Assembling Bare Au Nanoparticles at Positively Charged Templates

Wang, Wenjie; Zhang, Honghu; Kuzmenko, Ivan; Mallapragada, Surya; Vaknin, David

doi:10.1038/srep26462

Assembling Bare Au Nanoparticles at Positively Charged Templates

Journal Article · Thu May 26 00:00:00 EDT 2016 · Scientific Reports

DOI:https://doi.org/10.1038/srep26462· OSTI ID:1257413

Wang, Wenjie ^[1]; Zhang, Honghu ^[2]; Kuzmenko, Ivan ^[3]; Mallapragada, Surya ^[4]; Vaknin, David ^[5]

Ames Lab., Ames, IA (United States). Div. of Materials Sciences and Engineering
Ames Lab., Ames, IA (United States). Div. of Materials Sciences and Engineering; Iowa State Univ., Ames, IA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source, X-ray Science Div.
Ames Lab., Ames, IA (United States). Div. of Materials Sciences and Engineering; Iowa State Univ., Ames, IA (United States). Dept. of Chemical and Biological Engineering
Ames Lab., Ames, IA (United States). Div. of Materials Sciences and Engineering; Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy

In-situ X-ray reflectivity (XRR) and grazing incidence X-ray small-angle scattering (GISAXS) reveal that unfunctionalized (bare) gold nanoparticles (AuNP) spontaneously adsorb to a cationic lipid template formed by a Langmuir monolayer of DPTAP (1,2-dihexadecanoyl-3-trimethylammonium-propane) at vapor/aqueous interfaces. Analysis of the XRR yields the electron density profile across the charged-interfaces along the surface normal showing the AuNPs assemble with vertical thickness comparable to the particle size. The GISAXS analysis indicates that the adsorbed mono-particle layer exhibits short-range in-plane correlations. By contrast, single-stranded DNA-functionalized AuNPs, while attracted to the positively charged surface (more efficiently with the addition of salt to the solution), display less in-plane regular packing compared to bare AuNPs.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1257413

Alternate ID(s):: OSTI ID: 1323385

Report Number(s):: IS-J--8993; srep26462

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Vol. 6; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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