrier screening effects on excitonic valley relaxation in 2D semiconductors journal July 2018
Emerging photoluminescence from the dark-exciton phonon replica in monolayer WSe2 journal June 2019
Enhancing and controlling valley magnetic response in MoS2/WS2 heterostructures by all-optical route journal September 2019
Gate controlled valley polarizer in bilayer graphene journal March 2020
Giant Valley Coherence at Room Temperature in 3R WS 2 with Broken Inversion Symmetry journal October 2019
Valley-selective directional emission from a transition-metal dichalcogenide monolayer mediated by a plasmonic nanoantenna journal January 2018
Valley coherent exciton-polaritons in a monolayer semiconductor text January 2018
Giant Valley Splitting in Monolayer WS2 by Magnetic Proximity Effect text January 2019
Valley Phonons and Exciton Complexes in a Monolayer Semiconductor text January 2020
Giant magnetic splitting inducing near-unity valley polarization in van der Waals heterostructures text January 2017
Atomically Thin MoS 2 : A Versatile Nongraphene 2D Material journal February 2016
Epitaxial Stitching and Stacking Growth of Atomically Thin Transition-Metal Dichalcogenides (TMDCs) Heterojunctions journal January 2017
Continuous Control and Enhancement of Excitonic Valley Polarization in Monolayer WSe 2 by Electrostatic Doping journal March 2019
Facile and Versatile Functionalization of Two‐Dimensional Carbon Nitrides by Design: Magnetism/Multiferroicity, Valleytronics, and Photovoltaics journal August 2019
Phase‐Tunable Synthesis of Ultrathin Layered Tetragonal CoSe and Nonlayered Hexagonal CoSe Nanoplates journal April 2019
Room‐Temperature Active Modulation of Valley Dynamics in a Monolayer Semiconductor through Chiral Purcell Effects journal October 2019
Synthesis of Co‐Doped MoS 2 Monolayers with Enhanced Valley Splitting journal February 2020
Biaxial Strain and Electric Field Dependent Conductivity of Monolayer WTe 2 on Top of Fe 3 O 4 (111) journal August 2016
Luminescence in 2D Materials and van der Waals Heterostructures journal March 2018
Light Emission Properties of 2D Transition Metal Dichalcogenides: Fundamentals and Applications journal August 2018
Inorganic 2D Luminescent Materials: Structure, Luminescence Modulation, and Applications journal October 2019
Recent Advances in van der Waals Heterojunctions Based on Semiconducting Transition Metal Dichalcogenides journal August 2018
Spatial variations of valley splitting in monolayer transition metal dichalcogenide journal November 2019
Spin and valley dynamics of excitons in transition metal dichalcogenide monolayers: Spin and valley dynamics of excitons in transition metal dichalcogenide monolayers journal October 2015
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Probing and Tuning the Spin Textures of the K and Q Valleys in Few‐Layer MoS 2 journal May 2019
Recent Advances in Quantum Effects of 2D Materials journal April 2019
Light Sources and Photodetectors Enabled by 2D Semiconductors journal May 2018
Properties of Transition Metal Dichalcogenides book January 2019
Environmental engineering of transition metal dichalcogenide optoelectronics journal June 2018
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Exciton diamagnetic shifts and valley Zeeman effects in monolayer WS2 and MoS2 to 65 Tesla journal February 2016
Even–odd layer-dependent magnetotransport of high-mobility Q-valley electrons in transition metal disulfides journal September 2016
Concepts of ferrovalley material and anomalous valley Hall effect journal December 2016
Directional interlayer spin-valley transfer in two-dimensional heterostructures journal December 2016
Optically initialized robust valley-polarized holes in monolayer WSe2 journal November 2015
Robust reconfigurable electromagnetic pathways within a photonic topological insulator journal February 2016
Valley magnetoelectricity in single-layer MoS2 journal July 2017
Optically active quantum dots in monolayer WSe2 journal May 2015
Single quantum emitters in monolayer semiconductors journal May 2015
Valley- and spin-polarized Landau levels in monolayer WSe2 journal October 2016
