Ultem®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties

doi:https://doi.org/10.1590/1980-5373-MR-2015-0621

Title: Ultem ^®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties

Abstract

Mixed matrix membranes are promising options for improving gas separation processes. Zeolitic imidazolate frameworks (ZIFs) have a porous structure similar to conventional zeolites, being capable in principle of separating gases based on their differences in kinetic diameter while offering the advantage of having a partial organic character. This partial organic nature improves the compatibility between the sieve and the polymer, and a combination of the mentioned characteristics makes these hybrid materials interesting for the preparation of mixed matrix gas separation membranes. In this context the present work reports the preparation of Ultem ^®/ZIF-8 mixed matrix membranes and their permeabilities to pure CO ₂, N ₂ and CH ₄ gases. A significant increase in permeability with increase in CO ₂/N ₂selectivity was observed for the mixed matrix systems as compared to the properties of the neat Ultem ^®. Sorption results allowed to speculate that the ZIF-8 framework is not completely stable dimensionally, what influences the separation process by allowing gases with higher kinetic diameter than its nominal aperture to be sorbed and to diffuse through the crystal. Lastly, sorption and diffusion selectivities indicate that the higher separation performance of the mixed matrix membranes is governed by the diffusion process associatedmore »« less

Authors:

Eiras, Daniel ^[1]; Labreche, Ying ^[2]; Pessan, Luiz Antonio ^[1]

Univ. Federal de Sao Carlos, Sao Carlos (Brazil)
Georgia Inst. of Technology, Atlanta, GA (United States)

Publication Date:: 2016-02-19

Research Org.:: Georgia Tech Research Corporation, Atlanta, GA (United States)

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1257981

Grant/Contract Number:: AR0000074

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Materials Research (Sao Carlos, Online)

Additional Journal Information:: Journal Volume: 19; Journal Issue: 1; Journal ID: ISSN 1980-5373

Publisher:: Univerisdade Federale de Sao Carlos

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; ZIF-8; mixed matrix membranes; gas separation; gas permeation; gas sorption

Citation Formats


                    Eiras, Daniel, Labreche, Ying, and Pessan, Luiz Antonio. Ultem®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties.  United States: N. p., 2016. 
        Web.  doi:10.1590/1980-5373-MR-2015-0621.

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                    Eiras, Daniel, Labreche, Ying, & Pessan, Luiz Antonio. Ultem®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties.  United States.  https://doi.org/10.1590/1980-5373-MR-2015-0621

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                    Eiras, Daniel, Labreche, Ying, and Pessan, Luiz Antonio. Fri .  
        "Ultem®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties".  United States.  https://doi.org/10.1590/1980-5373-MR-2015-0621.  https://www.osti.gov/servlets/purl/1257981.

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@article{osti_1257981,

  title        = {Ultem®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties},

  author       = {Eiras, Daniel and Labreche, Ying and Pessan, Luiz Antonio},

  abstractNote = {Mixed matrix membranes are promising options for improving gas separation processes. Zeolitic imidazolate frameworks (ZIFs) have a porous structure similar to conventional zeolites, being capable in principle of separating gases based on their differences in kinetic diameter while offering the advantage of having a partial organic character. This partial organic nature improves the compatibility between the sieve and the polymer, and a combination of the mentioned characteristics makes these hybrid materials interesting for the preparation of mixed matrix gas separation membranes. In this context the present work reports the preparation of Ultem®/ZIF-8 mixed matrix membranes and their permeabilities to pure CO2, N2 and CH4 gases. A significant increase in permeability with increase in CO2/N2 selectivity was observed for the mixed matrix systems as compared to the properties of the neat Ultem®. Sorption results allowed to speculate that the ZIF-8 framework is not completely stable dimensionally, what influences the separation process by allowing gases with higher kinetic diameter than its nominal aperture to be sorbed and to diffuse through the crystal. Lastly, sorption and diffusion selectivities indicate that the higher separation performance of the mixed matrix membranes is governed by the diffusion process associated with the influence of gas molecule´s geometry.},

  doi          = {10.1590/1980-5373-MR-2015-0621},

  url          = {https://www.osti.gov/biblio/1257981},
  journal      = {Materials Research (Sao Carlos, Online)},

  issn         = {1980-5373},

  number       = 1,

  volume       = 19,

  place        = {United States},

  year         = {2016},

  month        = {2}

}

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Works referenced in this record:

Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies
journal, February 2006

Huang, Xiao-Chun; Lin, Yan-Yong; Zhang, Jie-Peng
Angewandte Chemie International Edition, Vol. 45, Issue 10, p. 1557-1559
https://doi.org/10.1002/anie.200503778

Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO ₂ capture?
journal, January 2015

Seoane, Beatriz; Coronas, Joaquin; Gascon, Ignacio
Chemical Society Reviews, Vol. 44, Issue 8
https://doi.org/10.1039/c4cs00437j

Mixed gas sorption in glassy polymers: Equipment design considerations and preliminary results
journal, April 1983

Sanders, E. S.; Koros, W. J.; Hopfenberg, H. B.
Journal of Membrane Science, Vol. 13, Issue 2
https://doi.org/10.1016/s0376-7388(00)80159-3

Correlation of separation factor versus permeability for polymeric membranes
journal, October 1991

Robeson, Lloyd M.
Journal of Membrane Science, Vol. 62, Issue 2
https://doi.org/10.1016/0376-7388(91)80060-j

Exploring the Framework Hydrophobicity and Flexibility of ZIF-8: From Biofuel Recovery to Hydrocarbon Separations
journal, October 2013

Zhang, Ke; Lively, Ryan P.; Zhang, Chen
The Journal of Physical Chemistry Letters, Vol. 4, Issue 21
https://doi.org/10.1021/jz402019d

Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation
journal, January 2012

Song, Qilei; Nataraj, S. K.; Roussenova, Mina V.
Energy & Environmental Science, Vol. 5, Issue 8
https://doi.org/10.1039/c2ee21996d

Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO ₂ /CH ₄ Separation
journal, January 2010

Venna, Surendar R.; Carreon, Moises A.
Journal of the American Chemical Society, Vol. 132, Issue 1
https://doi.org/10.1021/ja909263x

Crystallography Open Database – an open-access collection of crystal structures
journal, May 2009

Gražulis, Saulius; Chateigner, Daniel; Downs, Robert T.
Journal of Applied Crystallography, Vol. 42, Issue 4
https://doi.org/10.1107/s0021889809016690

Highly scalable ZIF-based mixed-matrix hollow fiber membranes for advanced hydrocarbon separations
journal, May 2014

Zhang, Chen; Zhang, Kuang; Xu, Liren
AIChE Journal, Vol. 60, Issue 7
https://doi.org/10.1002/aic.14496

Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014

Chen, Binling; Yang, Zhuxian; Zhu, Yanqiu
Journal of Materials Chemistry A, Vol. 2, Issue 40, p. 16811-16831
https://doi.org/10.1039/c4ta02984d

Tailoring mixed matrix composite membranes for gas separations
journal, December 1997

Zimmerman, Catherine M.; Singh, Anshu; Koros, William J.
Journal of Membrane Science, Vol. 137, Issue 1-2
https://doi.org/10.1016/s0376-7388(97)00194-4

Molecular Simulations and Theoretical Predictions for Adsorption and Diffusion of CH ₄ /H ₂ and CO ₂ /CH ₄ Mixtures in ZIFs
journal, June 2011

Liu, Jinchen; Keskin, Seda; Sholl, David S.
The Journal of Physical Chemistry C, Vol. 115, Issue 25
https://doi.org/10.1021/jp203053h

Natural gas purification and olefin/paraffin separation using thermal cross-linkable co-polyimide/ZIF-8 mixed matrix membranes
journal, October 2013

Askari, Mohammad; Chung, Tai-Shung
Journal of Membrane Science, Vol. 444
https://doi.org/10.1016/j.memsci.2013.05.016

Reticular synthesis and the design of new materials
journal, June 2003

Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
Nature, Vol. 423, Issue 6941, p. 705-714
https://doi.org/10.1038/nature01650

Diffusion of CH4 and H2 in ZIF-8
journal, July 2011

Hertäg, Loreen; Bux, Helge; Caro, Jürgen
Journal of Membrane Science, Vol. 377, Issue 1-2
https://doi.org/10.1016/j.memsci.2011.01.019

Permeation Equipment for High-Pressure Gas Separation Membranes
journal, December 2003

Damle, Shilpa; Koros, William J.
Industrial & Engineering Chemistry Research, Vol. 42, Issue 25
https://doi.org/10.1021/ie030039n

