Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts

Conference · Fri Dec 01 00:00:00 EST 1995

OSTI ID:126454

Chuang, S S.C.; Brundage, M A; Balakos, M W ^[1]

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1. Univ. of Akron, OH (United States)

Carbon monoxide insertion is a key step toward the formation of higher oxygenates on hydroformylation and the Fischer-Tropsch synthesis. Steady-state isotopic transient and in situ infrared have been employed to determine the effect of partial pressure of reactants on the reactivity and the coverages of IR-observable adsorbates and reaction intermediates leading to the formation of propionaldehyde during ethylene hydroformylation on rhodium/silica.

• OSTI ID: 126454
• Report Number(s): CONF-950402-; TRN: 95:006086-0438
• Resource Relation: Conference: 209. American Chemical Society (ACS) national meeting, Anaheim, CA (United States), 2-6 Apr 1995; Other Information: PBD: 1995; Related Information: Is Part Of 209th ACS national meeting; PB: 2088 p.
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
10 SYNTHETIC FUELS
ALCOHOLS
CHEMICAL PREPARATION
RHODIUM
CATALYTIC EFFECTS
CARBON MONOXIDE
CATALYSTS
ETHYLENE
FISCHER-TROPSCH SYNTHESIS
PARTIAL PRESSURE
REACTION INTERMEDIATES
SILICA
FUELS
CHEMICAL REACTION KINETICS