Enhanced valley splitting in monolayer WSe2 due to magnetic exchange field journal May 2017
Photonics and optoelectronics of 2D semiconductor transition metal dichalcogenides journal March 2016
Divide and polarize journal January 2015
Generation and detection of pure valley current by electrically induced Berry curvature in bilayer graphene journal November 2015
Excitonic luminescence upconversion in a two-dimensional semiconductor journal December 2015
Optical manipulation of valley pseudospin journal September 2016
Charge-tuneable biexciton complexes in monolayer WSe2 journal September 2018
Biexcitons in monolayer transition metal dichalcogenides tuned by magnetic fields journal September 2018
Revealing the biexciton and trion-exciton complexes in BN encapsulated WSe2 journal September 2018
Valley coherent exciton-polaritons in a monolayer semiconductor journal November 2018
Beating the exclusion rule against the coexistence of robust luminescence and ferromagnetism in chalcogenide monolayers journal April 2019
The valley Zeeman effect in inter- and intra-valley trions in monolayer WSe2 journal May 2019
Giant valley splitting in monolayer WS2 by magnetic proximity effect journal September 2019
Valley phonons and exciton complexes in a monolayer semiconductor journal January 2020
Repairing atomic vacancies in single-layer MoSe2 field-effect transistor and its defect dynamics journal March 2017
Giant spin-valley polarization and multiple Hall effect in functionalized bismuth monolayers journal August 2018
Ambipolar Landau levels and strong band-selective carrier interactions in monolayer WSe2 journal March 2018
Optical initialization of a single spin-valley in charged WSe2 quantum dots journal March 2019
Light–valley interactions in 2D semiconductors journal July 2018
Polarization switching and electrical control of interlayer excitons in two-dimensional van der Waals heterostructures journal December 2018
Valley optomechanics in a monolayer semiconductor journal May 2019
Entanglement of single-photons and chiral phonons in atomically thin WSe2 journal December 2018
Signatures of moiré-trapped valley excitons in MoSe2/WSe2 heterobilayers journal February 2019
Enhanced interlayer neutral excitons and trions in trilayer van der Waals heterostructures journal September 2018
Identifying defect-related quantum emitters in monolayer WSe2 journal February 2020
Tunable Valley Polarization and Valley Orbital Magnetic Moment Hall Effect in Honeycomb Systems with Broken Inversion Symmetry journal September 2015
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Generation of large spin and valley currents in a quantum pump based on molybdenum disulfide journal January 2017
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The magnetic proximity effect and electrical field tunable valley degeneracy in MoS 2 /EuS van der Waals heterojunctions journal January 2017
Electronic-dimensionality reduction of bulk MoS 2 by hydrogen treatment journal January 2018
An ab initio study of sensing applications of MoB 2 monolayer: a potential gas sensor journal January 2019
Composition modulation in one-dimensional and two-dimensional chalcogenide semiconductor nanostructures journal January 2018
Tunable valley and spin splitting in 2 H -VSe 2 /BiFeO 3 (111) triferroic heterostructures journal January 2019
Tunable valley splitting and an anomalous valley Hall effect in hole-doped WS 2 by proximity coupling with a ferromagnetic MnO 2 monolayer journal January 2019
Spin polarization and tunable valley degeneracy in a MoS 2 monolayer via proximity coupling to a Cr 2 O 3 substrate journal January 2019
Biaxial strain induced band transition and valley–spin coupling in the ferromagnetic semiconducting WSe 2 /1T-FeCl 2 heterostructure journal January 2019
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Discrete quantum dot like emitters in monolayer MoSe 2 : Spatial mapping, magneto-optics, and charge tuning journal April 2016
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Valley Zeeman splitting of monolayer MoS 2 probed by low-field magnetic circular dichroism spectroscopy at room temperature journal April 2018