Molecular sieving realized with ZIF-8/Matrimid^® mixed-matrix membranes
journal, September 2010

Ordoñez, Ma. Josephine C.; Balkus, Kenneth J.; Ferraris, John P.
Journal of Membrane Science, Vol. 361, Issue 1-2, p. 28-37
https://doi.org/10.1016/j.memsci.2010.06.017

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
https://doi.org/10.1039/b802426j

Crosslinkable mixed matrix membranes with surface modified molecular sieves for natural gas purification: I. Preparation and experimental results
journal, July 2011

Ward, Jason K.; Koros, William J.
Journal of Membrane Science, Vol. 377, Issue 1-2
https://doi.org/10.1016/j.memsci.2011.04.010

High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations
journal, February 2012

Zhang, Chen; Dai, Ying; Johnson, Justin R.
Journal of Membrane Science, Vol. 389
https://doi.org/10.1016/j.memsci.2011.10.003

Ultem®/ZIF-8 mixed matrix hollow fiber membranes for CO2/N2 separations
journal, May 2012

Dai, Ying; Johnson, J. R.; Karvan, Oğuz
Journal of Membrane Science, Vol. 401-402
https://doi.org/10.1016/j.memsci.2012.01.044

The diffusion time lag in polymer membranes containing adsorptive fillers
journal, January 1973

Paul, D. R.; Kemp, D. R.
Journal of Polymer Science: Polymer Symposia, Vol. 41, Issue 1
https://doi.org/10.1002/polc.5070410109

Highly permeable zeolitic imidazolate framework (ZIF)-71 nano-particles enhanced polyimide membranes for gas separation
journal, October 2014

Japip, Susilo; Wang, Huan; Xiao, Youchang
Journal of Membrane Science, Vol. 467
https://doi.org/10.1016/j.memsci.2014.05.025

Preparation of zeolite filled glassy polymer membranes
journal, October 1994

Duval, J. -M.; Kemperman, A. J. B.; Folkers, B.
Journal of Applied Polymer Science, Vol. 54, Issue 4
https://doi.org/10.1002/app.1994.070540401

Mixed-linker zeolitic imidazolate framework mixed-matrix membranes for aggressive CO2 separation from natural gas
journal, July 2014

Thompson, Joshua A.; Vaughn, Justin T.; Brunelli, Nicholas A.
Microporous and Mesoporous Materials, Vol. 192
https://doi.org/10.1016/j.micromeso.2013.06.036

Polymer–nanoparticle interfacial interactions in polymer nanocomposites: Confinement effects on glass transition temperature and suppression of physical aging
journal, January 2006

Rittigstein, Perla; Torkelson, John M.
Journal of Polymer Science Part B: Polymer Physics, Vol. 44, Issue 20
https://doi.org/10.1002/polb.20925

Significance of Entropic Selectivity for Advanced Gas Separation Membranes
journal, January 1996

Singh, Anshu; Koros, W. J.
Industrial & Engineering Chemistry Research, Vol. 35, Issue 4
https://doi.org/10.1021/ie950559l

Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations
journal, June 2011

Fairen-Jimenez, D.; Moggach, S. A.; Wharmby, M. T.
Journal of the American Chemical Society, Vol. 133, Issue 23
https://doi.org/10.1021/ja202154j

Mixed matrix hollow fiber membranes made with modified HSSZ-13 zeolite in polyetherimide polymer matrix for gas separation
journal, February 2007

Husain, Shabbir; Koros, William J.
Journal of Membrane Science, Vol. 288, Issue 1-2
https://doi.org/10.1016/j.memsci.2006.11.016

Structural Evolution of Zeolitic Imidazolate Framework-8
journal, December 2010

Venna, Surendar R.; Jasinski, Jacek B.; Carreon, Moises A.
Journal of the American Chemical Society, Vol. 132, Issue 51
https://doi.org/10.1021/ja109268m

Mixed matrix membrane materials with glassy polymers. Part 2
journal, July 2002

Mahajan, Rajiv; Koros, William J.
Polymer Engineering & Science, Vol. 42, Issue 7
https://doi.org/10.1002/pen.11042

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO₂ Capture
journal, February 2008

Banerjee, Rahul; Phan, Anh; Wang, Bo
Science, Vol. 319, Issue 5865, p. 939-943
https://doi.org/10.1126/science.1152516

