Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage

Ren, Chang E.; Zhao, M-Q; Makaryan, Taron; Halim, Joseph; Boota, M.; Kota, Sankalp; Anasori, Babak; Barsoum, M W; Gogotsi, Yury

doi:10.1002/celc.201600059

Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage

Journal Article · Tue Feb 16 00:00:00 EST 2016 · ChemElectroChem

DOI:https://doi.org/10.1002/celc.201600059· OSTI ID:1261374

Ren, Chang E. ^[1]; Zhao, M-Q ^[1]; Makaryan, Taron ^[1]; Halim, Joseph ^[1]; Boota, M. ^[1]; Kota, Sankalp ^[1]; Anasori, Babak ^[1]; Barsoum, M W ^[1]; Gogotsi, Yury ^[1]

Drexel Univ., Philadelphia, PA (United States)

Herein we develop a chemical etching method to produce porous two-dimensional (2D) Ti₃C₂T_x MXenes at room temperature in aqueous solutions. The as-produced porous Ti₃C₂T_x (p-Ti₃C₂T_x) have larger specific surface areas and more open structures than their pristine counterparts, and can be fabricated into flexible films with, or without, the addition of carbon nanotubes (CNTs). The as-fabricated p-Ti₃C₂T_x/CNT films showed significantly improved lithium ion storage capabilities compared to pristine Ti₃C₂T_x based films, with a very high capacity of ≈1250 mAh g^-1 at 0.1 C, excellent cycling stability, and good rate performance (330 mAh g^-1 at 10 C). Using the same chemical etching method, we also made porous Nb₂CT_x and V₂CT_x MXenes. Therefore, this study provides a simple, yet effective, procedure to introduce pores into MXenes and possibly other 2D sheets that in turn, can enhance their electrochemical properties.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261374

Alternate ID(s):: OSTI ID: 1401647
OSTI ID: 1371308
OSTI ID: 1387578

Journal Information:: ChemElectroChem, Journal Name: ChemElectroChem Journal Issue: 5 Vol. 3; ISSN 2196-0216

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Fe ₃ O ₄ @Ti ₃ C ₂ MXene hybrids with ultrahigh volumetric capacity as an anode material for lithium-ion batteries Wang, Yesheng; Li, Yanyan; Qiu, Zhipeng Journal of Materials Chemistry A, Vol. 6, Issue 24 https://doi.org/10.1039/c8ta00122g	journal	January 2018
Stanene nanomeshes as anode materials for Na-ion batteries Wu, Liyuan; Lu, Pengfei; Quhe, Ruge Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/c8ta01716f	journal	January 2018
g-C ₃ N ₄ /Ti ₃ C ₂ T _x (MXenes) composite with oxidized surface groups for efficient photocatalytic hydrogen evolution Sun, Yuliang; Jin, Di; Sun, Yuan Journal of Materials Chemistry A, Vol. 6, Issue 19 https://doi.org/10.1039/c8ta02706d	journal	January 2018
Thick and freestanding MXene/PANI pseudocapacitive electrodes with ultrahigh specific capacitance VahidMohammadi, Armin; Moncada, Jorge; Chen, Hengze Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta05807e	journal	January 2018
Quick mass-production of MAX (Ti 2 AlC) book with pages separated by stacking faults benefiting removal of “A” layer Wu, Chaozhong; Qi, Ruifeng; Zhang, Xiong Chemical Communications, Vol. 55, Issue 52 https://doi.org/10.1039/c9cc04105b	journal	January 2019
MXene and MXene-based composites: synthesis, properties and environment-related applications Zhan, Xiaoxue; Si, Chen; Zhou, Jian Nanoscale Horizons, Vol. 5, Issue 2 https://doi.org/10.1039/c9nh00571d	journal	January 2020
Two-dimensional porous silicon nanosheets as anode materials for high performance lithium-ion batteries Tang, Jingjing; Yin, Qifang; Wang, Qian Nanoscale, Vol. 11, Issue 22 https://doi.org/10.1039/c9nr01440c	journal	January 2019
A black phosphorus/Ti ₃ C ₂ MXene nanocomposite for sodium-ion batteries: a combined experimental and theoretical study Li, Huan; Liu, Anmin; Ren, Xuefeng Nanoscale, Vol. 11, Issue 42 https://doi.org/10.1039/c9nr04790e	journal	January 2019
Structural prediction and multilayer Li ⁺ storage in two-dimensional VC ₂ carbide studied by first-principles calculations Xu, Jing; Wang, Dashuai; Lian, Ruqian Journal of Materials Chemistry A, Vol. 7, Issue 15 https://doi.org/10.1039/c9ta01476d	journal	January 2019
Few-layered Ti ₃ C ₂ T _x MXenes coupled with Fe ₂ O ₃ nanorod arrays grown on carbon cloth as anodes for flexible asymmetric supercapacitors Li, Fei; Liu, Yi-Lin; Wang, Gui-Gen Journal of Materials Chemistry A, Vol. 7, Issue 39 https://doi.org/10.1039/c9ta08144e	journal	January 2019
Mesoporous MXene powders synthesized by acid induced crumpling and their use as Na-ion battery anodes Natu, Varun; Clites, Mallory; Pomerantseva, Ekaterina Materials Research Letters, Vol. 6, Issue 4 https://doi.org/10.1080/21663831.2018.1434249	journal	February 2018
Layered ternary M _{n +1} AX _n phases and their 2D derivative MXene: an overview from a thin-film perspective Eklund, Per; Rosen, Johanna; Persson, Per O. Å Journal of Physics D: Applied Physics, Vol. 50, Issue 11 https://doi.org/10.1088/1361-6463/aa57bc	journal	February 2017
Mesoporous MXene powders synthesized by acid induced crumpling and their use as Na-ion battery anodes Natu, Varun; Clites, Mallory; Pomerantseva, Ekaterina Figshare https://doi.org/10.6084/m9.figshare.5914738	text	January 2018
Mesoporous MXene powders synthesized by acid induced crumpling and their use as Na-ion battery anodes Natu, Varun; Clites, Mallory; Pomerantseva, Ekaterina Figshare https://doi.org/10.6084/m9.figshare.5914738.v1	text	January 2018

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