Research Update: Recent progress on 2D materials beyond graphene: From ripples, defects, intercalation, and valley dynamics to straintronics and power dissipation journal August 2018
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Valleytronic properties of monolayer WSe 2 in external magnetic field journal April 2019
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Magneto-spectroscopy of exciton Rydberg states in a CVD grown WSe 2 monolayer journal June 2019
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Low-dimensional ScO 2 with tunable electronic and magnetic properties: first-principles studies journal November 2015
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Tuning of impurity-bound interlayer complexes in a van der Waals heterobilayer journal May 2019
Controlling valley splitting and polarization of dark- and bi-excitons in monolayer WS 2 by a tilted magnetic field journal July 2019
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Proximity exchange effects in MoSe 2 and WSe 2 heterostructures with CrI 3 : Twist angle, layer, and gate dependence journal August 2019
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Hole spin relaxation in bilayer WSe 2 journal October 2015
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Long valley relaxation time of free carriers in monolayer WSe 2 journal June 2017
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Large valley splitting in monolayer WS 2 by proximity coupling to an insulating antiferromagnetic substrate journal January 2018
Strong valley Zeeman effect of dark excitons in monolayer transition metal dichalcogenides in a tilted magnetic field journal February 2018
Band nesting, massive Dirac fermions, and valley Landé and Zeeman effects in transition metal dichalcogenides: A tight-binding model journal February 2018
Excitons, trions, and biexcitons in transition-metal dichalcogenides: Magnetic-field dependence journal May 2018
Exciton-polarons in doped semiconductors in a strong magnetic field journal June 2018
Band structure of monolayer transition-metal dichalcogenides and topological properties of their nanoribbons: Next-nearest-neighbor hopping journal August 2018
Valley-polarized magnetic state in hole-doped monolayers of transition-metal dichalcogenides journal October 2018
Monolayer transition metal dichalcogenides in strong magnetic fields: Validating the Wannier model using a microscopic calculation journal January 2019
Spectrum of exciton states in monolayer transition metal dichalcogenides: Angular momentum and Landau levels journal March 2019
Valley splitting in the van der Waals heterostructure WSe 2 / CrI 3 : The role of atom superposition journal March 2019
Magnetophotoluminescence of exciton Rydberg states in monolayer WS e 2 journal May 2019
Double Resonant Raman Scattering and Valley Coherence Generation in Monolayer WSe 2 journal September 2015
Electrical Tuning of Exciton Binding Energies in Monolayer WS 2 journal September 2015
Anomalous Light Cones and Valley Optical Selection Rules of Interlayer Excitons in Twisted Heterobilayers journal October 2015
Exciton Band Structure in Two-Dimensional Materials journal February 2016
Shubnikov–de Haas Oscillations of High-Mobility Holes in Monolayer and Bilayer WSe 2 : Landau Level Degeneracy, Effective Mass, and Negative Compressibility journal February 2016
Magnetic-Field-Induced Rotation of Polarized Light Emission from Monolayer WS 2 journal August 2016
Odd-Integer Quantum Hall States and Giant Spin Susceptibility in p -Type Few-Layer WSe 2 journal February 2017
Topological Exciton Bands in Moiré Heterojunctions journal April 2017
Giant Paramagnetism-Induced Valley Polarization of Electrons in Charge-Tunable Monolayer MoSe 2 journal June 2017
Density-Dependent Quantum Hall States and Zeeman Splitting in Monolayer and Bilayer WSe 2 journal June 2017
Strongly Interaction-Enhanced Valley Magnetic Response in Monolayer WSe 2 journal February 2018
Zeeman Splitting and Inverted Polarization of Biexciton Emission in Monolayer WS 2 journal August 2018
Experimental Observation of Hidden Berry Curvature in Inversion-Symmetric Bulk 2 H − WSe 2 journal October 2018