Mixed matrix membrane materials with glassy polymers. Part 1
journal, July 2002

Mahajan, Rajiv; Koros, William J.
Polymer Engineering & Science, Vol. 42, Issue 7
https://doi.org/10.1002/pen.11041

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
Science, Vol. 295, Issue 5554, p. 469-472
https://doi.org/10.1126/science.1067208

Non-ideal effects in organic–inorganic materials for gas separation membranes
journal, April 2005

Moore, Theodore T.; Koros, William J.
Journal of Molecular Structure, Vol. 739, Issue 1-3
https://doi.org/10.1016/j.molstruc.2004.05.043

Ethene/ethane separation by the MOF membrane ZIF-8: Molecular correlation of permeation, adsorption, diffusion
journal, March 2011

Bux, Helge; Chmelik, Christian; Krishna, Rajamani
Journal of Membrane Science, Vol. 369, Issue 1-2
https://doi.org/10.1016/j.memsci.2010.12.001

Hydrogen and Methane Adsorption in Metal−Organic Frameworks: A High-Pressure Volumetric Study
journal, November 2007

Zhou, Wei; Wu, Hui; Hartman, Michael R.
The Journal of Physical Chemistry C, Vol. 111, Issue 44
https://doi.org/10.1021/jp074889i

Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis
journal, November 2009

Bux, Helge; Liang, Fangyi; Li, Yanshuo
Journal of the American Chemical Society, Vol. 131, Issue 44
https://doi.org/10.1021/ja907359t

Structural Relaxation of Polymer Glasses at Surfaces, Interfaces, and In Between
journal, July 2005

Priestley, R. D.
Science, Vol. 309, Issue 5733
https://doi.org/10.1126/science.1112217

Effect of zeolitic imidazolate frameworks on the gas transport performance of ZIF8-poly(1,4-phenylene ether-ether-sulfone) hybrid membranes
journal, November 2011

Díaz, Kenya; López-González, Mar; del Castillo, Luis F.
Journal of Membrane Science, Vol. 383, Issue 1-2
https://doi.org/10.1016/j.memsci.2011.08.042

Mixed matrix membranes using carbon molecular sieves
journal, January 2003

Vu, De Q.; Koros, William J.; Miller, Stephen J.
Journal of Membrane Science, Vol. 211, Issue 2
https://doi.org/10.1016/s0376-7388(02)00429-5

The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1.47 GPa
journal, September 2009

Moggach, Stephen A.; Bennett, Thomas D.; Cheetham, Anthony K.
Angewandte Chemie International Edition, Vol. 48, Issue 38
https://doi.org/10.1002/anie.200902643

Zeolite A imidazolate frameworks
journal, May 2007

Hayashi, Hideki; Côté, Adrien P.; Furukawa, Hiroyasu
Nature Materials, Vol. 6, Issue 7, p. 501-506
https://doi.org/10.1038/nmat1927

Alcohol and water adsorption in zeolitic imidazolate frameworks
journal, January 2013

Zhang, Ke; Lively, Ryan P.; Dose, Michelle E.
Chemical Communications, Vol. 49, Issue 31
https://doi.org/10.1039/c3cc39116g

Characterization of low permeability gas separation membranes and barrier materials; design and operation considerations
journal, December 2004

Moore, Theodore T.; Damle, Shilpa; Williams, P. Jason
Journal of Membrane Science, Vol. 245, Issue 1-2
https://doi.org/10.1016/j.memsci.2004.07.017

Gas transport in polymers based on bisphenol-A
journal, April 1988

Barbari, T. A.; Koros, W. J.; Paul, D. R.
Journal of Polymer Science Part B: Polymer Physics, Vol. 26, Issue 4
https://doi.org/10.1002/polb.1988.090260401

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
Nature, Vol. 402, Issue 6759, p. 276-279
https://doi.org/10.1038/46248

Molecular Simulation for Adsorption and Separation of CH ₄ /H ₂ in Zeolitic Imidazolate Frameworks
journal, June 2010

Guo, Hai-chao; Shi, Fan; Ma, Zheng-fei
The Journal of Physical Chemistry C, Vol. 114, Issue 28
https://doi.org/10.1021/jp908978q

Challenges in forming successful mixed matrix membranes with rigid polymeric materials
journal, August 2002

Mahajan, Rajiv; Burns, Ryan; Schaeffer, Michael
Journal of Applied Polymer Science, Vol. 86, Issue 4
https://doi.org/10.1002/app.10998

