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Methods of making non-covalently bonded carbon-titania nanocomposite thin films and applications of the same

Patent ·
OSTI ID:1264475

In one aspect, a method of making non-covalently bonded carbon-titania nanocomposite thin films includes: forming a carbon-based ink; forming a titania (TiO.sub.2) solution; blade-coating a mechanical mixture of the carbon-based ink and the titania solution onto a substrate; and annealing the blade-coated substrate at a first temperature for a first period of time to obtain the carbon-based titania nanocomposite thin films. In certain embodiments, the carbon-based titania nanocomposite thin films may include solvent-exfoliated graphene titania (SEG-TiO.sub.2) nanocomposite thin films, or single walled carbon nanotube titania (SWCNT-TiO.sub.2) nanocomposite thin films.

Research Organization:
Northwestern University, Evanston, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-03ER15457
Assignee:
Northwestern University (Evanston, IL)
Patent Number(s):
9,393,550
Application Number:
13/745,092
OSTI ID:
1264475
Country of Publication:
United States
Language:
English

References (43)

Boron nitride substrates for high-quality graphene electronics journal August 2010
Photocatalytic Carbon-Nanotube-TiO2 Composites journal June 2009
Highly Concentrated Graphene Solutions via Polymer Enhanced Solvent Exfoliation and Iterative Solvent Exchange journal December 2010
A One-Step, Solvothermal Reduction Method for Producing Reduced Graphene Oxide Dispersions in Organic Solvents journal June 2010
Towards Rationally Designed Graphene-Based Materials and Devices journal March 2012
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene journal July 2008
New insights into the structure and reduction of graphite oxide journal July 2009
Emerging Methods for Producing Monodisperse Graphene Dispersions journal December 2009
100-GHz Transistors from Wafer-Scale Epitaxial Graphene journal February 2010
To What Extent Do Graphene Scaffolds Improve the Photovoltaic and Photocatalytic Response of TiO 2 Nanostructured Films? journal July 2010
Progress towards monodisperse single-walled carbon nanotubes journal May 2008
Hydrothermal Route for Cutting Graphene Sheets into Blue-Luminescent Graphene Quantum Dots journal February 2010
Toward Solar Fuels: Photocatalytic Conversion of Carbon Dioxide to Hydrocarbons journal February 2010
Electric Field Effect in Atomically Thin Carbon Films journal October 2004
Enhanced photocatalytic H2-production activity of graphene-modified titania nanosheets journal January 2011
P25-Graphene Composite as a High Performance Photocatalyst journal December 2009
A synergistic assembly of nanoscale lamellar photoconductor hybrids journal December 2008
Enhancement of Photoexcited Charge Transfer by {001} Facet-Dominating TiO 2 Nanoparticles journal October 2011
Photoreactive TiO 2 /Carbon Nanotube Composites: Synthesis and Reactivity journal July 2008
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results journal May 1995
Nonradiative recombination of excitons in carbon nanotubes mediated by free charge carriers journal October 2008
Enhanced photocatalytic activity of mesoporous TiO 2 aggregates by embedding carbon nanotubes as electron-transfer channel journal January 2011
Graphene-Based Nanoarchitectures. Anchoring Semiconductor and Metal Nanoparticles on a Two-Dimensional Carbon Support journal December 2009
Graphene-Based Nanoassemblies for Energy Conversion journal January 2011
Electrochemical Photolysis of Water at a Semiconductor Electrode journal July 1972
Synergetic Effect of MoS 2 and Graphene as Cocatalysts for Enhanced Photocatalytic H 2 Production Activity of TiO 2 Nanoparticles journal April 2012
Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders journal February 1979
Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets journal November 2007
Anatase TiO2 single crystals with a large percentage of reactive facets journal May 2008
TiO 2 −Graphene Nanocomposites for Gas-Phase Photocatalytic Degradation of Volatile Aromatic Pollutant: Is TiO 2 −Graphene Truly Different from Other TiO 2 −Carbon Composite Materials? journal November 2010
Stacking-Dependent Optical Conductivity of Bilayer Graphene journal June 2010
Large area mosaic films of graphene–titania: self-assembly at the liquid–air interface and photo-responsive behavior journal January 2011
Colloidal Suspensions of Highly Reduced Graphene Oxide in a Wide Variety of Organic Solvents journal April 2009
Explaining the Enhanced Photocatalytic Activity of Degussa P25 Mixed-Phase TiO 2 Using EPR journal May 2003
High-yield production of graphene by liquid-phase exfoliation of graphite journal August 2008
Engineering the Unique 2D Mat of Graphene to Achieve Graphene-TiO 2 Nanocomposite for Photocatalytic Selective Transformation: What Advantage does Graphene Have over Its Forebear Carbon Nanotube? journal August 2011
Single Wall Carbon Nanotube Scaffolds for Photoelectrochemical Solar Cells. Capture and Transport of Photogenerated Electrons journal March 2007
Sorting carbon nanotubes by electronic structure using density differentiation journal October 2006
Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material journal April 2008
Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite journal August 2009
Introduction to Surface Chemistry and Catalysis journal January 1995
Minimizing Graphene Defects Enhances Titania Nanocomposite-Based Photocatalytic Reduction of CO2 for Improved Solar Fuel Production journal July 2011
Graphene-based photocatalytic composites journal January 2011

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