Catalytic reduction of nitric oxide
Conference
·
OSTI ID:126217
- Univ. of California at San Diego, La Jolla, CA (United States)
Nitric oxide (NO) and nitrous oxide (N{sub 2}O) are environmentally and physiologically important gasses. NO is catalytically reduced to N{sub 2}O, and cuprous chloride (CuCl) is oxidized to cupric chloride (CuCl2) in the presence of palladium dichloride in 2M HCl. The kinetics of this reaction were studied with uv/vis and IR spectroscopy. The rate of Cu oxidation exhibits a first order dependence on the concentration of Pd(II). This dependence implies that a monomeric Pd(II) is functioning as the active catalyst. A novel apparatus for studying the rate of N{sub 2}O production while simultaneously studying the rate of CuCl2 production is presented.
- OSTI ID:
- 126217
- Report Number(s):
- CONF-950402--
- Country of Publication:
- United States
- Language:
- English
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