Performance and plasticization behavior of polymer–MOF membranes for gas separation at elevated pressures
journal, November 2014

Shahid, Salman; Nijmeijer, Kitty
Journal of Membrane Science, Vol. 470
https://doi.org/10.1016/j.memsci.2014.07.034

The upper bound revisited
journal, July 2008

Robeson, Lloyd M.
Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400
https://doi.org/10.1016/j.memsci.2008.04.030

Mixed matrix membranes using carbon molecular sieves
journal, January 2003

Vu, De Q.; Koros, William J.; Miller, Stephen J.
Journal of Membrane Science, Vol. 211, Issue 2
https://doi.org/10.1016/S0376-7388(02)00429-5

Tailoring mixed matrix composite membranes for gas separations
journal, December 1997

Zimmerman, Catherine M.; Singh, Anshu; Koros, William J.
Journal of Membrane Science, Vol. 137, Issue 1-2
https://doi.org/10.1016/S0376-7388(97)00194-4

Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014

Chen, Binling; Yang, Zhuxian; Zhu, Yanqiu
Journal of Materials Chemistry A, Vol. 2, Issue 40, p. 16811-16831
https://doi.org/10.1039/C4TA02984D

Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO ₂ capture?
journal, January 2015

Seoane, Beatriz; Coronas, Joaquin; Gascon, Ignacio
Chemical Society Reviews, Vol. 44, Issue 8
https://doi.org/10.1039/C4CS00437J

Crystallography Open Database – an open-access collection of crystal structures
journal, May 2009

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Journal of Applied Crystallography, Vol. 42, Issue 4
https://doi.org/10.1107/S0021889809016690

Correlation of separation factor versus permeability for polymeric membranes
journal, October 1991

Robeson, Lloyd M.
Journal of Membrane Science, Vol. 62, Issue 2
https://doi.org/10.1016/0376-7388(91)80060-J

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Title: Ultem ®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties

Abstract

Citation Formats

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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal, January 2002

Non-ideal effects in organic–inorganic materials for gas separation membranes journal, April 2005

Ethene/ethane separation by the MOF membrane ZIF-8: Molecular correlation of permeation, adsorption, diffusion journal, March 2011

Hydrogen and Methane Adsorption in Metal−Organic Frameworks: A High-Pressure Volumetric Study journal, November 2007

Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis journal, November 2009

Structural Relaxation of Polymer Glasses at Surfaces, Interfaces, and In Between journal, July 2005

Effect of zeolitic imidazolate frameworks on the gas transport performance of ZIF8-poly(1,4-phenylene ether-ether-sulfone) hybrid membranes journal, November 2011

Mixed matrix membranes using carbon molecular sieves journal, January 2003

The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1.47 GPa journal, September 2009

Zeolite A imidazolate frameworks journal, May 2007

Alcohol and water adsorption in zeolitic imidazolate frameworks journal, January 2013

Characterization of low permeability gas separation membranes and barrier materials; design and operation considerations journal, December 2004

Gas transport in polymers based on bisphenol-A journal, April 1988

Design and synthesis of an exceptionally stable and highly porous metal-organic framework journal, November 1999

Molecular Simulation for Adsorption and Separation of CH 4 /H 2 in Zeolitic Imidazolate Frameworks journal, June 2010

Challenges in forming successful mixed matrix membranes with rigid polymeric materials journal, August 2002

Performance and plasticization behavior of polymer–MOF membranes for gas separation at elevated pressures journal, November 2014

The upper bound revisited journal, July 2008

Mixed matrix membranes using carbon molecular sieves journal, January 2003

Tailoring mixed matrix composite membranes for gas separations journal, December 1997

Zeolitic imidazolate framework materials: recent progress in synthesis and applications journal, January 2014

Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO 2 capture? journal, January 2015

Crystallography Open Database – an open-access collection of crystal structures journal, May 2009

Correlation of separation factor versus permeability for polymeric membranes journal, October 1991

Title: Ultem ^®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties

Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies
journal, February 2006

Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO ₂ capture?
journal, January 2015

Mixed gas sorption in glassy polymers: Equipment design considerations and preliminary results
journal, April 1983

Correlation of separation factor versus permeability for polymeric membranes
journal, October 1991

Exploring the Framework Hydrophobicity and Flexibility of ZIF-8: From Biofuel Recovery to Hydrocarbon Separations
journal, October 2013

Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation
journal, January 2012

Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO ₂ /CH ₄ Separation
journal, January 2010

Crystallography Open Database – an open-access collection of crystal structures
journal, May 2009

Highly scalable ZIF-based mixed-matrix hollow fiber membranes for advanced hydrocarbon separations
journal, May 2014

Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014

Tailoring mixed matrix composite membranes for gas separations
journal, December 1997

Molecular Simulations and Theoretical Predictions for Adsorption and Diffusion of CH ₄ /H ₂ and CO ₂ /CH ₄ Mixtures in ZIFs
journal, June 2011

Natural gas purification and olefin/paraffin separation using thermal cross-linkable co-polyimide/ZIF-8 mixed matrix membranes
journal, October 2013

Reticular synthesis and the design of new materials
journal, June 2003

Diffusion of CH4 and H2 in ZIF-8
journal, July 2011

Permeation Equipment for High-Pressure Gas Separation Membranes
journal, December 2003

Molecular sieving realized with ZIF-8/Matrimid^® mixed-matrix membranes
journal, September 2010

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

Crosslinkable mixed matrix membranes with surface modified molecular sieves for natural gas purification: I. Preparation and experimental results
journal, July 2011

High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations
journal, February 2012

Ultem®/ZIF-8 mixed matrix hollow fiber membranes for CO2/N2 separations
journal, May 2012

The diffusion time lag in polymer membranes containing adsorptive fillers
journal, January 1973

Highly permeable zeolitic imidazolate framework (ZIF)-71 nano-particles enhanced polyimide membranes for gas separation
journal, October 2014

Preparation of zeolite filled glassy polymer membranes
journal, October 1994

Mixed-linker zeolitic imidazolate framework mixed-matrix membranes for aggressive CO2 separation from natural gas
journal, July 2014

Polymer–nanoparticle interfacial interactions in polymer nanocomposites: Confinement effects on glass transition temperature and suppression of physical aging
journal, January 2006

Significance of Entropic Selectivity for Advanced Gas Separation Membranes
journal, January 1996

Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations
journal, June 2011

Mixed matrix hollow fiber membranes made with modified HSSZ-13 zeolite in polyetherimide polymer matrix for gas separation
journal, February 2007

Structural Evolution of Zeolitic Imidazolate Framework-8
journal, December 2010

Mixed matrix membrane materials with glassy polymers. Part 2
journal, July 2002

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO₂ Capture
journal, February 2008

Mixed matrix membrane materials with glassy polymers. Part 1
journal, July 2002

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

Non-ideal effects in organic–inorganic materials for gas separation membranes
journal, April 2005

Ethene/ethane separation by the MOF membrane ZIF-8: Molecular correlation of permeation, adsorption, diffusion
journal, March 2011

Hydrogen and Methane Adsorption in Metal−Organic Frameworks: A High-Pressure Volumetric Study
journal, November 2007

Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis
journal, November 2009

Structural Relaxation of Polymer Glasses at Surfaces, Interfaces, and In Between
journal, July 2005

Effect of zeolitic imidazolate frameworks on the gas transport performance of ZIF8-poly(1,4-phenylene ether-ether-sulfone) hybrid membranes
journal, November 2011

Mixed matrix membranes using carbon molecular sieves
journal, January 2003

The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1.47 GPa
journal, September 2009

Zeolite A imidazolate frameworks
journal, May 2007

Alcohol and water adsorption in zeolitic imidazolate frameworks
journal, January 2013

Characterization of low permeability gas separation membranes and barrier materials; design and operation considerations
journal, December 2004

Gas transport in polymers based on bisphenol-A
journal, April 1988

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

Molecular Simulation for Adsorption and Separation of CH ₄ /H ₂ in Zeolitic Imidazolate Frameworks
journal, June 2010

Challenges in forming successful mixed matrix membranes with rigid polymeric materials
journal, August 2002

Performance and plasticization behavior of polymer–MOF membranes for gas separation at elevated pressures
journal, November 2014

The upper bound revisited
journal, July 2008

Mixed matrix membranes using carbon molecular sieves
journal, January 2003

Tailoring mixed matrix composite membranes for gas separations
journal, December 1997

Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014

Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO ₂ capture?
journal, January 2015

Crystallography Open Database – an open-access collection of crystal structures
journal, May 2009

Correlation of separation factor versus permeability for polymeric membranes
journal, October 1991