Spin and Charge Transport of Multiorbital Quantum Spin Hall Insulators journal May 2019
Gate Tunable Dark Trions in Monolayer WSe 2 journal July 2019
Strain Engineering of the Berry Curvature Dipole and Valley Magnetization in Monolayer MoS 2 journal July 2019
Interaction-Induced Shubnikov–de Haas Oscillations in Optical Conductivity of Monolayer MoSe 2 journal August 2019
Valley-Layer Coupling: A New Design Principle for Valleytronics journal January 2020
Optical spectroscopy of excited exciton states in MoS 2 monolayers in van der Waals heterostructures journal January 2018
Electrical valley filtering in transition metal dichalcogenides journal March 2018
Valley-selective chiral phonon replicas of dark excitons and trions in monolayer WS e 2 journal October 2019
Topological Polaritons journal July 2015
Excitonic Linewidth Approaching the Homogeneous Limit in MoS 2 -Based van der Waals Heterostructures journal May 2017
Colloquium : Excitons in atomically thin transition metal dichalcogenides journal April 2018
Broadband transient THz conductivity of the transition-metal dichalcogenide MoS 2 conference March 2015
Observation of ultralong valley lifetime in WSe 2 /MoS 2 heterostructures journal July 2017
Electrotunable artificial molecules based on van der Waals heterostructures journal October 2017
Ultrafast generation of pseudo-magnetic field for valley excitons in WSe 2 monolayers journal December 2014
Tunable excitons in bilayer graphene journal November 2017
Imaging of pure spin-valley diffusion current in WS 2 -WSe 2 heterostructures journal May 2018
Optical properties of atomically thin transition metal dichalcogenides: observations and puzzles journal January 2017
Magneto-optics in transition metal diselenide monolayers text January 2015
Universal low-temperature Ohmic contacts for quantum transport in transition metal dichalcogenides text January 2015
Anomalous light cones and valley optical selection rules of interlayer excitons in twisted heterobilayers text January 2015
Discrete quantum dot like emitters in monolayer MoSe2: Spatial mapping, Magneto-optics and Charge tuning text January 2016
Concepts of Ferrovalley Material and Anomalous Valley Hall Effect text January 2016
Directional Interlayer Spin-Valley Transfer in Two-Dimensional Heterostructures text January 2016
Spin-Degenerate Regimes for Single Quantum Dots in Transition Metal Dichalcogenide Monolayers text January 2017
Band nesting, massive Dirac Fermions and Valley Lande and Zeeman effects in transition metal dichalcogenides: a tight-binding model text January 2017
Twisting Dirac fermions: Circular dichroism in bilayer graphene text January 2017
Enhanced interlayer neutral excitons and trions in trilayer van der Waals heterostructures text January 2017
Ambipolar Landau levels and strong band-selective carrier interactions in monolayer WSe$_2$ text January 2017
Symmetry-forbidden intervalley scattering by atomic defects in monolayer transition-metal dichalcogenides text January 2017
Spin-orbit coupling induced valley Hall effects in transition-metal dichalcogenides text January 2017
Strong Valley Zeeman Effect of Dark Excitons in Monolayer Transition Metal Dichalcogenides in a Tilted Magnetic Field text January 2018
Entanglement of single-photons and chiral phonons in atomically thin WSe$_2$ text January 2018
Excitonic magneto-optics in monolayer transition metal dichalcogenides: From nanoribbons to two-dimensional response text January 2019
Magneto-spectroscopy of exciton Rydberg states in a CVD grown WSe2 monolayer text January 2019
Geometric band properties in strained monolayer transition metal dichalcogenides using simple band structures text January 2019
Identifying defect-related quantum emitters in monolayer WSe$_2$ text January 2020
Negative flat band magnetism in a spin–orbit-coupled correlated kagome magnet text January 2019
Zeeman Splitting and Inverted Polarization of Biexciton Emission in Monolayer WS2 text January 2018
Colloquium : Excitons in atomically thin transition metal dichalcogenides text January 2018

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