Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation

Zhaunerchyk, V.; Kaminska, M.; Mucke, M.; Squibb, R. J.; Eland, J. H. D.; Piancastelli, M. N.; Frasinski, L. J.; Grilj, J.; Koch, M.; McFarland, B. K.; Sistrunk, E.; Guhr, M.; Coffee, R. N.; Bostedt, C.; Bozek, J. D.; Salen, P.; Meulen, P. v. d.; Linusson, P.; Thomas, R. D.; Larsson, M.; Foucar, L.; Ullrich, J.; Motomura, K.; Mondal, S.; Ueda, K.; Richter, R.; Prince, K. C.; Takahashi, O.; Osipov, T.; Fang, L.; Murphy, B. F.; Berrah, N.; Feifel, R.

doi:10.1088/0953-4075/48/24/244003

Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation

Journal Article · Wed Oct 28 00:00:00 EDT 2015 · Journal of Physics. B, Atomic, Molecular and Optical Physics

DOI:https://doi.org/10.1088/0953-4075/48/24/244003· OSTI ID:1257226

Zhaunerchyk, V. ^[1]; Kaminska, M. ^[2]; Mucke, M. ^[3]; Squibb, R. J. ^[4]; Eland, J. H. D. ^[5]; Piancastelli, M. N. ^[6]; Frasinski, L. J. ^[7]; Grilj, J. ^[8]; Koch, M. ^[9]; McFarland, B. K. ^[8]; Sistrunk, E. ^[8]; Guhr, M. ^[8]; Coffee, R. N. ^[8]; Bostedt, C. ^[8]; Bozek, J. D. ^[8]; Salen, P. ^[10]; Meulen, P. v. d. ^[10]; Linusson, P. ^[10]; Thomas, R. D. ^[10]; Larsson, M. ^[10] more »

Univ. of Gothenburg, Gothenburg (Sweden); Uppsala Univ., Uppsala (Sweden)
Uppsala Univ., Uppsala (Sweden); Stockholm Univ., Stockholm (Sweden); Jan Kochanowski Univ., Kielce (Poland)
Uppsala Univ., Uppsala (Sweden)
Univ. of Gothenburg, Gothenburg (Sweden); Uppsala Univ., Uppsala (Sweden); Imperial College London, London (United Kingdom)
Univ. of Gothenburg, Gothenburg (Sweden); Uppsala Univ., Uppsala (Sweden); Oxford Univ., Oxford (United Kingdom)
Uppsala Univ., Uppsala (Sweden); LCPMR, UPMC and CNRS, Paris (France)
Imperial College London, London (United Kingdom)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States); Graz Univ. of Technology, Graz (Austria)
Stockholm Univ., Stockholm (Sweden)
Max-Planck-Institut fur Medizinische Forschung, Heidelberg (Germany)
Max Planck-Institut fur Kernphysik, Heidelberg (Germany); Physikalisch-Technische Bundesanstalt, Braunschweig (Germany)
Tohoku Univ., Sendai (Japan)
Elettra-Sincrotrone Trieste, Trieste (Italy)
Western Michigan Univ., Kalamazoo MI (United States)
Western Michigan Univ., Kalamazoo MI (United States); Univ. of Connecticut, Storrs, CT (United States)

Competing multi-photon ionization processes, some leading to the formation of double core hole states, have been examined in 4-aminophenol. The experiments used the linac coherent light source (LCLS) x-ray free electron laser, in combination with a time-of-flight magnetic bottle electron spectrometer and the correlation analysis method of covariance mapping. Furthermore, the results imply that 4-aminophenol molecules exposed to the focused x-ray pulses of the LCLS sequentially absorb more than two x-ray photons, resulting in the formation of multiple core holes as well as in the sequential removal of photoelectrons and Auger electrons (so-called PAPA sequences).

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1257226

Alternate ID(s):: OSTI ID: 1234723
OSTI ID: 22532196

Journal Information:: Journal of Physics. B, Atomic, Molecular and Optical Physics, Journal Name: Journal of Physics. B, Atomic, Molecular and Optical Physics Journal Issue: 24 Vol. 48; ISSN 0953-4075

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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Study of double core hole excitations in molecules by X-ray double-quantum-coherence signals: a multi-configuration simulation Hua, Weijie; Bennett, Kochise; Zhang, Yu Chemical Science, Vol. 7, Issue 9 https://doi.org/10.1039/c6sc01571a	journal	January 2016
Double core hole valence-to-core x-ray emission spectroscopy: A theoretical exploration using time-dependent density functional theory Zhang, Yu; Bergmann, Uwe; Schoenlein, Robert The Journal of Chemical Physics, Vol. 151, Issue 14 https://doi.org/10.1063/1.5111141	journal	October 2019
Multiple core-hole formation by free-electron laser radiation in molecular nitrogen Banks, H. I. B.; Little, D. A.; Emmanouilidou, A. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 51, Issue 9 https://doi.org/10.1088/1361-6455/aab40f	journal	April 2018
Short-wavelength free-electron laser sources and science: a review Seddon, E. A.; Clarke, J. A.; Dunning, D. J. Reports on Progress in Physics, Vol. 80, Issue 11 https://doi.org/10.1088/1361-6633/aa7cca	journal	October 2017
Short-wavelength free-electron laser sources and science: a review Seddon, E. A.; Clarke, J. A.; Dunning, D. J. Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2018-00596	text	January 2017

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