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Title: Highly Improved Rate Capability for a Lithium-Ion Battery Nano-Li4Ti5O12 Negative Electrode via Carbon-Coated Mesoporous Uniform Pores with a Simple Self-Assembly Method

Journal Article · · Advanced Functional Materials

Research Organization:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE; NREL Laboratory Directed Research and Development Fund
DOE Contract Number:
AC36-08GO28308
OSTI ID:
1259247
Report Number(s):
NREL/JA-5900-53703
Journal Information:
Advanced Functional Materials, Vol. 21, Issue 22; ISSN 1616-301X
Publisher:
Wiley
Country of Publication:
United States
Language:
English

References (76)

Issues and challenges facing rechargeable lithium batteries journal November 2001
Nanostructured materials for advanced energy conversion and storage devices journal May 2005
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries journal February 2006
Building better batteries journal February 2008
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries journal May 2009
Key challenges in future Li-battery research journal July 2010
Nanostructured Fe3O4/SWNT Electrode: Binder-Free and High-Rate Li-Ion Anode journal May 2010
Structure and electrochemistry of the spinel oxides LiTi2O4 and Li43Ti53O4 journal May 1989
Spinel Anodes for Lithium-Ion Batteries journal January 1994
Zero-Strain Insertion Material of Li[Li[sub 1∕3]Ti[sub 5∕3]]O[sub 4] for Rechargeable Lithium Cells journal January 1995
Nanostructures and lithium electrochemical reactivity of lithium titanites and titanium oxides: A review journal July 2009
Size Effects in the Li 4+ x Ti 5 O 12 Spinel journal December 2009
Li4Ti5O12/Ag composite as electrode materials for lithium-ion battery journal March 2006
Three-Dimensionally Ordered Macroporous Li4Ti5O12:  Effect of Wall Structure on Electrochemical Properties journal December 2005
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model journal January 1979
Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells journal January 1990
The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries journal January 1994
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes journal January 1997
In Situ Investigation of the Electrochemical Reduction of Carbonate Electrolyte Solutions at Graphite Electrodes journal January 1998
New Insight into the Solid Electrolyte Interphase with Use of a Focused Ion Beam journal December 2005
Surface reactivity of graphite materials and their surface passivation during the first electrochemical lithium insertion journal February 2006
Ultrathin Direct Atomic Layer Deposition on Composite Electrodes for Highly Durable and Safe Li-Ion Batteries journal April 2010
Fluorinated organic solvents in electrolytes for lithium ion cells journal July 2001
Investigations of the Exothermic Reactions of Natural Graphite Anode for Li-Ion Batteries during Thermal Runaway journal January 2005
Quantitative studies on the thermal stability of the interface between graphite electrode and electrolyte journal December 2008
Electrochemical stability of bis(trifluoromethanesulfonyl)imide-based ionic liquids at elevated temperature as a solvent for a titanium oxide bronze electrode journal December 2009
Ultrathin Coatings on Nano-LiCoO2 for Li-Ion Vehicular Applications journal February 2011
High-performance lithium battery anodes using silicon nanowires journal December 2007
Superior Lithium Electroactive Mesoporous Si@Carbon Core−Shell Nanowires for Lithium Battery Anode Material journal November 2008
Silicon Nanotube Battery Anodes journal November 2009
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions journal August 2010
Inhibition of Lithium Dendrites by Fumed Silica-Based Composite Electrolytes journal January 2004
A consideration of lithium cell safety journal September 1999
Safety mechanisms in lithium-ion batteries journal April 2006
Zero-strain insertion mechanism of Li[Li1/3Ti5/3]O4 for advanced lithium-ion (shuttlecock) batteries journal November 2005
Harnessing the Actuation Potential of Solid-State Intercalation Compounds journal March 2006
Diffusion coefficient measurement of lithium ion in sintered Li1.33Ti1.67O4 by means of neutron radiography journal August 1999
Electrochemical study of Li4Ti5O12 as negative electrode for Li-ion polymer rechargeable batteries journal September 1999
