Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts

Conference ·
OSTI ID:126454

Carbon monoxide insertion is a key step toward the formation of higher oxygenates on hydroformylation and the Fischer-Tropsch synthesis. Steady-state isotopic transient and in situ infrared have been employed to determine the effect of partial pressure of reactants on the reactivity and the coverages of IR-observable adsorbates and reaction intermediates leading to the formation of propionaldehyde during ethylene hydroformylation on rhodium/silica.

OSTI ID:
126454
Report Number(s):
CONF-950402--
Country of Publication:
United States
Language:
English

Similar Records

Dynamic and LHHW kinetic analysis of heterogeneous catalytic hydroformylation
Journal Article · Tue Jan 31 23:00:00 EST 1995 · Journal of Catalysis · OSTI ID:175712

Kinetics and dynamics of heterogeneous hydroformylation Rh catalyst
Journal Article · Sat Dec 30 23:00:00 EST 1995 · Preprints of Papers, American Chemical Society, Division of Fuel Chemistry · OSTI ID:433263

Transient infrared study of methanation and ethylene hydroformylation over Rh/SiO[sub 2] catalysts
Journal Article · Sun Feb 28 23:00:00 EST 1993 · Journal of Catalysis; (United States) · OSTI ID:6305002