Studies of Mg-Substituted Li4−xMgxTi5O12 Spinel Electrodes (0≤x≤1) for Lithium Batteries journal January 2001
General synthesis of carbon-coated nanostructure Li 4 Ti 5 O 12 as a high rate electrode material for Li-ion intercalation journal January 2010
In situ growth of Li 4 Ti 5 O 12 on multi-walled carbon nanotubes: novel coaxial nanocables for high rate lithium ion batteries journal January 2011
Preparation and electrochemical performance of Ag doped Li4Ti5O12 journal November 2004
Structure and Electrochemical Properties of Zn-Doped Li[sub 4]Ti[sub 5]O[sub 12] as Anode Materials in Li-Ion Battery journal January 2010
Nitridation-Driven Conductive Li 4 Ti 5 O 12 for Lithium Ion Batteries journal November 2008
Reversible Lithium-Ion Insertion in Molybdenum Oxide Nanoparticles journal October 2008
Influence of Size on the Rate of Mesoporous Electrodes for Lithium Batteries journal January 2010
Nanostructured Anode Material for High-Power Battery System in Electric Vehicles journal June 2010
A new family of mesoporous molecular sieves prepared with liquid crystal templates journal December 1992
Titanium-containing mesoporous molecular sieves for catalytic oxidation of aromatic compounds journal March 1994
Templating of Mesoporous Molecular Sieves by Nonionic Polyethylene Oxide Surfactants journal September 1995
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores journal January 1998
Mesostructured γ-Al 2 O 3 with a Lathlike Framework Morphology journal October 2002
Ordered Mesoporous Metallic MoO 2 Materials with Highly Reversible Lithium Storage Capacity journal December 2009
Synthesis of Nanowire and Mesoporous Low-Temperature LiCoO2 by a Post-Templating Reaction journal October 2005
Synthesis of Ordered Mesoporous Li-Mn-O Spinel as a Positive Electrode for Rechargeable Lithium Batteries journal December 2008
Lithium Intercalation into Mesoporous Anatase with an Ordered 3D Pore Structure journal March 2010
Synthesis of a Stable Hexagonally Packed Mesoporous Niobium Oxide Molecular Sieve Through a Novel Ligand-Assisted Templating Mechanism journal March 1996
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks journal November 1998
Evidence of Two-Phase Formation upon Lithium Insertion into the Li[sub 1.33]Ti[sub 1.67]O[sub 4] Spinel journal January 1999
Electrochemical characteristics of spinel Li4Ti5O12 discharged to 0.01V journal May 2008
Electrochemical behavior and stability of Li4Ti5O12 in a broad voltage window journal November 2008
Direct access to thermally stable and highly crystalline mesoporous transition-metal oxides with uniform pores journal January 2008
Development of a New Mesoporous Carbon Using an HMS Aluminosilicate Template journal March 2000
A Neutral Templating Route to Mesoporous Molecular Sieves journal February 1995
Employing Raman Spectroscopy to Qualitatively Evaluate the Purity of Carbon Single-Wall Nanotube Materials journal September 2004
Disordered Molecular Sieve with Branched Mesoporous Channel Network journal January 1996
Gas Adsorption Characterization of Ordered Organic−Inorganic Nanocomposite Materials journal October 2001
Controllable and Repeatable Synthesis of Thermally Stable Anatase Nanocrystal−Silica Composites with Highly Ordered Hexagonal Mesostructures journal November 2007
A Kinetic Two-Phase and Equilibrium Solid Solution in Spinel Li4+xTi5O12 journal December 2006
Large Impact of Particle Size on Insertion Reactions. A Case for Anatase Li x TiO 2 journal April 2007
Impedance Spectroscopy of Li Electrodes. 4. A General Simple Model of the Li−Solution Interphase in Polar Aprotic Systems journal January 1996
Common Electroanalytical Behavior of Li Intercalation Processes into Graphite and Transition Metal Oxides journal January 1998
The Importance of Interphase Contacts in Li Ion Electrodes: The Meaning of the High-Frequency Impedance Arc journal January 2008
On the Interpretation of Measured Impedance Spectra of Insertion Cathodes for Lithium-Ion Batteries journal January 2010
Carbon-Coated Li[sub 4]Ti[sub 5]O[sub 12] as a High Rate Electrode Material for Li-Ion Intercalation journal January 2007
Microstructure effect on the electrochemical property of Li4Ti5O12 as an anode material for lithium-ion batteries journal October 2008